MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials

Abstract MnO2 nanowires coated with conjugated microporous polymers (CMP) are applied as triboelectric energy harvesting materials. The tribopositive performance of the CMP shells is enhanced with the assistance of MnO2 nanowires (MnO2 NW), likely due to cationic charge transfer from the tribopositi...

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Main Authors: Hanbyeol Jung, Dong‐Min Lee, Jina Park, Taeho Kim, Sang‐Woo Kim, Seung Uk Son
Format: Article
Language:English
Published: Wiley 2024-12-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202409917
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author Hanbyeol Jung
Dong‐Min Lee
Jina Park
Taeho Kim
Sang‐Woo Kim
Seung Uk Son
author_facet Hanbyeol Jung
Dong‐Min Lee
Jina Park
Taeho Kim
Sang‐Woo Kim
Seung Uk Son
author_sort Hanbyeol Jung
collection DOAJ
description Abstract MnO2 nanowires coated with conjugated microporous polymers (CMP) are applied as triboelectric energy harvesting materials. The tribopositive performance of the CMP shells is enhanced with the assistance of MnO2 nanowires (MnO2 NW), likely due to cationic charge transfer from the tribopositive CMP layers to the surface Mn2+ and Mn3+ species of MnO2 NW. This is supported by model studies. The MnO2@CMP‐2 with sub‐10 nm thick CMP layers shows promising triboelectric output voltages up to 576 V and a maximum power density of 1.31 mW cm−2. Spring‐assisted triboelectric nanogenerators fabricated with MnO2@CMP‐2/PVP‐3 films are used as power supplies to operate electronic devices.
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spelling doaj-art-c18b9d155d6e4d0b94a3b1b73476f6fa2025-08-20T02:01:00ZengWileyAdvanced Science2198-38442024-12-011148n/an/a10.1002/advs.202409917MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric MaterialsHanbyeol Jung0Dong‐Min Lee1Jina Park2Taeho Kim3Sang‐Woo Kim4Seung Uk Son5Department of Chemistry Sungkyunkwan University Suwon 16419 South KoreaDepartment of Materials Science and Engineering Yonsei University Seoul 03722 South KoreaDepartment of Chemistry Sungkyunkwan University Suwon 16419 South KoreaDepartment of Chemistry Sungkyunkwan University Suwon 16419 South KoreaDepartment of Materials Science and Engineering Yonsei University Seoul 03722 South KoreaDepartment of Chemistry Sungkyunkwan University Suwon 16419 South KoreaAbstract MnO2 nanowires coated with conjugated microporous polymers (CMP) are applied as triboelectric energy harvesting materials. The tribopositive performance of the CMP shells is enhanced with the assistance of MnO2 nanowires (MnO2 NW), likely due to cationic charge transfer from the tribopositive CMP layers to the surface Mn2+ and Mn3+ species of MnO2 NW. This is supported by model studies. The MnO2@CMP‐2 with sub‐10 nm thick CMP layers shows promising triboelectric output voltages up to 576 V and a maximum power density of 1.31 mW cm−2. Spring‐assisted triboelectric nanogenerators fabricated with MnO2@CMP‐2/PVP‐3 films are used as power supplies to operate electronic devices.https://doi.org/10.1002/advs.202409917conjugated microporous polymermanganese dioxidenanowiretriboelectric materialtriboelectric nanogenerator
spellingShingle Hanbyeol Jung
Dong‐Min Lee
Jina Park
Taeho Kim
Sang‐Woo Kim
Seung Uk Son
MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials
Advanced Science
conjugated microporous polymer
manganese dioxide
nanowire
triboelectric material
triboelectric nanogenerator
title MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials
title_full MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials
title_fullStr MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials
title_full_unstemmed MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials
title_short MnO2 Nanowires with Sub‐10 nm Thick Conjugated Microporous Polymers as Synergistic Triboelectric Materials
title_sort mno2 nanowires with sub 10 nm thick conjugated microporous polymers as synergistic triboelectric materials
topic conjugated microporous polymer
manganese dioxide
nanowire
triboelectric material
triboelectric nanogenerator
url https://doi.org/10.1002/advs.202409917
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AT jinapark mno2nanowireswithsub10nmthickconjugatedmicroporouspolymersassynergistictriboelectricmaterials
AT taehokim mno2nanowireswithsub10nmthickconjugatedmicroporouspolymersassynergistictriboelectricmaterials
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