Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions

Chitosan has sometimes been perceived to have a poor stability, which may explain why only a few chitosan-based products are available commercially. The purpose of this study was to investigate the stability of two chitosan powders and of Ortho-R (ChitogenX Inc), a chitosan-containing finished produ...

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Main Authors: Anik Chevrier, Dong Wang, Elizabeth Ladd, Jean-Simon Blais, Marc Lavertu
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Carbohydrate Polymer Technologies and Applications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666893925001161
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author Anik Chevrier
Dong Wang
Elizabeth Ladd
Jean-Simon Blais
Marc Lavertu
author_facet Anik Chevrier
Dong Wang
Elizabeth Ladd
Jean-Simon Blais
Marc Lavertu
author_sort Anik Chevrier
collection DOAJ
description Chitosan has sometimes been perceived to have a poor stability, which may explain why only a few chitosan-based products are available commercially. The purpose of this study was to investigate the stability of two chitosan powders and of Ortho-R (ChitogenX Inc), a chitosan-containing finished product that is used as an adjunct to improve repair of soft tissues. The powders and Ortho-R product were subjected to accelerated (40 °C/75 % RH) and long-term (25 °C/60 % RH) stability testing. The chitosan number average molar mass (Mn), polydispersity index (PDI), degree of deacetylation (DDA) and water content did not change substantially throughout the stability testing period and remained within the established specifications. Forced degradation studies were also performed on the Ortho-R product by exposing it to light, heat, humidity, hydrochloric acid and hydrogen peroxide. Storing the Ortho-R product in an open vial under warm and humid conditions (40 °C/75 % RH) led to an increase in chitosan Mn and PDI. The Ortho-R product was sensitive to oxidation as revealed by a decrease in chitosan Mn and PDI. Chitosan powders and the Ortho-R finished product are stable in the long term when the proper container closure systems are used.
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spelling doaj-art-bc96430acebb473ca9564e9e59986bd52025-08-20T02:39:35ZengElsevierCarbohydrate Polymer Technologies and Applications2666-89392025-06-011010077710.1016/j.carpta.2025.100777Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditionsAnik Chevrier0Dong Wang1Elizabeth Ladd2Jean-Simon Blais3Marc Lavertu4Chemical Engineering Department, Polytechnique Montreal, 2500 Chem. de Polytechnique, Montréal, QC, H3T 1J4, CanadaChemical Engineering Department, Polytechnique Montreal, 2500 Chem. de Polytechnique, Montréal, QC, H3T 1J4, CanadaKABS Laboratories Inc, 4500, rue de Tonnancour, St-Hubert, QC, J3Y 9G2, CanadaKABS Laboratories Inc, 4500, rue de Tonnancour, St-Hubert, QC, J3Y 9G2, CanadaChemical Engineering Department, Polytechnique Montreal, 2500 Chem. de Polytechnique, Montréal, QC, H3T 1J4, Canada; Biomedical Engineering Institute, Polytechnique Montreal, 2500 Chem. de Polytechnique, Montréal, QC, H3T 1J4, Canada; Corresponding author at: Department of Chemical Engineering, Polytechnique Montreal, PO Box 6079 Succ Centre-Ville, Montreal, Quebec, H3C 3A7, Canada.Chitosan has sometimes been perceived to have a poor stability, which may explain why only a few chitosan-based products are available commercially. The purpose of this study was to investigate the stability of two chitosan powders and of Ortho-R (ChitogenX Inc), a chitosan-containing finished product that is used as an adjunct to improve repair of soft tissues. The powders and Ortho-R product were subjected to accelerated (40 °C/75 % RH) and long-term (25 °C/60 % RH) stability testing. The chitosan number average molar mass (Mn), polydispersity index (PDI), degree of deacetylation (DDA) and water content did not change substantially throughout the stability testing period and remained within the established specifications. Forced degradation studies were also performed on the Ortho-R product by exposing it to light, heat, humidity, hydrochloric acid and hydrogen peroxide. Storing the Ortho-R product in an open vial under warm and humid conditions (40 °C/75 % RH) led to an increase in chitosan Mn and PDI. The Ortho-R product was sensitive to oxidation as revealed by a decrease in chitosan Mn and PDI. Chitosan powders and the Ortho-R finished product are stable in the long term when the proper container closure systems are used.http://www.sciencedirect.com/science/article/pii/S2666893925001161ChitosanAccelerated stabilityLong-term stabilityForced degradation
spellingShingle Anik Chevrier
Dong Wang
Elizabeth Ladd
Jean-Simon Blais
Marc Lavertu
Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions
Carbohydrate Polymer Technologies and Applications
Chitosan
Accelerated stability
Long-term stability
Forced degradation
title Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions
title_full Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions
title_fullStr Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions
title_full_unstemmed Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions
title_short Chitosan powders and Ortho-R, a chitosan-containing finished product, are stable long term when stored in proper conditions
title_sort chitosan powders and ortho r a chitosan containing finished product are stable long term when stored in proper conditions
topic Chitosan
Accelerated stability
Long-term stability
Forced degradation
url http://www.sciencedirect.com/science/article/pii/S2666893925001161
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