Reduction of CO2 and Related Compounds with a Low‐Valent CaI Synthon
The reduction of CO2 with low‐valent s‐block metal complexes is limited to MgI reducing agents. Herein, the reduction of a series of CX2 reagents (X = O, S, NiPr) with the CaI synthon [(BDI)Ca(THP)]2(N2) (VI) is described, which is a CaII complex that reacts like the hypothetical CaI complex (BDI)Ca...
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| Main Authors: | Stefan Thum, Jonathan Mai, Neha Patel, Jens Langer, Sjoerd Harder |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley-VCH
2025-07-01
|
| Series: | ChemistryEurope |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/ceur.202500080 |
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