Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes
Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 3...
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University of Tehran
2016-01-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
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| Online Access: | https://jsciences.ut.ac.ir/article_56006_d5af44c6d6fc7998320b965750aff647.pdf |
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| author | F. Farzaneh L. Hamidipour |
| author_facet | F. Farzaneh L. Hamidipour |
| author_sort | F. Farzaneh |
| collection | DOAJ |
| description | Manganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions. |
| format | Article |
| id | doaj-art-c439cdd90e4049919aeaa07157b0993a |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-c439cdd90e4049919aeaa07157b0993a2025-08-20T02:25:54ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142016-01-01271313756006Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and AlkenesF. Farzaneh0L. Hamidipour1Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of IranDepartment of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O.Box 1993891176, Vanak,Tehran, Islamic Republic of IranManganese metal-organic framework (Mn-MOF) containing Mn2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, ethylbenzene and diphenylmethane to alcohols or ketones with tert-butylhydroperoxide (TBHP) with 19-64% conversion and 80-100% selectivity. Study of the catalyst stability and reusability revealed that Mn-MOF behaves heterogeneously in the oxidation reactions.https://jsciences.ut.ac.ir/article_56006_d5af44c6d6fc7998320b965750aff647.pdfmn metal organic frameworkheterogeneous catalysisoxidation reactionsakanesalkenes |
| spellingShingle | F. Farzaneh L. Hamidipour Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes Journal of Sciences, Islamic Republic of Iran mn metal organic framework heterogeneous catalysis oxidation reactions akanes alkenes |
| title | Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes |
| title_full | Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes |
| title_fullStr | Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes |
| title_full_unstemmed | Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes |
| title_short | Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes |
| title_sort | mn metal organic framework as heterogenous catalyst for oxidation of alkanes and alkenes |
| topic | mn metal organic framework heterogeneous catalysis oxidation reactions akanes alkenes |
| url | https://jsciences.ut.ac.ir/article_56006_d5af44c6d6fc7998320b965750aff647.pdf |
| work_keys_str_mv | AT ffarzaneh mnmetalorganicframeworkasheterogenouscatalystforoxidationofalkanesandalkenes AT lhamidipour mnmetalorganicframeworkasheterogenouscatalystforoxidationofalkanesandalkenes |