Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion

Polysubstituted pyrroles have been synthesized in good yields via a four-component one-pot reaction of 1,3-dicarbonyl compounds, amines, aldehydes, and nitroalkanes using natural hydroxyapatite (HAp) as an efficient green catalyst. This strategy provides advantages such as simple experimental and wo...

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Main Authors: Abdelhadi Louroubi, Abdallah Nayad, Ali Hasnaoui, Rachid Idouhli, Abdessalam Abouelfida, Larbi El Firdoussi, Mustapha Ait Ali
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2021/6613243
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author Abdelhadi Louroubi
Abdallah Nayad
Ali Hasnaoui
Rachid Idouhli
Abdessalam Abouelfida
Larbi El Firdoussi
Mustapha Ait Ali
author_facet Abdelhadi Louroubi
Abdallah Nayad
Ali Hasnaoui
Rachid Idouhli
Abdessalam Abouelfida
Larbi El Firdoussi
Mustapha Ait Ali
author_sort Abdelhadi Louroubi
collection DOAJ
description Polysubstituted pyrroles have been synthesized in good yields via a four-component one-pot reaction of 1,3-dicarbonyl compounds, amines, aldehydes, and nitroalkanes using natural hydroxyapatite (HAp) as an efficient green catalyst. This strategy provides advantages such as simple experimental and work-up procedures, mild conditions, high selectivity, low cost, high atom economy, and environmental friendliness; it uses a green commercial catalyst and does not require a solvent. The electrochemical behavior of S300 steel in 1 M hydrochloric acidic was studied in the presence of these heterocyclic compounds. The results showed good inhibition efficiency for steel in acidic media.
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issn 2090-9063
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publishDate 2021-01-01
publisher Wiley
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series Journal of Chemistry
spelling doaj-art-bf6d7df021984d1b8639a79b1fae7b5c2025-08-20T02:18:59ZengWileyJournal of Chemistry2090-90632090-90712021-01-01202110.1155/2021/66132436613243Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of CorrosionAbdelhadi Louroubi0Abdallah Nayad1Ali Hasnaoui2Rachid Idouhli3Abdessalam Abouelfida4Larbi El Firdoussi5Mustapha Ait Ali6Molecular Chemistry Laboratory, Coordination Chemistry and Catalyse Unit, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoMolecular Chemistry Laboratory, Coordination Chemistry and Catalyse Unit, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoMolecular Chemistry Laboratory, Coordination Chemistry and Catalyse Unit, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoPhysical-Chemistry of Materials and Environment Laboratory, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoPhysical-Chemistry of Materials and Environment Laboratory, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoMolecular Chemistry Laboratory, Coordination Chemistry and Catalyse Unit, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoMolecular Chemistry Laboratory, Coordination Chemistry and Catalyse Unit, Faculty of Sciences Semlalia, Cadi Ayyad University, Marrakech, MoroccoPolysubstituted pyrroles have been synthesized in good yields via a four-component one-pot reaction of 1,3-dicarbonyl compounds, amines, aldehydes, and nitroalkanes using natural hydroxyapatite (HAp) as an efficient green catalyst. This strategy provides advantages such as simple experimental and work-up procedures, mild conditions, high selectivity, low cost, high atom economy, and environmental friendliness; it uses a green commercial catalyst and does not require a solvent. The electrochemical behavior of S300 steel in 1 M hydrochloric acidic was studied in the presence of these heterocyclic compounds. The results showed good inhibition efficiency for steel in acidic media.http://dx.doi.org/10.1155/2021/6613243
spellingShingle Abdelhadi Louroubi
Abdallah Nayad
Ali Hasnaoui
Rachid Idouhli
Abdessalam Abouelfida
Larbi El Firdoussi
Mustapha Ait Ali
Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion
Journal of Chemistry
title Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion
title_full Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion
title_fullStr Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion
title_full_unstemmed Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion
title_short Natural Hydroxyapatite: Green Catalyst for the Synthesis of Pyrroles, Inhibitors of Corrosion
title_sort natural hydroxyapatite green catalyst for the synthesis of pyrroles inhibitors of corrosion
url http://dx.doi.org/10.1155/2021/6613243
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