Solvatochromie Shifts and Polarity of Solvent Mixtures
The local polarity of solvent mixtures near a polar solute molecule can be very different from the mixture’s bulk polarity. A general mechanism which determines the local polarity is the “dielectric enrichment” which is described by the thermodynamic equilibrium in a solvent shell enriched in polar...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1982-09-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9567 |
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