The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid
The electrodeposition of tin from SnO in ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate ([Bmim]HSO4) in the presence of water at different cathodic potential was investigated. With the addition of water to [Bmim]HSO4 ionic liquid, the electrochemical window of the electrolyte decreases an...
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| Format: | Article |
| Language: | English |
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Wiley
2018-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.1155/2018/1210394 |
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| author | Jie Tang DongLiang Lv CunYing Xu YiXin Hua QiBo Zhang PingZhao Niu XiaoLin Zhu |
| author_facet | Jie Tang DongLiang Lv CunYing Xu YiXin Hua QiBo Zhang PingZhao Niu XiaoLin Zhu |
| author_sort | Jie Tang |
| collection | DOAJ |
| description | The electrodeposition of tin from SnO in ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate ([Bmim]HSO4) in the presence of water at different cathodic potential was investigated. With the addition of water to [Bmim]HSO4 ionic liquid, the electrochemical window of the electrolyte decreases and the reduction potential of Sn(II) positively shifts. The water content of ionic liquid electrolyte has a distinct effect on morphology of the deposits. As water content increased from 0 to 50% (v/v), the morphology of deposits varies from granular to hexagonal rod-like, then to hollow tubular, and finally to wire-like. The XRD phase analysis showed that both Sn and CuSn alloys were deposited in ionic liquid/water mixtures. However, in dried ionic liquids only Cu3Sn was obtained, surprisingly. The difference in the structure might be attributed to the various interactions of the ions with the Cu substrate. In addition, the deposition potential was found to play a significant role in the morphology of deposits. |
| format | Article |
| id | doaj-art-c12c49294aee42ed8f5cfccf5d64b48a |
| institution | OA Journals |
| issn | 2090-3529 2090-3537 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-c12c49294aee42ed8f5cfccf5d64b48a2025-08-20T02:19:23ZengWileyInternational Journal of Electrochemistry2090-35292090-35372018-01-01201810.1155/2018/12103941210394The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic LiquidJie Tang0DongLiang Lv1CunYing Xu2YiXin Hua3QiBo Zhang4PingZhao Niu5XiaoLin Zhu6Department of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaDepartment of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaDepartment of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaDepartment of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaDepartment of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaDepartment of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaDepartment of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaThe electrodeposition of tin from SnO in ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate ([Bmim]HSO4) in the presence of water at different cathodic potential was investigated. With the addition of water to [Bmim]HSO4 ionic liquid, the electrochemical window of the electrolyte decreases and the reduction potential of Sn(II) positively shifts. The water content of ionic liquid electrolyte has a distinct effect on morphology of the deposits. As water content increased from 0 to 50% (v/v), the morphology of deposits varies from granular to hexagonal rod-like, then to hollow tubular, and finally to wire-like. The XRD phase analysis showed that both Sn and CuSn alloys were deposited in ionic liquid/water mixtures. However, in dried ionic liquids only Cu3Sn was obtained, surprisingly. The difference in the structure might be attributed to the various interactions of the ions with the Cu substrate. In addition, the deposition potential was found to play a significant role in the morphology of deposits.http://dx.doi.org/10.1155/2018/1210394 |
| spellingShingle | Jie Tang DongLiang Lv CunYing Xu YiXin Hua QiBo Zhang PingZhao Niu XiaoLin Zhu The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid International Journal of Electrochemistry |
| title | The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid |
| title_full | The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid |
| title_fullStr | The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid |
| title_full_unstemmed | The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid |
| title_short | The Effect of Water on the Tin Electrodeposition from [Bmim]HSO4 Ionic Liquid |
| title_sort | effect of water on the tin electrodeposition from bmim hso4 ionic liquid |
| url | http://dx.doi.org/10.1155/2018/1210394 |
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