Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms
With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-a...
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| Format: | Article |
| Language: | English |
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Kazan State Power Engineering University
2019-06-01
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| Series: | Известия высших учебных заведений: Проблемы энергетики |
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| Online Access: | https://www.energyret.ru/jour/article/view/916 |
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| author | L. R. Gaynullina V. P. Tutubalina |
| author_facet | L. R. Gaynullina V. P. Tutubalina |
| author_sort | L. R. Gaynullina |
| collection | DOAJ |
| description | With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-arny ratio 1:1 at a temperature of 80 °C proceeds before formation of a dibutilsulfoksid, and at a ratio 1:2 and at a temperature of 100 °C – to a dibutilsulfon.The increase in amount of hydrogen peroxide and temperature is followed by for-mation of sour products – the sulfoniyevykh and sulfonew acids.By method of a gas-liquid chromatography it is proved that during oxidation of dibutylsulfide by hydrogen peroxide his destruction doesn't happen. |
| format | Article |
| id | doaj-art-bf07a0fb04644c0699d824f9d5015fe0 |
| institution | OA Journals |
| issn | 1998-9903 |
| language | English |
| publishDate | 2019-06-01 |
| publisher | Kazan State Power Engineering University |
| record_format | Article |
| series | Известия высших учебных заведений: Проблемы энергетики |
| spelling | doaj-art-bf07a0fb04644c0699d824f9d5015fe02025-08-20T02:24:04ZengKazan State Power Engineering UniversityИзвестия высших учебных заведений: Проблемы энергетики1998-99032019-06-01213-43610.30724/1998-9903-2019-21-3-4-3-6567Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermogramsL. R. Gaynullina0V. P. Tutubalina1Kazan State Power Engineering UniversityKazan State Power Engineering UniversityWith the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-arny ratio 1:1 at a temperature of 80 °C proceeds before formation of a dibutilsulfoksid, and at a ratio 1:2 and at a temperature of 100 °C – to a dibutilsulfon.The increase in amount of hydrogen peroxide and temperature is followed by for-mation of sour products – the sulfoniyevykh and sulfonew acids.By method of a gas-liquid chromatography it is proved that during oxidation of dibutylsulfide by hydrogen peroxide his destruction doesn't happen.https://www.energyret.ru/jour/article/view/916transformer oildibutylsulfideoxidationhydrogen peroxidethermogram |
| spellingShingle | L. R. Gaynullina V. P. Tutubalina Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms Известия высших учебных заведений: Проблемы энергетики transformer oil dibutylsulfide oxidation hydrogen peroxide thermogram |
| title | Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
| title_full | Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
| title_fullStr | Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
| title_full_unstemmed | Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
| title_short | Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
| title_sort | dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
| topic | transformer oil dibutylsulfide oxidation hydrogen peroxide thermogram |
| url | https://www.energyret.ru/jour/article/view/916 |
| work_keys_str_mv | AT lrgaynullina dibutylsulfideoxidationresearchtheconcentratedhydrogenperoxidesolutionbymeansofthermograms AT vptutubalina dibutylsulfideoxidationresearchtheconcentratedhydrogenperoxidesolutionbymeansofthermograms |