Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules

Interfacial properties significantly influence emulsifying and foaming stability. We here explore the interfacial behavior of egg yolk granules (EYGs) combined with various Span emulsifiers (Span 20, 40, 60, 80) to assess their solution properties, interface dynamics, and effects on emulsifying and...

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Main Authors: Wenyan Liu, Jingxia Cao, Qixin Zhang, Weiqin Wang, Yuanping Ye, Senwang Zhang, Leiyan Wu
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/1/35
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author Wenyan Liu
Jingxia Cao
Qixin Zhang
Weiqin Wang
Yuanping Ye
Senwang Zhang
Leiyan Wu
author_facet Wenyan Liu
Jingxia Cao
Qixin Zhang
Weiqin Wang
Yuanping Ye
Senwang Zhang
Leiyan Wu
author_sort Wenyan Liu
collection DOAJ
description Interfacial properties significantly influence emulsifying and foaming stability. We here explore the interfacial behavior of egg yolk granules (EYGs) combined with various Span emulsifiers (Span 20, 40, 60, 80) to assess their solution properties, interface dynamics, and effects on emulsifying and foaming stability. The results unveiled that as the Span concentration increased, particle size decreased from 7028 to 1200 nm, absolute zeta potential increased from 4.86 to 9.26 mv, and the structure became increasingly loosened. This loose structure of EYGs-Span complexes resulted in reduced interfacial tension (γ), higher adsorption rate (Kd), and improved interfacial composite modulus (E) compared with native EYGs. These effects were more pronounced with shorter hydrophobic chain Spans but diminished with longer chain lengths. Enhanced interfacial properties contributed to better emulsification and foaming stability, with EYGs-Span complexes displaying increased emulsifying ability and stability compared with natural EYGs. Emulsifying and foaming stability improved in the order of Span 20 > Span 40 > Span 60 > Span 80 as the Span concentration increased. The correlation analysis (<i>p</i> > 0.05) indicated that emulsifying stability was positively associated with interfacial composite modulus and negatively correlated with particle size. Consequently, EYGs-Span composites demonstrate considerable potential for use as effective emulsifiers in food industry applications.
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spelling doaj-art-bfc17bdafe1249d195e6fa226032d82a2025-01-10T13:17:35ZengMDPI AGFoods2304-81582024-12-011413510.3390/foods14010035Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk GranulesWenyan Liu0Jingxia Cao1Qixin Zhang2Weiqin Wang3Yuanping Ye4Senwang Zhang5Leiyan Wu6College of Food Science and Engineering, Jiangxi Agricultural University, Nanchang 330045, ChinaCollege of Food Science and Engineering, Jiangxi Agricultural University, Nanchang 330045, ChinaCollege of Food Science and Engineering, Jiangxi Agricultural University, Nanchang 330045, ChinaJiangxi Riyuan Food Co., Shangrao 334604, ChinaJiangxi Riyuan Food Co., Shangrao 334604, ChinaInstitute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang 330096, ChinaCollege of Food Science and Engineering, Jiangxi Agricultural University, Nanchang 330045, ChinaInterfacial properties significantly influence emulsifying and foaming stability. We here explore the interfacial behavior of egg yolk granules (EYGs) combined with various Span emulsifiers (Span 20, 40, 60, 80) to assess their solution properties, interface dynamics, and effects on emulsifying and foaming stability. The results unveiled that as the Span concentration increased, particle size decreased from 7028 to 1200 nm, absolute zeta potential increased from 4.86 to 9.26 mv, and the structure became increasingly loosened. This loose structure of EYGs-Span complexes resulted in reduced interfacial tension (γ), higher adsorption rate (Kd), and improved interfacial composite modulus (E) compared with native EYGs. These effects were more pronounced with shorter hydrophobic chain Spans but diminished with longer chain lengths. Enhanced interfacial properties contributed to better emulsification and foaming stability, with EYGs-Span complexes displaying increased emulsifying ability and stability compared with natural EYGs. Emulsifying and foaming stability improved in the order of Span 20 > Span 40 > Span 60 > Span 80 as the Span concentration increased. The correlation analysis (<i>p</i> > 0.05) indicated that emulsifying stability was positively associated with interfacial composite modulus and negatively correlated with particle size. Consequently, EYGs-Span composites demonstrate considerable potential for use as effective emulsifiers in food industry applications.https://www.mdpi.com/2304-8158/14/1/35egg yolk granulesspanprotein structural modificationsinterfacial propertiesemulsifying agentsfoaming stability
spellingShingle Wenyan Liu
Jingxia Cao
Qixin Zhang
Weiqin Wang
Yuanping Ye
Senwang Zhang
Leiyan Wu
Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules
Foods
egg yolk granules
span
protein structural modifications
interfacial properties
emulsifying agents
foaming stability
title Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules
title_full Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules
title_fullStr Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules
title_full_unstemmed Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules
title_short Interfacial Properties and Structure of Emulsions and Foams Co-Stabilized by Span Emulsifiers of Varying Carbon Chain Lengths and Egg Yolk Granules
title_sort interfacial properties and structure of emulsions and foams co stabilized by span emulsifiers of varying carbon chain lengths and egg yolk granules
topic egg yolk granules
span
protein structural modifications
interfacial properties
emulsifying agents
foaming stability
url https://www.mdpi.com/2304-8158/14/1/35
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