Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands
The reaction of Co(NO3)2.6H2O and Ni(NO3)2.6H2O with hydrazones derived from 1-phenyl-3-methyl-4-acyl-5-pyrazolone (where acyl = acetyl, propionyl, butyryl and benzoyl) with 2-picolinic acid hydrazide have been studied and characterized on the basis of elemental analysis, magnetic moments, molar con...
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| Format: | Article |
| Language: | English |
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Wiley
2005-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2005/608974 |
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| author | Chetan K. Modi Ashwin S. Patel Bharat T. Thaker |
| author_facet | Chetan K. Modi Ashwin S. Patel Bharat T. Thaker |
| author_sort | Chetan K. Modi |
| collection | DOAJ |
| description | The reaction of Co(NO3)2.6H2O and Ni(NO3)2.6H2O with hydrazones derived from 1-phenyl-3-methyl-4-acyl-5-pyrazolone (where acyl = acetyl, propionyl, butyryl and benzoyl) with 2-picolinic acid hydrazide have been studied and characterized on the basis of elemental analysis, magnetic moments, molar conductivity measurements, IR and electronic spectral studies and thermogravimetric analysis. Various ligand field parameters have been calculated. Electronic spectral data and the magnetic moment values suggest an octahedral structure for all cobalt(II) and nickel(II) complexes. |
| format | Article |
| id | doaj-art-bf43dfc7ebb8453bbae48226d6b51a30 |
| institution | OA Journals |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2005-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-bf43dfc7ebb8453bbae48226d6b51a302025-08-20T02:18:58ZengWileyE-Journal of Chemistry0973-49452090-98102005-01-0121212910.1155/2005/608974Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone LigandsChetan K. Modi0Ashwin S. Patel1Bharat T. Thaker2Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar 388 120, IndiaDepartment of Chemistry, Navyug Science College, Rander Road, Surat 395 009, IndiaDepartment of Chemistry, Veer Narmad South Gujarat University, Surat 395 007, IndiaThe reaction of Co(NO3)2.6H2O and Ni(NO3)2.6H2O with hydrazones derived from 1-phenyl-3-methyl-4-acyl-5-pyrazolone (where acyl = acetyl, propionyl, butyryl and benzoyl) with 2-picolinic acid hydrazide have been studied and characterized on the basis of elemental analysis, magnetic moments, molar conductivity measurements, IR and electronic spectral studies and thermogravimetric analysis. Various ligand field parameters have been calculated. Electronic spectral data and the magnetic moment values suggest an octahedral structure for all cobalt(II) and nickel(II) complexes.http://dx.doi.org/10.1155/2005/608974 |
| spellingShingle | Chetan K. Modi Ashwin S. Patel Bharat T. Thaker Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands E-Journal of Chemistry |
| title | Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands |
| title_full | Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands |
| title_fullStr | Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands |
| title_full_unstemmed | Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands |
| title_short | Synthesis, Spectral, Magnetic and Thermal Studies of the Complexes of CoII and NiII With Some Bidentate and Tridentate Hydrazone Ligands |
| title_sort | synthesis spectral magnetic and thermal studies of the complexes of coii and niii with some bidentate and tridentate hydrazone ligands |
| url | http://dx.doi.org/10.1155/2005/608974 |
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