Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline
3,4,5-Trimethoxy N-(salicylidene) aniline was synthesized and characterized by IR spectroscopy, 1H NMR and x-ray single crystal analysis. UV-visible spectroscopy was used for physicochemical tests. X-ray data reveals that the crystalline network cohesion of this compound is essentially assured by CH...
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| Format: | Article |
| Language: | English |
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Wiley
2009-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2009/473124 |
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| author | Kodjo Charles Guillaume Zabri Herve Benie Anoubile Estienne Jacques |
| author_facet | Kodjo Charles Guillaume Zabri Herve Benie Anoubile Estienne Jacques |
| author_sort | Kodjo Charles Guillaume |
| collection | DOAJ |
| description | 3,4,5-Trimethoxy N-(salicylidene) aniline was synthesized and characterized by IR spectroscopy, 1H NMR and x-ray single crystal analysis. UV-visible spectroscopy was used for physicochemical tests. X-ray data reveals that the crystalline network cohesion of this compound is essentially assured by CH/pi type hydrogen bounds. It crystallized in the orthorhombic Pbcn space group. Electronic spectroscopy shows that the title compound doesn't present photochromic property but thermochromic one. Intermolecular interactions analysis confirms for this compound a thermochromic structural predisposition. |
| format | Article |
| id | doaj-art-bcf02fdf63304c55a60ab712b058d9a8 |
| institution | DOAJ |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2009-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-bcf02fdf63304c55a60ab712b058d9a82025-08-20T03:23:19ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-01641103110810.1155/2009/473124Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) anilineKodjo Charles Guillaume0Zabri Herve1Benie Anoubile2Estienne Jacques3Laboratoire de chimie bio-organique et de substances naturelles, UFR-SFA, Universit d’Abobo-adjam, 02 B.P. 801 Abidjan 02, Cote D'IvoireLaboratoire de chimie bio-organique et de substances naturelles, UFR-SFA, Universit d’Abobo-adjam, 02 B.P. 801 Abidjan 02, Cote D'IvoireLaboratoire de chimie bio-organique et de substances naturelles, UFR-SFA, Universit d’Abobo-adjam, 02 B.P. 801 Abidjan 02, Cote D'IvoireLaboratoire de Spectrométries et Physico-Chimie Structurale, Universit Paul Czanne Aix-Marseille III, Centre de Saint Jrôme, case 242, 13397 Marseille cedex 20 , France3,4,5-Trimethoxy N-(salicylidene) aniline was synthesized and characterized by IR spectroscopy, 1H NMR and x-ray single crystal analysis. UV-visible spectroscopy was used for physicochemical tests. X-ray data reveals that the crystalline network cohesion of this compound is essentially assured by CH/pi type hydrogen bounds. It crystallized in the orthorhombic Pbcn space group. Electronic spectroscopy shows that the title compound doesn't present photochromic property but thermochromic one. Intermolecular interactions analysis confirms for this compound a thermochromic structural predisposition.http://dx.doi.org/10.1155/2009/473124 |
| spellingShingle | Kodjo Charles Guillaume Zabri Herve Benie Anoubile Estienne Jacques Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline E-Journal of Chemistry |
| title | Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline |
| title_full | Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline |
| title_fullStr | Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline |
| title_full_unstemmed | Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline |
| title_short | Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline |
| title_sort | preparation spectroscopy physicochemical properties and x ray structure analysis of 3 4 5 trimethoxy n 2 hydroxybenzylidene aniline |
| url | http://dx.doi.org/10.1155/2009/473124 |
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