Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay

Abstract Structural materials are used extensively in nature where mechanical function is required. These structures are composites consisting of soft and, in some cases, hard phases precisely distributed over different length scales. Bio-inspiration aims at producing materials with structure, desig...

Full description

Saved in:
Bibliographic Details
Main Authors: Marco Curto, Jack Dowsett, Alexander P. Kao, Gianluca Tozzi, Asa H. Barber
Format: Article
Language:English
Published: Nature Portfolio 2025-02-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-91080-2
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850026052167925760
author Marco Curto
Jack Dowsett
Alexander P. Kao
Gianluca Tozzi
Asa H. Barber
author_facet Marco Curto
Jack Dowsett
Alexander P. Kao
Gianluca Tozzi
Asa H. Barber
author_sort Marco Curto
collection DOAJ
description Abstract Structural materials are used extensively in nature where mechanical function is required. These structures are composites consisting of soft and, in some cases, hard phases precisely distributed over different length scales. Bio-inspiration aims at producing materials with structure, design and/or mechanical properties adopted from biological tissues. To reproduce complex structures found in nature, additive manufacturing (AM) using three-dimensional printing (3DP) is an attractive method to assemble complex topologies with resolutions approaching the micro and nano-composition. Specifically, high-resolution MultiJetPrinting (MJP) 3D printing allows the simultaneous deposition of soft and hard photo curable plastic resins. Nacre is a prevalent example of a complex biological composite material organization that can test the ability of MJP to manufacture a bio-inspired engineering structure, where the organization of materials in nacre is optimized to avoid catastrophic failure. The ability to generate complex 3D organizations required to mimic the structure of nacre by controlled organization of soft and hard materials is achieved here using a generative design approach. Such a generative design is further enhanced by incorporating two differing MJP directions that provide relatively strong and weak interfaces between the soft and hard material phases. Consideration of classical stress transfer theory between at a hard material reinforcement interface was shown to correlate with experimental observations of mechanical performance and failure in 3D printed nacre inspired composites. Thus, the ability to distribute materials with a range of mechanical properties and incorporate further interfacial design is demonstrated. The approach presented is flexible and allows complex bio-inspired composites to be 3D printed that incorporate different interfacial quality through changing printing direction.
format Article
id doaj-art-bc33affc34924eb7b9999f6f5332e931
institution DOAJ
issn 2045-2322
language English
publishDate 2025-02-01
publisher Nature Portfolio
record_format Article
series Scientific Reports
spelling doaj-art-bc33affc34924eb7b9999f6f5332e9312025-08-20T03:00:39ZengNature PortfolioScientific Reports2045-23222025-02-0115111210.1038/s41598-025-91080-2Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplayMarco Curto0Jack Dowsett1Alexander P. Kao2Gianluca Tozzi3Asa H. Barber4School of Mechanical and Design Engineering, University of PortsmouthSchool of Mechanical and Design Engineering, University of PortsmouthSchool of Mechanical and Design Engineering, University of PortsmouthSchool of Engineering, University of GreenwichDepartment of Engineering, City St. George’s, University of LondonAbstract Structural materials are used extensively in nature where mechanical function is required. These structures are composites consisting of soft and, in some cases, hard phases precisely distributed over different length scales. Bio-inspiration aims at producing materials with structure, design and/or mechanical properties adopted from biological tissues. To reproduce complex structures found in nature, additive manufacturing (AM) using three-dimensional printing (3DP) is an attractive method to assemble complex topologies with resolutions approaching the micro and nano-composition. Specifically, high-resolution MultiJetPrinting (MJP) 3D printing allows the simultaneous deposition of soft and hard photo curable plastic resins. Nacre is a prevalent example of a complex biological composite material organization that can test the ability of MJP to manufacture a bio-inspired engineering structure, where the organization of materials in nacre is optimized to avoid catastrophic failure. The ability to generate complex 3D organizations required to mimic the structure of nacre by controlled organization of soft and hard materials is achieved here using a generative design approach. Such a generative design is further enhanced by incorporating two differing MJP directions that provide relatively strong and weak interfaces between the soft and hard material phases. Consideration of classical stress transfer theory between at a hard material reinforcement interface was shown to correlate with experimental observations of mechanical performance and failure in 3D printed nacre inspired composites. Thus, the ability to distribute materials with a range of mechanical properties and incorporate further interfacial design is demonstrated. The approach presented is flexible and allows complex bio-inspired composites to be 3D printed that incorporate different interfacial quality through changing printing direction.https://doi.org/10.1038/s41598-025-91080-2BioinspiredAdditive manufacturing3D printingCompositesX-ray tomographyMulti-material
spellingShingle Marco Curto
Jack Dowsett
Alexander P. Kao
Gianluca Tozzi
Asa H. Barber
Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay
Scientific Reports
Bioinspired
Additive manufacturing
3D printing
Composites
X-ray tomography
Multi-material
title Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay
title_full Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay
title_fullStr Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay
title_full_unstemmed Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay
title_short Multi-material 3D printed composites inspired by nacre: a hard/soft mechanical interplay
title_sort multi material 3d printed composites inspired by nacre a hard soft mechanical interplay
topic Bioinspired
Additive manufacturing
3D printing
Composites
X-ray tomography
Multi-material
url https://doi.org/10.1038/s41598-025-91080-2
work_keys_str_mv AT marcocurto multimaterial3dprintedcompositesinspiredbynacreahardsoftmechanicalinterplay
AT jackdowsett multimaterial3dprintedcompositesinspiredbynacreahardsoftmechanicalinterplay
AT alexanderpkao multimaterial3dprintedcompositesinspiredbynacreahardsoftmechanicalinterplay
AT gianlucatozzi multimaterial3dprintedcompositesinspiredbynacreahardsoftmechanicalinterplay
AT asahbarber multimaterial3dprintedcompositesinspiredbynacreahardsoftmechanicalinterplay