Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach

Chitosan which can be obtained from fishery waste was studied as an alternative source to remove pollutants in the wastewater. The adsorption process of Reactive Black 5 (RB5) by chitosan was studied under batch experimental condition to identify the optimum condition in which the dye can be removed...

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Main Authors: Yi-Pin Phung, Siew-Teng Ong, Pei-Sin Keng
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/387865
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author Yi-Pin Phung
Siew-Teng Ong
Pei-Sin Keng
author_facet Yi-Pin Phung
Siew-Teng Ong
Pei-Sin Keng
author_sort Yi-Pin Phung
collection DOAJ
description Chitosan which can be obtained from fishery waste was studied as an alternative source to remove pollutants in the wastewater. The adsorption process of Reactive Black 5 (RB5) by chitosan was studied under batch experimental condition to identify the optimum condition in which the dye can be removed at a higher rate. The best fit kinetics model was determined to be the pseudo-second-order kinetics. From the isotherm study, the experimental result was better explained by Freundlich isotherm. Plackett-Burman was employed to identify the influential variables affecting the dye uptake. Response surface methodology (RSM) was used to determine the interactions between the factors and their optimum levels for maximum uptake of RB5. The optimum condition for the highest percentage uptake of RB5 dye was determined to be at pH 4, agitation rate of 200 rpm, sorbent dosage of 1.0 g, contact time of 300 minutes, and initial dye concentration of 25 mg/L.
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publishDate 2013-01-01
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series Journal of Chemistry
spelling doaj-art-c27679e3defd461d8a8d821e9ef1a6832025-08-20T03:23:15ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/387865387865Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical ApproachYi-Pin Phung0Siew-Teng Ong1Pei-Sin Keng2Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, MalaysiaDepartment of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, MalaysiaDepartment of Pharmaceutical Chemistry, International Medical University, No.126, Jalan Jalil Perkasa 19, Bukit Jalil, 57000 Kuala Lumpur, MalaysiaChitosan which can be obtained from fishery waste was studied as an alternative source to remove pollutants in the wastewater. The adsorption process of Reactive Black 5 (RB5) by chitosan was studied under batch experimental condition to identify the optimum condition in which the dye can be removed at a higher rate. The best fit kinetics model was determined to be the pseudo-second-order kinetics. From the isotherm study, the experimental result was better explained by Freundlich isotherm. Plackett-Burman was employed to identify the influential variables affecting the dye uptake. Response surface methodology (RSM) was used to determine the interactions between the factors and their optimum levels for maximum uptake of RB5. The optimum condition for the highest percentage uptake of RB5 dye was determined to be at pH 4, agitation rate of 200 rpm, sorbent dosage of 1.0 g, contact time of 300 minutes, and initial dye concentration of 25 mg/L.http://dx.doi.org/10.1155/2013/387865
spellingShingle Yi-Pin Phung
Siew-Teng Ong
Pei-Sin Keng
Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach
Journal of Chemistry
title Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach
title_full Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach
title_fullStr Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach
title_full_unstemmed Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach
title_short Determination of Important Parameters in Affecting the Uptake of Reactive Black 5 by Chitosan Beads through Statistical Approach
title_sort determination of important parameters in affecting the uptake of reactive black 5 by chitosan beads through statistical approach
url http://dx.doi.org/10.1155/2013/387865
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AT peisinkeng determinationofimportantparametersinaffectingtheuptakeofreactiveblack5bychitosanbeadsthroughstatisticalapproach