A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices

The Anderson localization of phonons in disordered superlattices has been proposed as a route to suppress thermal conductivity beyond the limits imposed by conventional scattering mechanisms. A commonly used signature of phonon localization is the emergence of the nonmonotonic dependence of thermal...

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Main Authors: Pranay Chakraborty, Milad Nasiri, Haoran Cui, Theodore Maranets, Yan Wang
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/15/7/654
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author Pranay Chakraborty
Milad Nasiri
Haoran Cui
Theodore Maranets
Yan Wang
author_facet Pranay Chakraborty
Milad Nasiri
Haoran Cui
Theodore Maranets
Yan Wang
author_sort Pranay Chakraborty
collection DOAJ
description The Anderson localization of phonons in disordered superlattices has been proposed as a route to suppress thermal conductivity beyond the limits imposed by conventional scattering mechanisms. A commonly used signature of phonon localization is the emergence of the nonmonotonic dependence of thermal conductivity <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>κ</mi></semantics></math></inline-formula> on system length <i>L</i>, i.e., a <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>κ</mi></semantics></math></inline-formula>-<i>L</i> maximum. However, such behavior has rarely been observed. In this work, we conduct extensive non-equilibrium molecular dynamics (NEMD) simulations, using the LAMMPS package, on both periodic superlattices (SLs) and aperiodic random multilayers (RMLs) constructed from Si/Ge and Lennard-Jones materials. By systematically varying acoustic contrast, interatomic bond strength, and average layer thickness, we examine the interplay between coherent and incoherent phonon transport in these systems. Our two-phonon model decomposition reveals that coherent phonons alone consistently exhibit a strong nonmonotonic <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>κ</mi></semantics></math></inline-formula>-<i>L</i>. This localization signature is often masked by the diffusive, monotonically increasing contribution from incoherent phonons. We further extract the ballistic-limit mean free paths for both phonon types, and demonstrate that incoherent transport often dominates, thereby concealing localization effects. Our findings highlight the importance of decoupling coherent and incoherent phonon contributions in both simulations and experiments. This work provides new insights and design principles for achieving phonon Anderson localization in superlattice structures.
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spelling doaj-art-c2bfeb32c2564f2689b910c8c0a229fc2025-08-20T02:45:38ZengMDPI AGCrystals2073-43522025-07-0115765410.3390/cryst15070654A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in SuperlatticesPranay Chakraborty0Milad Nasiri1Haoran Cui2Theodore Maranets3Yan Wang4Department of Engineering and Physics, Southern Arkansas University, Magnolia, AR 71753, USADepartment of Mechanical Engineering, University of Nevada, Reno, Reno, NV 89557, USADepartment of Mechanical Engineering, University of Nevada, Reno, Reno, NV 89557, USADepartment of Mechanical Engineering, University of Nevada, Reno, Reno, NV 89557, USADepartment of Mechanical Engineering, University of Nevada, Reno, Reno, NV 89557, USAThe Anderson localization of phonons in disordered superlattices has been proposed as a route to suppress thermal conductivity beyond the limits imposed by conventional scattering mechanisms. A commonly used signature of phonon localization is the emergence of the nonmonotonic dependence of thermal conductivity <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>κ</mi></semantics></math></inline-formula> on system length <i>L</i>, i.e., a <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>κ</mi></semantics></math></inline-formula>-<i>L</i> maximum. However, such behavior has rarely been observed. In this work, we conduct extensive non-equilibrium molecular dynamics (NEMD) simulations, using the LAMMPS package, on both periodic superlattices (SLs) and aperiodic random multilayers (RMLs) constructed from Si/Ge and Lennard-Jones materials. By systematically varying acoustic contrast, interatomic bond strength, and average layer thickness, we examine the interplay between coherent and incoherent phonon transport in these systems. Our two-phonon model decomposition reveals that coherent phonons alone consistently exhibit a strong nonmonotonic <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mi>κ</mi></semantics></math></inline-formula>-<i>L</i>. This localization signature is often masked by the diffusive, monotonically increasing contribution from incoherent phonons. We further extract the ballistic-limit mean free paths for both phonon types, and demonstrate that incoherent transport often dominates, thereby concealing localization effects. Our findings highlight the importance of decoupling coherent and incoherent phonon contributions in both simulations and experiments. This work provides new insights and design principles for achieving phonon Anderson localization in superlattice structures.https://www.mdpi.com/2073-4352/15/7/654superlatticephononcoherencespectral energy densitylifetimegroup velocity
spellingShingle Pranay Chakraborty
Milad Nasiri
Haoran Cui
Theodore Maranets
Yan Wang
A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices
Crystals
superlattice
phonon
coherence
spectral energy density
lifetime
group velocity
title A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices
title_full A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices
title_fullStr A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices
title_full_unstemmed A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices
title_short A Comprehensive Investigation of the Two-Phonon Characteristics of Heat Conduction in Superlattices
title_sort comprehensive investigation of the two phonon characteristics of heat conduction in superlattices
topic superlattice
phonon
coherence
spectral energy density
lifetime
group velocity
url https://www.mdpi.com/2073-4352/15/7/654
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