A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method

In this study, a phase-field model was developed to simulate quantitatively, for the first time, the precipitation process of the Cu-rich phase at grain boundaries in polycrystalline Fe–Cu alloys with different Cu contents at different aging temperatures. The results showed that, with increasing seg...

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Main Authors: Mingguang Wei, Tongguang Zhai, Kang Wang
Format: Article
Language:English
Published: Elsevier 2024-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424029065
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author Mingguang Wei
Tongguang Zhai
Kang Wang
author_facet Mingguang Wei
Tongguang Zhai
Kang Wang
author_sort Mingguang Wei
collection DOAJ
description In this study, a phase-field model was developed to simulate quantitatively, for the first time, the precipitation process of the Cu-rich phase at grain boundaries in polycrystalline Fe–Cu alloys with different Cu contents at different aging temperatures. The results showed that, with increasing segregation of Cu atoms at grain boundaries, the incubation time of the Cu-rich phase was decreased, and the number density of the Cu precipitates increases at the boundaries but decreases within grains. With lower initial Cu content or at a higher temperature, a relatively small number of Cu precipitates could preferentially be formed at grain boundaries through a nucleation-growth mechanism. With increasing the initial Cu content or decreasing temperature, precipitation of the Cu-rich phase occurred by a pseudo-spinodal decomposition, resulting in formation of the Cu precipitates in a large number at grain boundaries and inside grains over a shorter period. This work paved the way to applying the phase-field modeling technique to further quantify the precipitation behaviors of Cu-rich phase in polycrystalline Fe–Cu alloys.
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spelling doaj-art-bf4ec8b5cbec49d5b1e7a11824fdef1d2025-08-20T01:57:20ZengElsevierJournal of Materials Research and Technology2238-78542024-11-01338983899110.1016/j.jmrt.2024.12.103A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field methodMingguang Wei0Tongguang Zhai1Kang Wang2School of Materials Science and Engineering, Shandong Jianzhu University, Jinan, 250101, China; School of Physics Science and Technology, Guangxi University, Nanning, 530004, ChinaSchool of Materials Science and Engineering, Shandong Jianzhu University, Jinan, 250101, China; Corresponding author.School of Materials Science and Engineering, Dongguan University of Technology, Dongguan, 523808, ChinaIn this study, a phase-field model was developed to simulate quantitatively, for the first time, the precipitation process of the Cu-rich phase at grain boundaries in polycrystalline Fe–Cu alloys with different Cu contents at different aging temperatures. The results showed that, with increasing segregation of Cu atoms at grain boundaries, the incubation time of the Cu-rich phase was decreased, and the number density of the Cu precipitates increases at the boundaries but decreases within grains. With lower initial Cu content or at a higher temperature, a relatively small number of Cu precipitates could preferentially be formed at grain boundaries through a nucleation-growth mechanism. With increasing the initial Cu content or decreasing temperature, precipitation of the Cu-rich phase occurred by a pseudo-spinodal decomposition, resulting in formation of the Cu precipitates in a large number at grain boundaries and inside grains over a shorter period. This work paved the way to applying the phase-field modeling technique to further quantify the precipitation behaviors of Cu-rich phase in polycrystalline Fe–Cu alloys.http://www.sciencedirect.com/science/article/pii/S2238785424029065Fe-Cu alloysCu-rich phaseGrain boundaryPhase-field method
spellingShingle Mingguang Wei
Tongguang Zhai
Kang Wang
A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method
Journal of Materials Research and Technology
Fe-Cu alloys
Cu-rich phase
Grain boundary
Phase-field method
title A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method
title_full A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method
title_fullStr A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method
title_full_unstemmed A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method
title_short A study of grain boundary precipitation of nano-scale Cu-rich phase in polycrystalline Fe–Cu binary alloys using a phase-field method
title_sort study of grain boundary precipitation of nano scale cu rich phase in polycrystalline fe cu binary alloys using a phase field method
topic Fe-Cu alloys
Cu-rich phase
Grain boundary
Phase-field method
url http://www.sciencedirect.com/science/article/pii/S2238785424029065
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