Metallic and ferromagnetic carbon allotrope discovered using molecular precursors

Although carbon materials are known for their versatile structures and properties, a crystalline phase of carbon being both metallic and ferromagnetic is yet to be found. Here, using an organic molecular precursor 3,3-dimethyl-1-butene (C_{6}H_{12}) and a comprehensive theoretical study, we have dis...

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Main Authors: Hong Fang, Joel Therrien, Puru Jena
Format: Article
Language:English
Published: American Physical Society 2025-01-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.7.013048
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author Hong Fang
Joel Therrien
Puru Jena
author_facet Hong Fang
Joel Therrien
Puru Jena
author_sort Hong Fang
collection DOAJ
description Although carbon materials are known for their versatile structures and properties, a crystalline phase of carbon being both metallic and ferromagnetic is yet to be found. Here, using an organic molecular precursor 3,3-dimethyl-1-butene (C_{6}H_{12}) and a comprehensive theoretical study, we have discovered a metastable crystalline carbon phase that is both metallic and ferromagnetic under ambient conditions. The new carbon structures, produced by stacking puckered layers of 4,6-membered rings, are found to exhibit exotic electronic, magnetic, and mechanical properties originating from a special sp^{2}−sp^{3} bonding topology. These findings open the prospect of realizing the metallic and ferromagnetic carbon allotrope in practice.
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id doaj-art-c1fe7b29f33341398472241d06f0fb16
institution Kabale University
issn 2643-1564
language English
publishDate 2025-01-01
publisher American Physical Society
record_format Article
series Physical Review Research
spelling doaj-art-c1fe7b29f33341398472241d06f0fb162025-01-13T16:46:46ZengAmerican Physical SocietyPhysical Review Research2643-15642025-01-017101304810.1103/PhysRevResearch.7.013048Metallic and ferromagnetic carbon allotrope discovered using molecular precursorsHong FangJoel TherrienPuru JenaAlthough carbon materials are known for their versatile structures and properties, a crystalline phase of carbon being both metallic and ferromagnetic is yet to be found. Here, using an organic molecular precursor 3,3-dimethyl-1-butene (C_{6}H_{12}) and a comprehensive theoretical study, we have discovered a metastable crystalline carbon phase that is both metallic and ferromagnetic under ambient conditions. The new carbon structures, produced by stacking puckered layers of 4,6-membered rings, are found to exhibit exotic electronic, magnetic, and mechanical properties originating from a special sp^{2}−sp^{3} bonding topology. These findings open the prospect of realizing the metallic and ferromagnetic carbon allotrope in practice.http://doi.org/10.1103/PhysRevResearch.7.013048
spellingShingle Hong Fang
Joel Therrien
Puru Jena
Metallic and ferromagnetic carbon allotrope discovered using molecular precursors
Physical Review Research
title Metallic and ferromagnetic carbon allotrope discovered using molecular precursors
title_full Metallic and ferromagnetic carbon allotrope discovered using molecular precursors
title_fullStr Metallic and ferromagnetic carbon allotrope discovered using molecular precursors
title_full_unstemmed Metallic and ferromagnetic carbon allotrope discovered using molecular precursors
title_short Metallic and ferromagnetic carbon allotrope discovered using molecular precursors
title_sort metallic and ferromagnetic carbon allotrope discovered using molecular precursors
url http://doi.org/10.1103/PhysRevResearch.7.013048
work_keys_str_mv AT hongfang metallicandferromagneticcarbonallotropediscoveredusingmolecularprecursors
AT joeltherrien metallicandferromagneticcarbonallotropediscoveredusingmolecularprecursors
AT purujena metallicandferromagneticcarbonallotropediscoveredusingmolecularprecursors