Catalytic Epoxidation of Olefins by Nanolayered Polyoxomolybdate [4,4´-H2bipy][Mo7O22].(H2O)
A two-dimensional nanolayered polyoxomolybdate, [4,4´-H2bipy] [Mo7O22].H2O (1), where 4,4´-bipy = 4,4´-bipyridine, was prepared and characterized by FT-IR and atomic absorption spectroscopies, transmission electron microscopy (TEM), X-ray single crystal and powder diffraction (XRD), and thermogravim...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
University of Tehran
2014-09-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Subjects: | |
| Online Access: | https://jsciences.ut.ac.ir/article_51851_e8373a65286d816f369a1d5bfe8363d8.pdf |
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| Summary: | A two-dimensional nanolayered polyoxomolybdate, [4,4´-H2bipy] [Mo7O22].H2O (1), where 4,4´-bipy = 4,4´-bipyridine, was prepared and characterized by FT-IR and atomic absorption spectroscopies, transmission electron microscopy (TEM), X-ray single crystal and powder diffraction (XRD), and thermogravimetric analysis. The catalytic performance of 1 was assessed in the epoxidation of some olefins employing tert-butyl hydroperoxide (TBHP) as oxidant and acetonitrile as solvent. Compound 1 showed moderate to excellent activity and selectivity towards the epoxidation of the olefins. Thermal, structural and catalytic stability of 1 as well as its reusability were examined. The effect of the catalyst amount and the nature of solvent on the activity of 1 were also investigated. |
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| ISSN: | 1016-1104 2345-6914 |