Reduction of CO2 and Related Compounds with a Low‐Valent CaI Synthon

The reduction of CO2 with low‐valent s‐block metal complexes is limited to MgI reducing agents. Herein, the reduction of a series of CX2 reagents (X = O, S, NiPr) with the CaI synthon [(BDI)Ca(THP)]2(N2) (VI) is described, which is a CaII complex that reacts like the hypothetical CaI complex (BDI)Ca...

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Bibliographic Details
Main Authors: Stefan Thum, Jonathan Mai, Neha Patel, Jens Langer, Sjoerd Harder
Format: Article
Language:English
Published: Wiley-VCH 2025-07-01
Series:ChemistryEurope
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Online Access:https://doi.org/10.1002/ceur.202500080
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