Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids

Chronic rhinosinusitis (CRS) is associated with postoperative complications such as adhesions and recurrent inflammation. Nasal implants are clinically utilized as adjuncts to endoscopic sinus surgery (ESS) for controlling hemorrhage and enhancing drug delivery. However, existing implants, such as N...

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Main Authors: Bohuai Xu, Wei Wang, Jiayan Wang, Jibin Huang, Di Wu, Ming Xu
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Carbohydrate Polymer Technologies and Applications
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666893925001501
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author Bohuai Xu
Wei Wang
Jiayan Wang
Jibin Huang
Di Wu
Ming Xu
author_facet Bohuai Xu
Wei Wang
Jiayan Wang
Jibin Huang
Di Wu
Ming Xu
author_sort Bohuai Xu
collection DOAJ
description Chronic rhinosinusitis (CRS) is associated with postoperative complications such as adhesions and recurrent inflammation. Nasal implants are clinically utilized as adjuncts to endoscopic sinus surgery (ESS) for controlling hemorrhage and enhancing drug delivery. However, existing implants, such as NASOPORE®, exhibit uniform degradation patterns. In this study, we developed a stepwise degradable hyaluronic acid (HA) hydrogel hemostatic sponge loaded with mometasone furoate (Elocon Cream), designed to synchronize its degradation with the phases of wound healing. The sponge demonstrated a dual-phase degradation profile: rapid hemostatic material clearance (65 % mass loss by Day 5) followed by sustained HA hydrogel degradation (12 % residual mass at Day 14), enabling prolonged mucosal MF retention.The HA@F127-MF sponge exhibited exceptional water absorption (swelling ratio: 1470 ± 141 %), mechanical stability (compressive modulus: 12.8 ± 1.8 kPa), and controlled drug release (85.44 ± 3.22 % cumulative release over 15 days). In vivo studies revealed significant anti-inflammatory effects, with TNF-α, IL-5, and periostin levels reduced by 62 %, 68 %, and 54 %, respectively (p < 0.01 vs. control), attributed to HA’s CD44-mediated anti-inflammatory activity (100 kDa) combined with MF’s corticosteroid action. Histological analysis confirmed minimal inflammation and no systemic toxicity.This study addresses critical limitations of current implants by introducing a stepwise degradable design that enhances hemostasis and sustained drug delivery, offering a promising strategy for CRS postoperative management.
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spelling doaj-art-bc1281832e694a02b336167a73b2b1152025-08-20T03:20:58ZengElsevierCarbohydrate Polymer Technologies and Applications2666-89392025-06-011010081210.1016/j.carpta.2025.100812Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroidsBohuai Xu0Wei Wang1Jiayan Wang2Jibin Huang3Di Wu4Ming Xu5Department of otolaryngology head and neck surgery, The First Affiliated Hospital of Ningbo University, Ningbo, Zhejiang 315000, PR ChinaDepartment of Otorhinolaryngology, Ningbo Municipal Hospital of Traditional Chinese Medicine, Affiliated Hospital of Zhejiang Chinese Medical University, Ningbo 315012, PR ChinaDepartment of Otorhinolaryngology, Ningbo Municipal Hospital of Traditional Chinese Medicine, Affiliated Hospital of Zhejiang Chinese Medical University, Ningbo 315012, PR ChinaDepartment of Otorhinolaryngology, Ningbo Municipal Hospital of Traditional Chinese Medicine, Affiliated Hospital of Zhejiang Chinese Medical University, Ningbo 315012, PR ChinaDepartment of Otorhinolaryngology, Ningbo Municipal Hospital of Traditional Chinese Medicine, Affiliated Hospital of Zhejiang Chinese Medical University, Ningbo 315012, PR ChinaDepartment of Otorhinolaryngology, Ningbo Municipal Hospital of Traditional Chinese Medicine, Affiliated Hospital of Zhejiang Chinese Medical University, Ningbo 315012, PR China; Corresponding author at: Department of Otorhinolaryngology, Ningbo Municipal Hospital of Traditional Chinese Medicine (TCM), Affiliated Hospital of Zhejiang Chinese Medical University, No 819 Liyuan Roa, Haishu District, Ningbo 315012, China.Chronic rhinosinusitis (CRS) is associated with postoperative complications such as adhesions and recurrent inflammation. Nasal implants are clinically utilized as adjuncts to endoscopic sinus surgery (ESS) for controlling hemorrhage and enhancing drug delivery. However, existing implants, such as NASOPORE®, exhibit uniform degradation patterns. In this study, we developed a stepwise degradable hyaluronic acid (HA) hydrogel hemostatic sponge loaded with mometasone furoate (Elocon Cream), designed to synchronize its degradation with the phases of wound healing. The sponge demonstrated a dual-phase degradation profile: rapid hemostatic material clearance (65 % mass loss by Day 5) followed by sustained HA hydrogel degradation (12 % residual mass at Day 14), enabling prolonged mucosal MF retention.The HA@F127-MF sponge exhibited exceptional water absorption (swelling ratio: 1470 ± 141 %), mechanical stability (compressive modulus: 12.8 ± 1.8 kPa), and controlled drug release (85.44 ± 3.22 % cumulative release over 15 days). In vivo studies revealed significant anti-inflammatory effects, with TNF-α, IL-5, and periostin levels reduced by 62 %, 68 %, and 54 %, respectively (p < 0.01 vs. control), attributed to HA’s CD44-mediated anti-inflammatory activity (100 kDa) combined with MF’s corticosteroid action. Histological analysis confirmed minimal inflammation and no systemic toxicity.This study addresses critical limitations of current implants by introducing a stepwise degradable design that enhances hemostasis and sustained drug delivery, offering a promising strategy for CRS postoperative management.http://www.sciencedirect.com/science/article/pii/S2666893925001501Chronic rhinosinusitisPostoperative treatmentNasal implantsStepwise degradable hydrogelHyaluronic acidSteroids
spellingShingle Bohuai Xu
Wei Wang
Jiayan Wang
Jibin Huang
Di Wu
Ming Xu
Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
Carbohydrate Polymer Technologies and Applications
Chronic rhinosinusitis
Postoperative treatment
Nasal implants
Stepwise degradable hydrogel
Hyaluronic acid
Steroids
title Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
title_full Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
title_fullStr Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
title_full_unstemmed Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
title_short Preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
title_sort preparation and biological performance of a stepwise degradable hyaluronic acid hydrogel hemostatic sponge loaded with steroids
topic Chronic rhinosinusitis
Postoperative treatment
Nasal implants
Stepwise degradable hydrogel
Hyaluronic acid
Steroids
url http://www.sciencedirect.com/science/article/pii/S2666893925001501
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