Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS
The northern region of Brazil, particularly the states of Pará and Amazonas, concentrates the majority of açaí national production. Considering the possible use of pesticides in this species, this study aimed to develop a comprehensive method for the multiresidue determination of pesticides in açaí...
Saved in:
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2025-02-01
|
| Series: | Química Nova |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000400313&lng=pt&tlng=pt |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1823859205645271040 |
|---|---|
| author | Rafael Bel Prestes da Silva Luana Floriano Cleusa Fátima Zanchin Franciele Fátima Machado Júlia Antunes de Oliveira Osmar Damian Prestes Renato Zanella |
| author_facet | Rafael Bel Prestes da Silva Luana Floriano Cleusa Fátima Zanchin Franciele Fátima Machado Júlia Antunes de Oliveira Osmar Damian Prestes Renato Zanella |
| author_sort | Rafael Bel Prestes da Silva |
| collection | DOAJ |
| description | The northern region of Brazil, particularly the states of Pará and Amazonas, concentrates the majority of açaí national production. Considering the possible use of pesticides in this species, this study aimed to develop a comprehensive method for the multiresidue determination of pesticides in açaí pulp, using a modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) method with analysis by ultra-high performance liquid chromatography with tandem mass spectrometry (UHPLC-MS/MS). Various parameters of extraction were investigated, and the method was successfully validated. Analysis by UHPLC-MS/MS provided high selectivity and sensitivity. The main modification to the original QuEChERS method was the use of the C18 adsorbent associated with primary secondary amine (PSA) in the clean-up step by dispersive solid phase extraction (d-SPE). The method was validated for 83 compounds, showing adequate accuracy (70 to 120%) and precision (RSD ≤ 20%). The method limits of quantification, established by recovery tests, ranged from 5 to 25 µg kg-1. The method limits of detection were from 1.5 to 7.5 µg kg-1. The method was applied to commercial samples of açaí pulp, and no pesticide residues were detected. The proposed method proved to be fast, efficient and suitable for multiresidue determination of pesticides in açaí pulp in routine analysis. |
| format | Article |
| id | doaj-art-bdf54da260734705abbc9a449d0a03bc |
| institution | Kabale University |
| issn | 1678-7064 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj-art-bdf54da260734705abbc9a449d0a03bc2025-02-11T07:43:09ZengSociedade Brasileira de QuímicaQuímica Nova1678-70642025-02-0148410.21577/0100-4042.20250101Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MSRafael Bel Prestes da SilvaLuana FlorianoCleusa Fátima ZanchinFranciele Fátima MachadoJúlia Antunes de OliveiraOsmar Damian PrestesRenato Zanellahttps://orcid.org/0000-0002-5971-1785The northern region of Brazil, particularly the states of Pará and Amazonas, concentrates the majority of açaí national production. Considering the possible use of pesticides in this species, this study aimed to develop a comprehensive method for the multiresidue determination of pesticides in açaí pulp, using a modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) method with analysis by ultra-high performance liquid chromatography with tandem mass spectrometry (UHPLC-MS/MS). Various parameters of extraction were investigated, and the method was successfully validated. Analysis by UHPLC-MS/MS provided high selectivity and sensitivity. The main modification to the original QuEChERS method was the use of the C18 adsorbent associated with primary secondary amine (PSA) in the clean-up step by dispersive solid phase extraction (d-SPE). The method was validated for 83 compounds, showing adequate accuracy (70 to 120%) and precision (RSD ≤ 20%). The method limits of quantification, established by recovery tests, ranged from 5 to 25 µg kg-1. The method limits of detection were from 1.5 to 7.5 µg kg-1. The method was applied to commercial samples of açaí pulp, and no pesticide residues were detected. The proposed method proved to be fast, efficient and suitable for multiresidue determination of pesticides in açaí pulp in routine analysis.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000400313&lng=pt&tlng=pt |
| spellingShingle | Rafael Bel Prestes da Silva Luana Floriano Cleusa Fátima Zanchin Franciele Fátima Machado Júlia Antunes de Oliveira Osmar Damian Prestes Renato Zanella Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS Química Nova |
| title | Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS |
| title_full | Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS |
| title_fullStr | Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS |
| title_full_unstemmed | Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS |
| title_short | Método multirresíduo de agrotóxicos em polpa de açaí empregando método QuEChERS modificado e UHPLC-MS/MS |
| title_sort | metodo multirresiduo de agrotoxicos em polpa de acai empregando metodo quechers modificado e uhplc ms ms |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000400313&lng=pt&tlng=pt |
| work_keys_str_mv | AT rafaelbelprestesdasilva metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms AT luanafloriano metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms AT cleusafatimazanchin metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms AT francielefatimamachado metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms AT juliaantunesdeoliveira metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms AT osmardamianprestes metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms AT renatozanella metodomultirresiduodeagrotoxicosempolpadeacaiempregandometodoquechersmodificadoeuhplcmsms |