TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method

TiO2-Phosphotungstic acid nanocomposites were synthesized by annealing method. In this study, we used a specific annealing technique to optimize the microstructure and improve the performance characteristics of the material under investigation. The chemical nature of the nanocomposites were characte...

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Main Authors: Milton Praveendaniel, Ponpandian Rajesh Anantha Selvan, Moses Daniel Sweetlin
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Next Nanotechnology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2949829525000142
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author Milton Praveendaniel
Ponpandian Rajesh Anantha Selvan
Moses Daniel Sweetlin
author_facet Milton Praveendaniel
Ponpandian Rajesh Anantha Selvan
Moses Daniel Sweetlin
author_sort Milton Praveendaniel
collection DOAJ
description TiO2-Phosphotungstic acid nanocomposites were synthesized by annealing method. In this study, we used a specific annealing technique to optimize the microstructure and improve the performance characteristics of the material under investigation. The chemical nature of the nanocomposites were characterized by UV–visible, Fourier transform infrared (FT-IR), X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX), and Scanning electron microscopy (SEM) studies. UV–visible spectroscopy revealed a strong interaction between TiO2 and phosphotungstic acid. FT-IR spectroscopy confirmed new bond formed between TiO2 and phosphotungstic acid in the nanocomposites. XRD showed that the crystallite size of the nanocomposite materials decreased. SEM analysis showed that the particle size decreased and the dopants were uniformly distributed throughout the composite material. The photocatalytic activity of the nanocomposites was evaluated using the pollutant methylene blue dye. The results showed that the nanocomposites had good catalytic activity, with a degradation efficiency of up to 94 %. The temperature-dependent AC and DC electrical conductivities of the composite materials were also studied. The measurements of the dielectric constants produced informative results. Finally, the antimicrobial activities of the nanocomposites were determined by using the agar well diffusion method on the microorganism Streptococcus pyogenes. The results showed that the nanocomposites had a remarkable diameter of the zone of inhibition, indicating their potential as antimicrobial agents. Overall, the synthesized TiO2-phosphotungstic acid nanocomposites have proven to be very promising composites and have wide applications in different fields.
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spelling doaj-art-c42a4f8499bc42aabf25ee3d2ca565c22025-08-20T02:10:08ZengElsevierNext Nanotechnology2949-82952025-01-01710014510.1016/j.nxnano.2025.100145TiO2-Phosphotungstic acid nanocomposites synthesis by annealing methodMilton Praveendaniel0Ponpandian Rajesh Anantha Selvan1Moses Daniel Sweetlin2Department of Chemistry, St. John’s College, Palayamkottai, Tirunelveli, Tamil Nadu, Affiliated to Manonmaniam Sundaranar University, Tirunelveli. India; Department of Chemistry, Francis Xavier Engineering College, (Autonomous), Tirunelveli, Tamil Nadu 627003, IndiaDepartment of Chemistry, St. John’s College, Palayamkottai, Tirunelveli, Tamil Nadu, Affiliated to Manonmaniam Sundaranar University, Tirunelveli. India; Correspondence to: Department of Chemistry, St. John’s College, Palayamkottai, Tirunelveli, Tamil Nadu 627002, India.Department of Physics, St. John’s College, Palayamkottai, Tirunelveli, Tamil Nadu, Affiliated to Manonmaniam Sundaranar University, Tirunelveli. IndiaTiO2-Phosphotungstic acid nanocomposites were synthesized by annealing method. In this study, we used a specific annealing technique to optimize the microstructure and improve the performance characteristics of the material under investigation. The chemical nature of the nanocomposites were characterized by UV–visible, Fourier transform infrared (FT-IR), X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX), and Scanning electron microscopy (SEM) studies. UV–visible spectroscopy revealed a strong interaction between TiO2 and phosphotungstic acid. FT-IR spectroscopy confirmed new bond formed between TiO2 and phosphotungstic acid in the nanocomposites. XRD showed that the crystallite size of the nanocomposite materials decreased. SEM analysis showed that the particle size decreased and the dopants were uniformly distributed throughout the composite material. The photocatalytic activity of the nanocomposites was evaluated using the pollutant methylene blue dye. The results showed that the nanocomposites had good catalytic activity, with a degradation efficiency of up to 94 %. The temperature-dependent AC and DC electrical conductivities of the composite materials were also studied. The measurements of the dielectric constants produced informative results. Finally, the antimicrobial activities of the nanocomposites were determined by using the agar well diffusion method on the microorganism Streptococcus pyogenes. The results showed that the nanocomposites had a remarkable diameter of the zone of inhibition, indicating their potential as antimicrobial agents. Overall, the synthesized TiO2-phosphotungstic acid nanocomposites have proven to be very promising composites and have wide applications in different fields.http://www.sciencedirect.com/science/article/pii/S2949829525000142TiO2-phosphotungstic acidNanocompositeDielectric propertiesPhotodegradationAntimicrobial activity
spellingShingle Milton Praveendaniel
Ponpandian Rajesh Anantha Selvan
Moses Daniel Sweetlin
TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method
Next Nanotechnology
TiO2-phosphotungstic acid
Nanocomposite
Dielectric properties
Photodegradation
Antimicrobial activity
title TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method
title_full TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method
title_fullStr TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method
title_full_unstemmed TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method
title_short TiO2-Phosphotungstic acid nanocomposites synthesis by annealing method
title_sort tio2 phosphotungstic acid nanocomposites synthesis by annealing method
topic TiO2-phosphotungstic acid
Nanocomposite
Dielectric properties
Photodegradation
Antimicrobial activity
url http://www.sciencedirect.com/science/article/pii/S2949829525000142
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AT mosesdanielsweetlin tio2phosphotungsticacidnanocompositessynthesisbyannealingmethod