Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface

Surface modification of silicon steel was carried out by depositing nickel-bronze (Ni–Cu–Sn) using electrical discharge alloying. Three different compaction pressures (P) (450–650 MPa) were used to prepare compacts of nickel-bronze which were subsequently semi sintered at 1000 °C in a tubular furnac...

Full description

Saved in:
Bibliographic Details
Main Authors: Gopathy Veerappan, Manickam Ravichandran, David Pritima, Vinayagam Mohanavel, Nachimuthu Radhika, Rasaiah Naveenkumar
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Results in Surfaces and Interfaces
Online Access:http://www.sciencedirect.com/science/article/pii/S2666845924002204
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850222510409252864
author Gopathy Veerappan
Manickam Ravichandran
David Pritima
Vinayagam Mohanavel
Nachimuthu Radhika
Rasaiah Naveenkumar
author_facet Gopathy Veerappan
Manickam Ravichandran
David Pritima
Vinayagam Mohanavel
Nachimuthu Radhika
Rasaiah Naveenkumar
author_sort Gopathy Veerappan
collection DOAJ
description Surface modification of silicon steel was carried out by depositing nickel-bronze (Ni–Cu–Sn) using electrical discharge alloying. Three different compaction pressures (P) (450–650 MPa) were used to prepare compacts of nickel-bronze which were subsequently semi sintered at 1000 °C in a tubular furnace. The surface alloyed using the 450 MPa compacted, semi-sintered nickel-bronze electrode exhibited the presence of pores. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) analyses indicated the uniformity of the nickel-bronze coating on the surface achieved through EDA. The electrode synthesized at the highest compaction pressure of 650 MPa resulted in a uniform nickel-bronze coating on the steel surface. Among the three compaction pressures, the 650 MPa compacted, semi-sintered electrode (Ni–Cu–Sn) demonstrated the best performance in enhancing the hardness of the coated steel substrate, with values of 85.77 HV, 77.28 HV, 96.46 HV, 98.003 HV, and 89.613 HV. Analysis of variance (ANOVA) revealed that compaction pressure (P) is the most significant factor affecting the deposition of nickel-bronze, followed by peak current (I). The tribological behavior of uncoated silicon steel and nickel-bronze-coated steel was analyzed using a pin-on-disc tribometer. The investigation showed that the coated specimens exhibited a lower wear rate (WR) compared to the uncoated specimens. On average, there was a 19% reduction in the specific wear rate (SWR) of Ni–Cu–Sn-coated silicon steel compared to the uncoated specimens.Keywords: Silicon Steel, Microstructure, Electrical Discharge alloying, Powder metallurgy, Tribology.
format Article
id doaj-art-c4004bcecf8a4868a3beb7d2387f704f
institution OA Journals
issn 2666-8459
language English
publishDate 2025-01-01
publisher Elsevier
record_format Article
series Results in Surfaces and Interfaces
spelling doaj-art-c4004bcecf8a4868a3beb7d2387f704f2025-08-20T02:06:19ZengElsevierResults in Surfaces and Interfaces2666-84592025-01-011810040010.1016/j.rsurfi.2024.100400Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surfaceGopathy Veerappan0Manickam Ravichandran1David Pritima2Vinayagam Mohanavel3Nachimuthu Radhika4Rasaiah Naveenkumar5Department of Mechatronics Engineering, Sri Krishna College of Engineering and Technology, Coimbatore, 641 008, Tamil Nadu, IndiaDepartment of Mechanical Engineering, K.Ramakrishnan College of Engineering, Trichy, 621112, Tamil Nadu, India; Department of Mechanical Engineering and University Centre for Research & Development, Chandigarh University, Mohali, 140413, Punjab, India; Corresponding author. Department of Mechanical Engineering, K.Ramakrishnan College of Engineering, Trichy, 621112, Tamil Nadu, India.Department of Mechatronics Engineering, Sri Krishna College of Engineering and Technology, Coimbatore, 641 008, Tamil Nadu, IndiaCentre for Materials Engineering and Regenerative Medicine, Bharath Institute of Higher Education and Research, Selaiyur, Chennai, 600073, Tamil Nadu, India; Department of Mechanical Engineering, Graphic Era Hill University, Dehradun, 248002, Uttarakhand, IndiaDepartment of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa Vidyapeetham, Coimbatore, 641112, Tamil Nadu, IndiaDepartment of Mechanical Engineering, K.Ramakrishnan College of Engineering, Trichy, 621112, Tamil Nadu, IndiaSurface modification of silicon steel was carried out by depositing nickel-bronze (Ni–Cu–Sn) using electrical discharge alloying. Three different compaction pressures (P) (450–650 MPa) were used to prepare compacts of nickel-bronze which were subsequently semi sintered at 1000 °C in a tubular furnace. The surface alloyed using the 450 MPa compacted, semi-sintered nickel-bronze electrode exhibited the presence of pores. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) analyses indicated the uniformity of the nickel-bronze coating on the surface achieved through EDA. The electrode synthesized at the highest compaction pressure of 650 MPa resulted in a uniform nickel-bronze coating on the steel surface. Among the three compaction pressures, the 650 MPa compacted, semi-sintered electrode (Ni–Cu–Sn) demonstrated the best performance in enhancing the hardness of the coated steel substrate, with values of 85.77 HV, 77.28 HV, 96.46 HV, 98.003 HV, and 89.613 HV. Analysis of variance (ANOVA) revealed that compaction pressure (P) is the most significant factor affecting the deposition of nickel-bronze, followed by peak current (I). The tribological behavior of uncoated silicon steel and nickel-bronze-coated steel was analyzed using a pin-on-disc tribometer. The investigation showed that the coated specimens exhibited a lower wear rate (WR) compared to the uncoated specimens. On average, there was a 19% reduction in the specific wear rate (SWR) of Ni–Cu–Sn-coated silicon steel compared to the uncoated specimens.Keywords: Silicon Steel, Microstructure, Electrical Discharge alloying, Powder metallurgy, Tribology.http://www.sciencedirect.com/science/article/pii/S2666845924002204
spellingShingle Gopathy Veerappan
Manickam Ravichandran
David Pritima
Vinayagam Mohanavel
Nachimuthu Radhika
Rasaiah Naveenkumar
Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
Results in Surfaces and Interfaces
title Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
title_full Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
title_fullStr Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
title_full_unstemmed Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
title_short Synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
title_sort synthesis of semi sintered nickel bronze electrode for electric discharge surface alloying of silicon steel and the properties of coated surface
url http://www.sciencedirect.com/science/article/pii/S2666845924002204
work_keys_str_mv AT gopathyveerappan synthesisofsemisinterednickelbronzeelectrodeforelectricdischargesurfacealloyingofsiliconsteelandthepropertiesofcoatedsurface
AT manickamravichandran synthesisofsemisinterednickelbronzeelectrodeforelectricdischargesurfacealloyingofsiliconsteelandthepropertiesofcoatedsurface
AT davidpritima synthesisofsemisinterednickelbronzeelectrodeforelectricdischargesurfacealloyingofsiliconsteelandthepropertiesofcoatedsurface
AT vinayagammohanavel synthesisofsemisinterednickelbronzeelectrodeforelectricdischargesurfacealloyingofsiliconsteelandthepropertiesofcoatedsurface
AT nachimuthuradhika synthesisofsemisinterednickelbronzeelectrodeforelectricdischargesurfacealloyingofsiliconsteelandthepropertiesofcoatedsurface
AT rasaiahnaveenkumar synthesisofsemisinterednickelbronzeelectrodeforelectricdischargesurfacealloyingofsiliconsteelandthepropertiesofcoatedsurface