Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection
We report the first synthesis of zwitterionic thiacalixarenes featuring imidazolium and sulfonate groups on the upper rim and alkyl (butyl or octyl) fragments on the lower rim of the platform. Despite their amphiphilic structure, these macrocycles exhibit limited water solubility. However, dynamic l...
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2025-03-01
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| Series: | Colloids and Interfaces |
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| Online Access: | https://www.mdpi.com/2504-5377/9/2/20 |
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| author | Angelina A. Fedoseeva Indira Yespanova Elza D. Sultanova Bulat Kh. Gafiatullin Regina R. Ibragimova Klara Kh. Darmagambet Marina A. Il’ina Egor O. Chibirev Vladimir G. Evtugyn Nurbol O. Appazov Vladimir A. Burilov Svetlana E. Solovieva Igor S. Antipin |
| author_facet | Angelina A. Fedoseeva Indira Yespanova Elza D. Sultanova Bulat Kh. Gafiatullin Regina R. Ibragimova Klara Kh. Darmagambet Marina A. Il’ina Egor O. Chibirev Vladimir G. Evtugyn Nurbol O. