Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite

Natural bentonite was modified with zinc ions and was used as a filler to reduce the offensive odor from raw natural rubber (NR). Characterization of filler shows the limited exchange of inherent calcium ions and the preferred adsorption of zinc ions on the surface of natural bentonite during modifi...

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Main Authors: Bryan B. Pajarito, Kayla C. Castañeda, Sofia Denise M. Jeresano, Dominique Ann N. Repoquit
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2018/9102825
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author Bryan B. Pajarito
Kayla C. Castañeda
Sofia Denise M. Jeresano
Dominique Ann N. Repoquit
author_facet Bryan B. Pajarito
Kayla C. Castañeda
Sofia Denise M. Jeresano
Dominique Ann N. Repoquit
author_sort Bryan B. Pajarito
collection DOAJ
description Natural bentonite was modified with zinc ions and was used as a filler to reduce the offensive odor from raw natural rubber (NR). Characterization of filler shows the limited exchange of inherent calcium ions and the preferred adsorption of zinc ions on the surface of natural bentonite during modification. The modification process was also accompanied by bassanite formation due to sulfate ions brought by the zinc salt. Zinc-modified bentonite demonstrates an antimicrobial effect against microorganisms that are known to degrade or produce offensive odor from raw NR. Due to its antimicrobial and adsorption properties, zinc-modified bentonite significantly reduces the offensive odor from raw NR at loadings of 2.5–7.5 phr as shown by the olfactometry test. In terms of vulcanization characteristics, the loading of zinc-modified bentonite at 7.5 phr caused a slight decrease in elastic torque and increase in scorch and curing times of NR. The hardness and tensile properties of vulcanized NR are maintained after compounding with zinc-modified bentonite at 7.5 phr.
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institution Kabale University
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publishDate 2018-01-01
publisher Wiley
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series Advances in Materials Science and Engineering
spelling doaj-art-bdffcf48b032430a87e81f90aa0c22352025-02-03T05:44:03ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422018-01-01201810.1155/2018/91028259102825Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified BentoniteBryan B. Pajarito0Kayla C. Castañeda1Sofia Denise M. Jeresano2Dominique Ann N. Repoquit3Polymer Research Laboratory, Department of Chemical Engineering, University of the Philippines, Diliman, Quezon City 1101, PhilippinesPolymer Research Laboratory, Department of Chemical Engineering, University of the Philippines, Diliman, Quezon City 1101, PhilippinesPolymer Research Laboratory, Department of Chemical Engineering, University of the Philippines, Diliman, Quezon City 1101, PhilippinesPolymer Research Laboratory, Department of Chemical Engineering, University of the Philippines, Diliman, Quezon City 1101, PhilippinesNatural bentonite was modified with zinc ions and was used as a filler to reduce the offensive odor from raw natural rubber (NR). Characterization of filler shows the limited exchange of inherent calcium ions and the preferred adsorption of zinc ions on the surface of natural bentonite during modification. The modification process was also accompanied by bassanite formation due to sulfate ions brought by the zinc salt. Zinc-modified bentonite demonstrates an antimicrobial effect against microorganisms that are known to degrade or produce offensive odor from raw NR. Due to its antimicrobial and adsorption properties, zinc-modified bentonite significantly reduces the offensive odor from raw NR at loadings of 2.5–7.5 phr as shown by the olfactometry test. In terms of vulcanization characteristics, the loading of zinc-modified bentonite at 7.5 phr caused a slight decrease in elastic torque and increase in scorch and curing times of NR. The hardness and tensile properties of vulcanized NR are maintained after compounding with zinc-modified bentonite at 7.5 phr.http://dx.doi.org/10.1155/2018/9102825
spellingShingle Bryan B. Pajarito
Kayla C. Castañeda
Sofia Denise M. Jeresano
Dominique Ann N. Repoquit
Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite
Advances in Materials Science and Engineering
title Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite
title_full Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite
title_fullStr Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite
title_full_unstemmed Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite
title_short Reduction of Offensive Odor from Natural Rubber Using Zinc-Modified Bentonite
title_sort reduction of offensive odor from natural rubber using zinc modified bentonite
url http://dx.doi.org/10.1155/2018/9102825
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