A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures

Alkali-activated materials (AAMs) are promoted as a sustainable alternative to ordinary Portland cement (OPC). They not only have excellent resistance to high temperatures and chemical corrosion, but they can also help to reduce greenhouse gas emissions and reduce energy consumption. Despite their s...

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Main Authors: Ting Wu, Si Tang, Yao-Rong Dong, Jiang-Hua Luo
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Buildings
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Online Access:https://www.mdpi.com/2075-5309/15/5/738
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author Ting Wu
Si Tang
Yao-Rong Dong
Jiang-Hua Luo
author_facet Ting Wu
Si Tang
Yao-Rong Dong
Jiang-Hua Luo
author_sort Ting Wu
collection DOAJ
description Alkali-activated materials (AAMs) are promoted as a sustainable alternative to ordinary Portland cement (OPC). They not only have excellent resistance to high temperatures and chemical corrosion, but they can also help to reduce greenhouse gas emissions and reduce energy consumption. Despite their superior resistance to high temperatures compared to conventional cement-based concretes, studies have indicated that AAMs still face challenges related to performance degradation under elevated temperatures. This paper systematically reviews and summarizes the thermal properties (i.e., thermal expansion, thermal stability, and thermal conductivity), mechanical performance, and deterioration mechanisms of various alkali-activated composite systems. The findings reveal significant variability in resistance to high temperatures among different AAM systems, originating from the diversity of precursor materials used. Generally, the strength deterioration of various AAMs below 400 °C is minimal or even slightly increased, while between 600 °C and 800 °C, the strength degradation is significantly accelerated. Upon reaching 800 °C, the rate of the strength deterioration of AAMs tends to stabilize, with some alkali-activated composites even exhibiting signs of strength recovery. After exposure to high temperatures of 800 °C, the retentions of the compressive strength and flexural strength of alkali-activated composites are in the ranges of about 20–60% and 20–40%, respectively. The degradation mechanisms at elevated temperatures primarily include crystalline-phase transformation, microstructural changes, and thermal incompatibility arising from the differing coefficients of thermal expansion between the matrix and the aggregates. Finally, this paper discusses effective strategies to enhance the resistance of AAMs to high temperatures and highlights both the opportunities and challenges for future research in this field.
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spelling doaj-art-bec8d651c45d43cdb44ef4e34c7c416f2025-08-20T02:05:09ZengMDPI AGBuildings2075-53092025-02-0115573810.3390/buildings15050738A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated TemperaturesTing Wu0Si Tang1Yao-Rong Dong2Jiang-Hua Luo3College of Civil and Construction Engineering, Hunan Institute of Technology, Hengyang 421002, ChinaCollege of Civil and Construction Engineering, Hunan Institute of Technology, Hengyang 421002, ChinaSchool of Civil Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, ChinaCollege of Civil and Construction Engineering, Hunan Institute of Technology, Hengyang 421002, ChinaAlkali-activated materials (AAMs) are promoted as a sustainable alternative to ordinary Portland cement (OPC). They not only have excellent resistance to high temperatures and chemical corrosion, but they can also help to reduce greenhouse gas emissions and reduce energy consumption. Despite their superior resistance to high temperatures compared to conventional cement-based concretes, studies have indicated that AAMs still face challenges related to performance degradation under elevated temperatures. This paper systematically reviews and summarizes the thermal properties (i.e., thermal expansion, thermal stability, and thermal conductivity), mechanical performance, and deterioration mechanisms of various alkali-activated composite systems. The findings reveal significant variability in resistance to high temperatures among different AAM systems, originating from the diversity of precursor materials used. Generally, the strength deterioration of various AAMs below 400 °C is minimal or even slightly increased, while between 600 °C and 800 °C, the strength degradation is significantly accelerated. Upon reaching 800 °C, the rate of the strength deterioration of AAMs tends to stabilize, with some alkali-activated composites even exhibiting signs of strength recovery. After exposure to high temperatures of 800 °C, the retentions of the compressive strength and flexural strength of alkali-activated composites are in the ranges of about 20–60% and 20–40%, respectively. The degradation mechanisms at elevated temperatures primarily include crystalline-phase transformation, microstructural changes, and thermal incompatibility arising from the differing coefficients of thermal expansion between the matrix and the aggregates. Finally, this paper discusses effective strategies to enhance the resistance of AAMs to high temperatures and highlights both the opportunities and challenges for future research in this field.https://www.mdpi.com/2075-5309/15/5/738alkali-activated materialsthermal propertiesmechanical performancedeterioration mechanismshigh temperature
spellingShingle Ting Wu
Si Tang
Yao-Rong Dong
Jiang-Hua Luo
A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures
Buildings
alkali-activated materials
thermal properties
mechanical performance
deterioration mechanisms
high temperature
title A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures
title_full A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures
title_fullStr A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures
title_full_unstemmed A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures
title_short A Review of the Thermal and Mechanical Characteristics of Alkali-Activated Composites at Elevated Temperatures
title_sort review of the thermal and mechanical characteristics of alkali activated composites at elevated temperatures
topic alkali-activated materials
thermal properties
mechanical performance
deterioration mechanisms
high temperature
url https://www.mdpi.com/2075-5309/15/5/738
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