Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate
The new organic 3,4-diaminobenzophenone semihydrate (34ABPH) is grown by slow evaporation method. The compound crystallizes in the monoclinic space group: C2. The unit cell dimensions are (8) Å, (2) Å, (10) Å, and β = 99.40 (2)° with . The crystal structure analysis reveals that the C13H12N2O mol...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/871395 |
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| author | Tarek Ben Rhaiem Habib Boughzala Ahmed Driss |
| author_facet | Tarek Ben Rhaiem Habib Boughzala Ahmed Driss |
| author_sort | Tarek Ben Rhaiem |
| collection | DOAJ |
| description | The new organic 3,4-diaminobenzophenone semihydrate (34ABPH) is grown by slow evaporation method. The compound crystallizes in the monoclinic space group: C2. The unit cell dimensions are (8) Å, (2) Å, (10) Å, and β = 99.40 (2)° with . The crystal structure analysis reveals that the C13H12N2O molecules chains are organized into a double ribbon in the (b,c) plane. The structural components interact by N–H⋯O and O–H⋯O hydrogen bonds, building up a two-dimensional network. The presence of functional groups in the molecular structure is confirmed by the Fourier transform infrared (FT-IR) spectroscopy. Thermogravimetric analysis (TGA) confirms the presence of the water molecule. |
| format | Article |
| id | doaj-art-c044171bfbc6433eae42fd2570edaaf5 |
| institution | DOAJ |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-c044171bfbc6433eae42fd2570edaaf52025-08-20T03:23:23ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/871395871395Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone SemihydrateTarek Ben Rhaiem0Habib Boughzala1Ahmed Driss2Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Tunis, TunisiaLaboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Tunis, TunisiaLaboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Tunis, TunisiaThe new organic 3,4-diaminobenzophenone semihydrate (34ABPH) is grown by slow evaporation method. The compound crystallizes in the monoclinic space group: C2. The unit cell dimensions are (8) Å, (2) Å, (10) Å, and β = 99.40 (2)° with . The crystal structure analysis reveals that the C13H12N2O molecules chains are organized into a double ribbon in the (b,c) plane. The structural components interact by N–H⋯O and O–H⋯O hydrogen bonds, building up a two-dimensional network. The presence of functional groups in the molecular structure is confirmed by the Fourier transform infrared (FT-IR) spectroscopy. Thermogravimetric analysis (TGA) confirms the presence of the water molecule.http://dx.doi.org/10.1155/2013/871395 |
| spellingShingle | Tarek Ben Rhaiem Habib Boughzala Ahmed Driss Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate Journal of Chemistry |
| title | Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate |
| title_full | Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate |
| title_fullStr | Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate |
| title_full_unstemmed | Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate |
| title_short | Synthesis, Crystal Structure, and Comparative Study of a New Organic Material 3,4-Diaminobenzophenone Semihydrate |
| title_sort | synthesis crystal structure and comparative study of a new organic material 3 4 diaminobenzophenone semihydrate |
| url | http://dx.doi.org/10.1155/2013/871395 |
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