Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater

Olive mill wastewater (OMW) is nowadays considered a serious environmental problem, especially within the Mediterranean region. With this in mind, water shortages are also a very serious and prevalent concern in third world countries. The aim of this study is to investigate the feasibility of using...

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Main Authors: Khansaa Al-Essa, Ethar M. Al-Essa
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2021/7405238
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author Khansaa Al-Essa
Ethar M. Al-Essa
author_facet Khansaa Al-Essa
Ethar M. Al-Essa
author_sort Khansaa Al-Essa
collection DOAJ
description Olive mill wastewater (OMW) is nowadays considered a serious environmental problem, especially within the Mediterranean region. With this in mind, water shortages are also a very serious and prevalent concern in third world countries. The aim of this study is to investigate the feasibility of using Jordanian bentonite, a simple and natural clay, as a possible adsorbent to decrease the negative characteristics of raw OMW, as an approach to the development of a methodology that addresses the OMW problem without affecting freshwater resources. The purified bentonite was activated by sodium ions at room temperature. FTIR, XRD, TGA, and BET surface area measurements were performed. OMW was contacted with both purified and activated bentonite in the batch technique to figure out the optimum parameters for the adsorption process. Physiochemical parameters of OMW were measured before and after treatment. The maximum adsorption qm was found as 8.81 mg/g at 323 K for the total phenolic compounds. The Langmuir and Freundlich models were utilized to describe the equilibrium isotherms and both models fit well. The parameters of thermodynamic show that the adsorption process was feasible, spontaneous, and endothermic in nature. These promising results along with the sodium activation of bentonite significantly improve bentonite’s adsorption capacity.
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spelling doaj-art-bc6121bea24b47f4b533db17e64a85002025-02-03T01:27:22ZengWileyJournal of Chemistry2090-90632090-90712021-01-01202110.1155/2021/74052387405238Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill WastewaterKhansaa Al-Essa0Ethar M. Al-Essa1Department of Chemistry, Jerash University, Jerash 26150, JordanDepartment of Civil Engineering, University of Canterbury, Christchurch, New ZealandOlive mill wastewater (OMW) is nowadays considered a serious environmental problem, especially within the Mediterranean region. With this in mind, water shortages are also a very serious and prevalent concern in third world countries. The aim of this study is to investigate the feasibility of using Jordanian bentonite, a simple and natural clay, as a possible adsorbent to decrease the negative characteristics of raw OMW, as an approach to the development of a methodology that addresses the OMW problem without affecting freshwater resources. The purified bentonite was activated by sodium ions at room temperature. FTIR, XRD, TGA, and BET surface area measurements were performed. OMW was contacted with both purified and activated bentonite in the batch technique to figure out the optimum parameters for the adsorption process. Physiochemical parameters of OMW were measured before and after treatment. The maximum adsorption qm was found as 8.81 mg/g at 323 K for the total phenolic compounds. The Langmuir and Freundlich models were utilized to describe the equilibrium isotherms and both models fit well. The parameters of thermodynamic show that the adsorption process was feasible, spontaneous, and endothermic in nature. These promising results along with the sodium activation of bentonite significantly improve bentonite’s adsorption capacity.http://dx.doi.org/10.1155/2021/7405238
spellingShingle Khansaa Al-Essa
Ethar M. Al-Essa
Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater
Journal of Chemistry
title Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater
title_full Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater
title_fullStr Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater
title_full_unstemmed Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater
title_short Effective Approach of Activated Jordanian Bentonite by Sodium Ions for Total Phenolic Compounds Removal from Olive Mill Wastewater
title_sort effective approach of activated jordanian bentonite by sodium ions for total phenolic compounds removal from olive mill wastewater
url http://dx.doi.org/10.1155/2021/7405238
work_keys_str_mv AT khansaaalessa effectiveapproachofactivatedjordanianbentonitebysodiumionsfortotalphenoliccompoundsremovalfromolivemillwastewater
AT etharmalessa effectiveapproachofactivatedjordanianbentonitebysodiumionsfortotalphenoliccompoundsremovalfromolivemillwastewater