Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids
When solid polyacrylamide (PAam) is added to a solution of bismuth chloride, a polymeric salt of composition (CH2-CH-CONH2)n BiCl3 (n > 10) is obtained. This amorphous material is transparent in the visible. In this hybrid, bismuth seems to be coordinated both to amine and carbonyl groups. When t...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
1996-01-01
|
| Series: | Active and Passive Electronic Components |
| Online Access: | http://dx.doi.org/10.1155/1996/64239 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849684185664454656 |
|---|---|
| author | G. Campet L. Rabardel J. Portier H. S. Dweik M. A. Subramanian |
| author_facet | G. Campet L. Rabardel J. Portier H. S. Dweik M. A. Subramanian |
| author_sort | G. Campet |
| collection | DOAJ |
| description | When solid polyacrylamide (PAam) is added to a solution of bismuth chloride, a polymeric salt of
composition (CH2-CH-CONH2)n BiCl3 (n > 10) is obtained. This amorphous material is transparent in
the visible. In this hybrid, bismuth seems to be coordinated both to amine and carbonyl groups. When
the PAam-BiCI3 hybrid is swollen with a KI solution, the corresponding iodide salt is formed with
probably small particles of Bil3 precipitated into the polymeric matrix. Chemical, thermal, and optical
(in the UV, visible, and infrared regions) properties of the salt and of the composite are studied. |
| format | Article |
| id | doaj-art-be0be027dfb441d8806ff52e11ea8e12 |
| institution | DOAJ |
| issn | 0882-7516 1563-5031 |
| language | English |
| publishDate | 1996-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Active and Passive Electronic Components |
| spelling | doaj-art-be0be027dfb441d8806ff52e11ea8e122025-08-20T03:23:33ZengWileyActive and Passive Electronic Components0882-75161563-50311996-01-011929910410.1155/1996/64239Synthesis and Properties of Polyacrylamide-Bismuth Halogenated HybridsG. Campet0L. Rabardel1J. Portier2H. S. Dweik3M. A. Subramanian4ICMCB, Avenue Albert Schweitzer, Pessac 33800, FranceICMCB, Avenue Albert Schweitzer, Pessac 33800, FranceICMCB, Avenue Albert Schweitzer, Pessac 33800, FranceAl-Quds University, Department of Chemistry and Chemical Technology, P.O. Box 20002, West Bank, Jerusalem, Palestinian AuthorityCentral Research & Development, Dupont Company, Wilmington 19880-0328, Delaware, USAWhen solid polyacrylamide (PAam) is added to a solution of bismuth chloride, a polymeric salt of composition (CH2-CH-CONH2)n BiCl3 (n > 10) is obtained. This amorphous material is transparent in the visible. In this hybrid, bismuth seems to be coordinated both to amine and carbonyl groups. When the PAam-BiCI3 hybrid is swollen with a KI solution, the corresponding iodide salt is formed with probably small particles of Bil3 precipitated into the polymeric matrix. Chemical, thermal, and optical (in the UV, visible, and infrared regions) properties of the salt and of the composite are studied.http://dx.doi.org/10.1155/1996/64239 |
| spellingShingle | G. Campet L. Rabardel J. Portier H. S. Dweik M. A. Subramanian Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids Active and Passive Electronic Components |
| title | Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids |
| title_full | Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids |
| title_fullStr | Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids |
| title_full_unstemmed | Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids |
| title_short | Synthesis and Properties of Polyacrylamide-Bismuth Halogenated Hybrids |
| title_sort | synthesis and properties of polyacrylamide bismuth halogenated hybrids |
| url | http://dx.doi.org/10.1155/1996/64239 |
| work_keys_str_mv | AT gcampet synthesisandpropertiesofpolyacrylamidebismuthhalogenatedhybrids AT lrabardel synthesisandpropertiesofpolyacrylamidebismuthhalogenatedhybrids AT jportier synthesisandpropertiesofpolyacrylamidebismuthhalogenatedhybrids AT hsdweik synthesisandpropertiesofpolyacrylamidebismuthhalogenatedhybrids AT masubramanian synthesisandpropertiesofpolyacrylamidebismuthhalogenatedhybrids |