Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing

Abstract Acidizing boosts healthy production, while microwave radiation techniques and hybrid methods are emerging to enhance hydrocarbon extraction and oil production efficiency. This research systematically investigated the interaction between microwave radiation and working acid on crude oil. Cru...

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Main Authors: Hadi Tanhaei, Amir Hossein Saeedi Dehaghani
Format: Article
Language:English
Published: Nature Portfolio 2025-03-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-91932-x
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author Hadi Tanhaei
Amir Hossein Saeedi Dehaghani
author_facet Hadi Tanhaei
Amir Hossein Saeedi Dehaghani
author_sort Hadi Tanhaei
collection DOAJ
description Abstract Acidizing boosts healthy production, while microwave radiation techniques and hybrid methods are emerging to enhance hydrocarbon extraction and oil production efficiency. This research systematically investigated the interaction between microwave radiation and working acid on crude oil. Crude oil samples were positioned adjacent to an acid solution and subsequently subjected to microwave radiation at power levels of 1300 W (100% Microwave) and 780 W (60% Microwave) for durations of 1, 2, and 3 min. A comprehensive suite of analyses was performed, including viscometric assessments, interfacial tension measurements, density measurements, asphaltene quantification via extraction tests, sludge analysis, nuclear magnetic resonance (NMR) spectroscopy, pH measurements, and Fourier transform infrared spectroscopy (FTIR). The results indicate that the polarity of both the crude oil and the acid solution enhances the absorption of microwave radiation. FTIR analysis revealed an increase in polar functional groups relative to non-polar groups, suggesting significant molecular interactions; the NMR test also proves this trend. Furthermore, viscometric and surface tension tests demonstrated that increased polarity correlates with enhanced microwave absorption. The combined method, which is characterized by the simultaneous presence of polar acid solution and an electromagnetic field, led to alternating fluctuations (increase and decrease) of surface tension, viscosity, density, pH, and sludge during the tested process. It also caused a decrease in the concentration of asphaltene hydrocarbons; the reason for these intermittent changes is the simultaneous effects of changes in the strength of acid solutions and increasing or decreasing the power of microwave radiation at a particular time.
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spelling doaj-art-bbf339ca911145c1ab706c0fd6068b272025-08-20T02:20:06ZengNature PortfolioScientific Reports2045-23222025-03-0115113110.1038/s41598-025-91932-xImprovement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizingHadi Tanhaei0Amir Hossein Saeedi Dehaghani1Department of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares UniversityDepartment of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares UniversityAbstract Acidizing boosts healthy production, while microwave radiation techniques and hybrid methods are emerging to enhance hydrocarbon extraction and oil production efficiency. This research systematically investigated the interaction between microwave radiation and working acid on crude oil. Crude oil samples were positioned adjacent to an acid solution and subsequently subjected to microwave radiation at power levels of 1300 W (100% Microwave) and 780 W (60% Microwave) for durations of 1, 2, and 3 min. A comprehensive suite of analyses was performed, including viscometric assessments, interfacial tension measurements, density measurements, asphaltene quantification via extraction tests, sludge analysis, nuclear magnetic resonance (NMR) spectroscopy, pH measurements, and Fourier transform infrared spectroscopy (FTIR). The results indicate that the polarity of both the crude oil and the acid solution enhances the absorption of microwave radiation. FTIR analysis revealed an increase in polar functional groups relative to non-polar groups, suggesting significant molecular interactions; the NMR test also proves this trend. Furthermore, viscometric and surface tension tests demonstrated that increased polarity correlates with enhanced microwave absorption. The combined method, which is characterized by the simultaneous presence of polar acid solution and an electromagnetic field, led to alternating fluctuations (increase and decrease) of surface tension, viscosity, density, pH, and sludge during the tested process. It also caused a decrease in the concentration of asphaltene hydrocarbons; the reason for these intermittent changes is the simultaneous effects of changes in the strength of acid solutions and increasing or decreasing the power of microwave radiation at a particular time.https://doi.org/10.1038/s41598-025-91932-xAcidizingProduction efficiencyMicrowave radiationHybrid methodAsphaltene hydrocarbons
spellingShingle Hadi Tanhaei
Amir Hossein Saeedi Dehaghani
Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
Scientific Reports
Acidizing
Production efficiency
Microwave radiation
Hybrid method
Asphaltene hydrocarbons
title Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
title_full Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
title_fullStr Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
title_full_unstemmed Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
title_short Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
title_sort improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing
topic Acidizing
Production efficiency
Microwave radiation
Hybrid method
Asphaltene hydrocarbons
url https://doi.org/10.1038/s41598-025-91932-x
work_keys_str_mv AT haditanhaei improvementofthequalityofheavycrudeoilandreducingtheconcentrationofasphaltenehydrocarbonsusingmicrowaveradiationduringacidizing
AT amirhosseinsaeedidehaghani improvementofthequalityofheavycrudeoilandreducingtheconcentrationofasphaltenehydrocarbonsusingmicrowaveradiationduringacidizing