MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel

Due to its sarcoma-derived origin and the associated carcinogenic risks, as well as its lack of tissue-specific extracellular matrix biochemical cues, the use of the injectable gel scaffold Matrigel is generally restricted to research applications. Therefore, the development of new fully synthetic i...

Full description

Saved in:
Bibliographic Details
Main Authors: Sobuj Shahidul Islam, Tatsuya Dode, Soma Kawashima, Myu Fukuoka, Takaaki Tsuruoka, Koji Nagahama
Format: Article
Language:English
Published: MDPI AG 2025-07-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/11/7/514
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850078155460575232
author Sobuj Shahidul Islam
Tatsuya Dode
Soma Kawashima
Myu Fukuoka
Takaaki Tsuruoka
Koji Nagahama
author_facet Sobuj Shahidul Islam
Tatsuya Dode
Soma Kawashima
Myu Fukuoka
Takaaki Tsuruoka
Koji Nagahama
author_sort Sobuj Shahidul Islam
collection DOAJ
description Due to its sarcoma-derived origin and the associated carcinogenic risks, as well as its lack of tissue-specific extracellular matrix biochemical cues, the use of the injectable gel scaffold Matrigel is generally restricted to research applications. Therefore, the development of new fully synthetic injectable gel scaffolds that exhibit performance comparable to Matrigel is a high priority. In this study, we developed a novel fully synthetic injectable gel scaffold by combining a biodegradable PLGA-PEG-PLGA copolymer, clay nanoparticle LAPONITE®, and L-arginine-loaded metal–organic frameworks (NU-1000) at the nano level. An aqueous solution of the developed hybrid scaffold (PLGA-PEG-PLGA/LAPONITE®/L-Arg@NU-1000) exhibited rapid sol–gel transition at body temperature following simple injection and formed a continuous bulk-sized gel, demonstrating good injectability. Long-term sustained slow release of L-arginine from the resultant gels can be achieved because NU-1000 is a suitable reservoir for L-arginine. PLGA-PEG-PLGA/LAPONITE®/L-Arg@NU-1000 hybrid gels exhibited good compatibility with and promoted the growth of human skeletal muscle satellite cells. Importantly, in vivo experiments using skeletal muscle injury model mice demonstrated that the tissue regeneration efficiency of PLGA-PEG-PLGA/LAPONITE®/L-Arg@NU-1000 gels is higher than that of Matrigel. Specifically, we judged the higher tissue regeneration efficacy of our gels by histological analysis, including MYH3 immunofluorescent staining, H&E staining, and Masson’s trichrome staining. Taken together, these data suggest that novel hybrid hydrogels could serve as injectable hydrogel scaffolds for in vivo tissue engineering and ultimately replace Matrigel.
format Article
id doaj-art-c22c240cd51b49ebb7add4c10c560e83
institution DOAJ
issn 2310-2861
language English
publishDate 2025-07-01
publisher MDPI AG
record_format Article
series Gels
spelling doaj-art-c22c240cd51b49ebb7add4c10c560e832025-08-20T02:45:38ZengMDPI AGGels2310-28612025-07-0111751410.3390/gels11070514MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than MatrigelSobuj Shahidul Islam0Tatsuya Dode1Soma Kawashima2Myu Fukuoka3Takaaki Tsuruoka4Koji Nagahama5Department of Nanobiochemistry, Frontiers of Innovative Research on Science and Technology (FIRST), Konan University, 7-1-20 Minatojima-Minamimachi, Chuo-ku, Kobe 650-0047, JapanDepartment of Nanobiochemistry, Frontiers of Innovative Research on Science and Technology (FIRST), Konan University, 7-1-20 Minatojima-Minamimachi, Chuo-ku, Kobe 650-0047, JapanDepartment of Nanobiochemistry, Frontiers of Innovative Research on Science and Technology (FIRST), Konan University, 7-1-20 Minatojima-Minamimachi, Chuo-ku, Kobe 650-0047, JapanDepartment of Nanobiochemistry, Frontiers of Innovative Research on Science and Technology (FIRST), Konan University, 7-1-20 Minatojima-Minamimachi, Chuo-ku, Kobe 650-0047, JapanDepartment of Nanobiochemistry, Frontiers