A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water
The formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+ layered double hydroxide (LDH) and N,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aque...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | The Scientific World Journal |
| Online Access: | http://dx.doi.org/10.1155/2013/456789 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849764975646605312 |
|---|---|
| author | Aires da Conceição Silva Jaqueline Dias Senra Andréa Luzia Ferreira de Souza Luiz Fernando Brum Malta |
| author_facet | Aires da Conceição Silva Jaqueline Dias Senra Andréa Luzia Ferreira de Souza Luiz Fernando Brum Malta |
| author_sort | Aires da Conceição Silva |
| collection | DOAJ |
| description | The formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+ layered double hydroxide (LDH) and N,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aqueous medium were carried out at room temperature, and good yields were obtained with bromoarenes and iodoarenes using the ternary system LDH-Pd-CD (cyclodextrin) as catalyst. |
| format | Article |
| id | doaj-art-c4449e53ece84953981dc3ca04562a8b |
| institution | DOAJ |
| issn | 1537-744X |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | The Scientific World Journal |
| spelling | doaj-art-c4449e53ece84953981dc3ca04562a8b2025-08-20T03:04:59ZengWileyThe Scientific World Journal1537-744X2013-01-01201310.1155/2013/456789456789A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in WaterAires da Conceição Silva0Jaqueline Dias Senra1Andréa Luzia Ferreira de Souza2Luiz Fernando Brum Malta3Instituto de Química, Universidade Federal do Rio de Janeiro, CT Bloco A Lab 641, 21941-909 Rio de Janeiro, RJ, BrazilNúcleo de Pesquisas de Produtos Naturais, Universidade Federal do Rio de Janeiro, CCS Bloco H, 21941-614 Rio de Janeiro, RJ, BrazilInstituto de Química, Universidade Federal do Rio de Janeiro, 27930-560 Macaé, RJ, BrazilInstituto de Química, Universidade Federal do Rio de Janeiro, CT Bloco A Lab 641, 21941-909 Rio de Janeiro, RJ, BrazilThe formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+ layered double hydroxide (LDH) and N,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aqueous medium were carried out at room temperature, and good yields were obtained with bromoarenes and iodoarenes using the ternary system LDH-Pd-CD (cyclodextrin) as catalyst.http://dx.doi.org/10.1155/2013/456789 |
| spellingShingle | Aires da Conceição Silva Jaqueline Dias Senra Andréa Luzia Ferreira de Souza Luiz Fernando Brum Malta A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water The Scientific World Journal |
| title | A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water |
| title_full | A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water |
| title_fullStr | A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water |
| title_full_unstemmed | A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water |
| title_short | A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water |
| title_sort | ternary catalytic system for the room temperature suzuki miyaura reaction in water |
| url | http://dx.doi.org/10.1155/2013/456789 |
| work_keys_str_mv | AT airesdaconceicaosilva aternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT jaquelinediassenra aternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT andrealuziaferreiradesouza aternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT luizfernandobrummalta aternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT airesdaconceicaosilva ternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT jaquelinediassenra ternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT andrealuziaferreiradesouza ternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater AT luizfernandobrummalta ternarycatalyticsystemfortheroomtemperaturesuzukimiyaurareactioninwater |