Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling

The Ti1.27Fe + 11 wt.% Ni composite synthesized by arc melting and ball milling and its possible use in hydrogen storage were studied. First the intermetallic Ti1.27Fe was obtained from elemental powders of Ti and Fe by using the arc melting in argon atmosphere and was cracked in a reactor, after th...

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Main Authors: J. Bonifacio-Martínez, F. Ureña-Núñez, J. L. Iturbe-García
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/831853
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author J. Bonifacio-Martínez
F. Ureña-Núñez
J. L. Iturbe-García
author_facet J. Bonifacio-Martínez
F. Ureña-Núñez
J. L. Iturbe-García
author_sort J. Bonifacio-Martínez
collection DOAJ
description The Ti1.27Fe + 11 wt.% Ni composite synthesized by arc melting and ball milling and its possible use in hydrogen storage were studied. First the intermetallic Ti1.27Fe was obtained from elemental powders of Ti and Fe by using the arc melting in argon atmosphere and was cracked in a reactor, after that nickel powder was added to the Ti1.27Fe alloy before the milling. The mixture was subjected to high-energy ball milling to produce the Ti1.27Fe/Ni composite. Nanocrystalline phases Ti1.27Fe + Ni were observed after 5 h of milling. Hydrogenation results indicated that in the first cycle of hydriding the maximum amount of hydrogen release was 2.10 wt.% for the composite at 100∘C, under hydrogen pressure of 0.8 MPa and without prior activation.
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institution Kabale University
issn 2090-9063
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publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-bbdb479e4ace40659f1bc27594e938f52025-02-03T01:03:49ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/831853831853Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball MillingJ. Bonifacio-Martínez0F. Ureña-Núñez1J. L. Iturbe-García2Facultad de Química, Universidad Autónoma del Estado de México, Avenida Colón Esquina con Paseo Tollocan s/n, Toluca, 50120 Méx, MexicoFacultad de Química, Universidad Autónoma del Estado de México, Avenida Colón Esquina con Paseo Tollocan s/n, Toluca, 50120 Méx, MexicoDepartamento de Química, Instituto Nacional de Investigaciones Nucleares, Carretera México-Toluca s/n, La Marquesa, 52750 Ocoyoacac, Méx, MexicoThe Ti1.27Fe + 11 wt.% Ni composite synthesized by arc melting and ball milling and its possible use in hydrogen storage were studied. First the intermetallic Ti1.27Fe was obtained from elemental powders of Ti and Fe by using the arc melting in argon atmosphere and was cracked in a reactor, after that nickel powder was added to the Ti1.27Fe alloy before the milling. The mixture was subjected to high-energy ball milling to produce the Ti1.27Fe/Ni composite. Nanocrystalline phases Ti1.27Fe + Ni were observed after 5 h of milling. Hydrogenation results indicated that in the first cycle of hydriding the maximum amount of hydrogen release was 2.10 wt.% for the composite at 100∘C, under hydrogen pressure of 0.8 MPa and without prior activation.http://dx.doi.org/10.1155/2013/831853
spellingShingle J. Bonifacio-Martínez
F. Ureña-Núñez
J. L. Iturbe-García
Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling
Journal of Chemistry
title Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling
title_full Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling
title_fullStr Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling
title_full_unstemmed Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling
title_short Characteristics of the Ti1.27Fe + 11 wt.% Ni Composite Obtained by Arc Melting and Ball Milling
title_sort characteristics of the ti1 27fe 11 wt ni composite obtained by arc melting and ball milling
url http://dx.doi.org/10.1155/2013/831853
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