of Innovative Research on Science and Technology (FIRST), Konan University, 7-1-20 Minatojima-Minamimachi, Chuo-ku, Kobe 650-0047, JapanDepartment of Nanobiochemistry, Frontiers of Innovative Research on Science and Technology (FIRST), Konan University, 7-1-20 Minatojima-Minamimachi, Chuo-ku, Kobe 650-0047, JapanDue to its sarcoma-derived origin and the associated carcinogenic risks, as well as its lack of tissue-specific extracellular matrix biochemical cues, the use of the injectable gel scaffold Matrigel is generally restricted to research applications. Therefore, the development of new fully synthetic injectable gel scaffolds that exhibit performance comparable to Matrigel is a high priority. In this study, we developed a novel fully synthetic injectable gel scaffold by combining a biodegradable PLGA-PEG-PLGA copolymer, clay nanoparticle LAPONITE®, and L-arginine-loaded metal–organic frameworks (NU-1000) at the nano level. An aqueous solution of the developed hybrid scaffold (PLGA-PEG-PLGA/LAPONITE®/L-Arg@NU-1000) exhibited rapid sol–gel transition at body temperature following simple injection and formed a continuous bulk-sized gel, demonstrating good injectability. Long-term sustained slow release of L-arginine from the resultant gels can be achieved because NU-1000 is a suitable reservoir for L-arginine. PLGA-PEG-PLGA/LAPONITE®/L-Arg@NU-1000 hybrid gels exhibited good compatibility with and promoted the growth of human skeletal muscle satellite cells. Importantly, in vivo experiments using skeletal muscle injury model mice demonstrated that the tissue regeneration efficiency of PLGA-PEG-PLGA/LAPONITE®/L-Arg@NU-1000 gels is higher than that of Matrigel. Specifically, we judged the higher tissue regeneration efficacy of our gels by histological analysis, including MYH3 immunofluorescent staining, H&E staining, and Masson’s trichrome staining. Taken together, these data suggest that novel hybrid hydrogels could serve as injectable hydrogel scaffolds for in vivo tissue engineering and ultimately replace Matrigel.https://www.mdpi.com/2310-2861/11/7/514injectable hydrogelsMOFsscaffoldstissue engineeringskeletal muscle tissue
spellingShingle Sobuj Shahidul Islam
Tatsuya Dode
Soma Kawashima
Myu Fukuoka
Takaaki Tsuruoka
Koji Nagahama
MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel
Gels
injectable hydrogels
MOFs
scaffolds
tissue engineering
skeletal muscle tissue
title MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel
title_full MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel
title_fullStr MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel
title_full_unstemmed MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel
title_short MOFs—Combining Fully Synthetic Injectable Hydrogel Scaffolds Exhibiting Higher Skeletal Muscle Regenerative Efficiency than Matrigel
title_sort mofs combining fully synthetic injectable hydrogel scaffolds exhibiting higher skeletal muscle regenerative efficiency than matrigel
topic injectable hydrogels
MOFs
scaffolds
tissue engineering
skeletal muscle tissue
url https://www.mdpi.com/2310-2861/11/7/514
work_keys_str_mv AT sobujshahidulislam mofscombiningfullysyntheticinjectablehydrogelscaffoldsexhibitinghigherskeletalmuscleregenerativeefficiencythanmatrigel
AT tatsuyadode mofscombiningfullysyntheticinjectablehydrogelscaffoldsexhibitinghigherskeletalmuscleregenerativeefficiencythanmatrigel
AT somakawashima mofscombiningfullysyntheticinjectablehydrogelscaffoldsexhibitinghigherskeletalmuscleregenerativeefficiencythanmatrigel
AT myufukuoka mofscombiningfullysyntheticinjectablehydrogelscaffoldsexhibitinghigherskeletalmuscleregenerativeefficiencythanmatrigel
AT takaakitsuruoka mofscombiningfullysyntheticinjectablehydrogelscaffoldsexhibitinghigherskeletalmuscleregenerativeefficiencythanmatrigel
AT kojinagahama mofscombiningfullysyntheticinjectablehydrogelscaffoldsexhibitinghigherskeletalmuscleregenerativeefficiencythanmatrigel