Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau

Abstract As a highly volatile heavy metal, Hg is transported over long distances in the atmosphere and enters global ecosystems via Hg(II) wet deposition and Hg(0) dry deposition. The Chinese Loess Plateau develops loess‐paleosol sequences (eolian deposits) reflecting glacial‐interglacial cycles. He...

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Main Authors: Wen Xue, Zhidong Xu, Xing Cheng, Longfei Gou, Maoyong He, Zhangdong Jin, Miling Li, Linchuan Fang, Runsheng Yin
Format: Article
Language:English
Published: Wiley 2025-04-01
Series:Geophysical Research Letters
Online Access:https://doi.org/10.1029/2024GL113960
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author Wen Xue
Zhidong Xu
Xing Cheng
Longfei Gou
Maoyong He
Zhangdong Jin
Miling Li
Linchuan Fang
Runsheng Yin
author_facet Wen Xue
Zhidong Xu
Xing Cheng
Longfei Gou
Maoyong He
Zhangdong Jin
Miling Li
Linchuan Fang
Runsheng Yin
author_sort Wen Xue
collection DOAJ
description Abstract As a highly volatile heavy metal, Hg is transported over long distances in the atmosphere and enters global ecosystems via Hg(II) wet deposition and Hg(0) dry deposition. The Chinese Loess Plateau develops loess‐paleosol sequences (eolian deposits) reflecting glacial‐interglacial cycles. Here, we investigate the Hg concentration and isotopic composition of loess‐paleosol sequences covering three glacial‐interglacial cycles (spanning 350–80 ka). Paleosol layers display higher THg, Δ199Hg, and Δ200Hg values than loess layers, meaning enhanced Hg(II) wet deposition during interglacials. Based on a Δ200Hg‐based mixing model, Hg(II) wet and Hg(0) dry depositions account for 42% and 58% of Hg input into the Chinese Loess Plateau during interglacials but 21% and 79% during glacials, respectively. This work highlights a strong climatic control on atmospheric Hg deposition at glacial‐interglacial time scales, and suggests that atmospheric Hg deposition will likely increase in middle latitudes without considering perturbations of anthropogenic emissions.
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institution OA Journals
issn 0094-8276
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language English
publishDate 2025-04-01
publisher Wiley
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series Geophysical Research Letters
spelling doaj-art-c0375bdcd6f944d28848731529e09e662025-08-20T02:30:59ZengWileyGeophysical Research Letters0094-82761944-80072025-04-01527n/an/a10.1029/2024GL113960Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess PlateauWen Xue0Zhidong Xu1Xing Cheng2Longfei Gou3Maoyong He4Zhangdong Jin5Miling Li6Linchuan Fang7Runsheng Yin8State Key Laboratory of Ore Deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang ChinaState Key Laboratory of Environmental Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang ChinaShaanxi Experimental Center of Geological Survey Shaanxi Institute of Geological Survey Xi'an ChinaState Key Laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi'an ChinaState Key Laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi'an ChinaState Key Laboratory of Loess and Quaternary Geology Institute of Earth Environment Chinese Academy of Sciences Xi'an ChinaSchool of Marine Science and Policy University of Delaware Newark DE USACollege of Natural Resources and Environment Northwest A&F University Yangling ChinaState Key Laboratory of Ore Deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang ChinaAbstract As a highly volatile heavy metal, Hg is transported over long distances in the atmosphere and enters global ecosystems via Hg(II) wet deposition and Hg(0) dry deposition. The Chinese Loess Plateau develops loess‐paleosol sequences (eolian deposits) reflecting glacial‐interglacial cycles. Here, we investigate the Hg concentration and isotopic composition of loess‐paleosol sequences covering three glacial‐interglacial cycles (spanning 350–80 ka). Paleosol layers display higher THg, Δ199Hg, and Δ200Hg values than loess layers, meaning enhanced Hg(II) wet deposition during interglacials. Based on a Δ200Hg‐based mixing model, Hg(II) wet and Hg(0) dry depositions account for 42% and 58% of Hg input into the Chinese Loess Plateau during interglacials but 21% and 79% during glacials, respectively. This work highlights a strong climatic control on atmospheric Hg deposition at glacial‐interglacial time scales, and suggests that atmospheric Hg deposition will likely increase in middle latitudes without considering perturbations of anthropogenic emissions.https://doi.org/10.1029/2024GL113960
spellingShingle Wen Xue
Zhidong Xu
Xing Cheng
Longfei Gou
Maoyong He
Zhangdong Jin
Miling Li
Linchuan Fang
Runsheng Yin
Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau
Geophysical Research Letters
title Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau
title_full Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau
title_fullStr Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau
title_full_unstemmed Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau
title_short Glacial‐Interglacial Climate Cycles of Atmospheric Hg Deposition: Insights From Hg Isotopes in Loess‐Paleosol Sequences on the Chinese Loess Plateau
title_sort glacial interglacial climate cycles of atmospheric hg deposition insights from hg isotopes in loess paleosol sequences on the chinese loess plateau
url https://doi.org/10.1029/2024GL113960
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