Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts
The electrochemistry of Sn(II) was investigated with cyclic voltammetry and chronoamperometry in the 1-ethyl-3-methylimidazolium tetrafluoroborate molten salt containing free chloride ions (EMI ⋅BF4 ⋅Cl) originated from the mixture of EMIC and NaBF4 (60:40 mol%). The well defined redox waves for the...
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| Format: | Article |
| Language: | English |
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University of Belgrade, Technical Faculty, Bor
2003-01-01
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| Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302059M.pdf |
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| author | Morimitsu M. Nakahara Y. Iwaki Y. Matsunaga M. |
| author_facet | Morimitsu M. Nakahara Y. Iwaki Y. Matsunaga M. |
| author_sort | Morimitsu M. |
| collection | DOAJ |
| description | The electrochemistry of Sn(II) was investigated with cyclic voltammetry and chronoamperometry in the 1-ethyl-3-methylimidazolium tetrafluoroborate molten salt containing free chloride ions (EMI ⋅BF4 ⋅Cl) originated from the mixture of EMIC and NaBF4 (60:40 mol%). The well defined redox waves for the electro deposition and dissolution of tin were observed on a platinum electrode at 303 K. The deposition of tin proceeded through a quasi-reversible step with two electron transfer, and the deposited tin was sufficiently recovered during oxidation. The experimental current-time transient coincided with the theory based on one-dimensional diffusion control. |
| format | Article |
| id | doaj-art-bfd14a6817b84ed88d8fefaaf2e7449a |
| institution | Kabale University |
| issn | 1450-5339 |
| language | English |
| publishDate | 2003-01-01 |
| publisher | University of Belgrade, Technical Faculty, Bor |
| record_format | Article |
| series | Journal of Mining and Metallurgy. Section B: Metallurgy |
| spelling | doaj-art-bfd14a6817b84ed88d8fefaaf2e7449a2025-02-02T15:45:28ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392003-01-01391-2596710.2298/JMMB0302059MElectrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten saltsMorimitsu M.Nakahara Y.Iwaki Y.Matsunaga M.The electrochemistry of Sn(II) was investigated with cyclic voltammetry and chronoamperometry in the 1-ethyl-3-methylimidazolium tetrafluoroborate molten salt containing free chloride ions (EMI ⋅BF4 ⋅Cl) originated from the mixture of EMIC and NaBF4 (60:40 mol%). The well defined redox waves for the electro deposition and dissolution of tin were observed on a platinum electrode at 303 K. The deposition of tin proceeded through a quasi-reversible step with two electron transfer, and the deposited tin was sufficiently recovered during oxidation. The experimental current-time transient coincided with the theory based on one-dimensional diffusion control.http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302059M.pdfelectrodepositionSncyclic voltammetrymolten salts |
| spellingShingle | Morimitsu M. Nakahara Y. Iwaki Y. Matsunaga M. Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts Journal of Mining and Metallurgy. Section B: Metallurgy electrodeposition Sn cyclic voltammetry molten salts |
| title | Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts |
| title_full | Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts |
| title_fullStr | Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts |
| title_full_unstemmed | Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts |
| title_short | Electrodeposition of tin from EMI⋅BF4⋅Cl room temperature molten salts |
| title_sort | electrodeposition of tin from emi⋅bf4⋅cl room temperature molten salts |
| topic | electrodeposition Sn cyclic voltammetry molten salts |
| url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302059M.pdf |
| work_keys_str_mv | AT morimitsum electrodepositionoftinfromemibf4clroomtemperaturemoltensalts AT nakaharay electrodepositionoftinfromemibf4clroomtemperaturemoltensalts AT iwakiy electrodepositionoftinfromemibf4clroomtemperaturemoltensalts AT matsunagam electrodepositionoftinfromemibf4clroomtemperaturemoltensalts |