Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites

Poly(lactic acid) was filled with 20 wt% of the three mineral fillers Mica, Zeolite, and Vansil, differing in the particle shape and surface area. Viscoelastic properties of unfilled and filled composites were investigated via dynamic mechanical analysis, while filler and fracture surface morphology...

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Main Authors: Adriana Gregorova, Michal Machovsky, Rupert Wimmer
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2012/252981
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author Adriana Gregorova
Michal Machovsky
Rupert Wimmer
author_facet Adriana Gregorova
Michal Machovsky
Rupert Wimmer
author_sort Adriana Gregorova
collection DOAJ
description Poly(lactic acid) was filled with 20 wt% of the three mineral fillers Mica, Zeolite, and Vansil, differing in the particle shape and surface area. Viscoelastic properties of unfilled and filled composites were investigated via dynamic mechanical analysis, while filler and fracture surface morphology of the composites was analysed through scanning electron microscopy. Results demonstrate the relationships between viscoelastic damping behaviour of filled PLA composites and the filler distribution in the PLA matrix. Both damping reduction and scanning electron microscope analysis revealed that Zeolite was better distributed in the poly(lactic acid) matrix than the other used fillers Mica and Vansil. The interfacial filler/matrix adhesion has again proved to be the key factor determining thermal and mechanical properties of reinforced composite material.
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publishDate 2012-01-01
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series International Journal of Polymer Science
spelling doaj-art-bfe73ba179e6468fad1de6ae3c8ecf392025-08-20T02:19:27ZengWileyInternational Journal of Polymer Science1687-94221687-94302012-01-01201210.1155/2012/252981252981Viscoelastic Properties of Mineral-Filled Poly(lactic acid) CompositesAdriana Gregorova0Michal Machovsky1Rupert Wimmer2Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, AustriaPolymer Centre, Faculty of Technology, Tomas Bata University in Zlin, 76272 Zlin, Czech RepublicInstitute for Wood Technology and Renewable Materials, University of Natural Resources and Life Sciences, Vienna, Konrad Lorenz-Strasse 24, 3430 Tulln, AustriaPoly(lactic acid) was filled with 20 wt% of the three mineral fillers Mica, Zeolite, and Vansil, differing in the particle shape and surface area. Viscoelastic properties of unfilled and filled composites were investigated via dynamic mechanical analysis, while filler and fracture surface morphology of the composites was analysed through scanning electron microscopy. Results demonstrate the relationships between viscoelastic damping behaviour of filled PLA composites and the filler distribution in the PLA matrix. Both damping reduction and scanning electron microscope analysis revealed that Zeolite was better distributed in the poly(lactic acid) matrix than the other used fillers Mica and Vansil. The interfacial filler/matrix adhesion has again proved to be the key factor determining thermal and mechanical properties of reinforced composite material.http://dx.doi.org/10.1155/2012/252981
spellingShingle Adriana Gregorova
Michal Machovsky
Rupert Wimmer
Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites
International Journal of Polymer Science
title Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites
title_full Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites
title_fullStr Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites
title_full_unstemmed Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites
title_short Viscoelastic Properties of Mineral-Filled Poly(lactic acid) Composites
title_sort viscoelastic properties of mineral filled poly lactic acid composites
url http://dx.doi.org/10.1155/2012/252981
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AT rupertwimmer viscoelasticpropertiesofmineralfilledpolylacticacidcomposites