Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy

Honeydew honey represents a bee-derived product with different organoleptic characteristics and distinct properties with respect to floral honey. The market interest in honeydew honey has been growing in recent years due to its higher bioactive characteristics with respect to floral honey. The need...

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Main Authors: Dalila Iannone, Laura Ruth Cagliani, Roberto Consonni
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/13/2234
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author Dalila Iannone
Laura Ruth Cagliani
Roberto Consonni
author_facet Dalila Iannone
Laura Ruth Cagliani
Roberto Consonni
author_sort Dalila Iannone
collection DOAJ
description Honeydew honey represents a bee-derived product with different organoleptic characteristics and distinct properties with respect to floral honey. The market interest in honeydew honey has been growing in recent years due to its higher bioactive characteristics with respect to floral honey. The need for a deeper chemical characterization aimed to evaluate a possible botanical differentiation attracted the use of different analytical approaches. The present work aims to distinguish the botanical honeydew origin by using Nuclear Magnetic Resonance (NMR) spectroscopy and a multivariate approach. Two different data pretreatments have been considered to obtain the best sample discrimination. The saccharide content significantly affects the differentiation of the botanical variety consisting of fir, oak, citrus fruits, eucalyptus, and forest mainly by using a classification approach taking advantage of the Orthogonal Signal Correction filters. Notwithstanding the botanical diversity of the honeydew honey (HDH) samples, fir honeydew (F-HDH), oak honeydew (O-HDH), and eucalyptus honeydew (E-HDH) resulted always well discriminated among all the botanical varieties investigated, while citrus fruits honeydew (CF-HD) and forest honeydew (FO-HDH) did not. In particular, F-HDH resulted characterized by sucrose, erlose, maltose, maltotriose, maltotetraose, and melezitose, E-HDH resulted enriched in α, β-glucose and β-fructose in furanosidic form, and O-HDH enriched in β-fructose in furanosidic form, isomaltose.
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spelling doaj-art-c0e2e2a0d5a54974ac6a25a1cc47c5a32025-08-20T03:28:28ZengMDPI AGFoods2304-81582025-06-011413223410.3390/foods14132234Italian Honeydew Honey Characterization by <sup>1</sup>H NMR SpectroscopyDalila Iannone0Laura Ruth Cagliani1Roberto Consonni2Institute of Chemical Sciences and Technologies “G. Natta” (SCITEC), National Research Council, Via Corti 12, 20133 Milan, ItalyInstitute of Chemical Sciences and Technologies “G. Natta” (SCITEC), National Research Council, Via Corti 12, 20133 Milan, ItalyInstitute of Chemical Sciences and Technologies “G. Natta” (SCITEC), National Research Council, Via Corti 12, 20133 Milan, ItalyHoneydew honey represents a bee-derived product with different organoleptic characteristics and distinct properties with respect to floral honey. The market interest in honeydew honey has been growing in recent years due to its higher bioactive characteristics with respect to floral honey. The need for a deeper chemical characterization aimed to evaluate a possible botanical differentiation attracted the use of different analytical approaches. The present work aims to distinguish the botanical honeydew origin by using Nuclear Magnetic Resonance (NMR) spectroscopy and a multivariate approach. Two different data pretreatments have been considered to obtain the best sample discrimination. The saccharide content significantly affects the differentiation of the botanical variety consisting of fir, oak, citrus fruits, eucalyptus, and forest mainly by using a classification approach taking advantage of the Orthogonal Signal Correction filters. Notwithstanding the botanical diversity of the honeydew honey (HDH) samples, fir honeydew (F-HDH), oak honeydew (O-HDH), and eucalyptus honeydew (E-HDH) resulted always well discriminated among all the botanical varieties investigated, while citrus fruits honeydew (CF-HD) and forest honeydew (FO-HDH) did not. In particular, F-HDH resulted characterized by sucrose, erlose, maltose, maltotriose, maltotetraose, and melezitose, E-HDH resulted enriched in α, β-glucose and β-fructose in furanosidic form, and O-HDH enriched in β-fructose in furanosidic form, isomaltose.https://www.mdpi.com/2304-8158/14/13/2234honeydew honeyNMR spectroscopybotanical originmultivariate statistical analysis
spellingShingle Dalila Iannone
Laura Ruth Cagliani
Roberto Consonni
Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy
Foods
honeydew honey
NMR spectroscopy
botanical origin
multivariate statistical analysis
title Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy
title_full Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy
title_fullStr Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy
title_full_unstemmed Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy
title_short Italian Honeydew Honey Characterization by <sup>1</sup>H NMR Spectroscopy
title_sort italian honeydew honey characterization by sup 1 sup h nmr spectroscopy
topic honeydew honey
NMR spectroscopy
botanical origin
multivariate statistical analysis
url https://www.mdpi.com/2304-8158/14/13/2234
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AT lauraruthcagliani italianhoneydewhoneycharacterizationbysup1suphnmrspectroscopy
AT robertoconsonni italianhoneydewhoneycharacterizationbysup1suphnmrspectroscopy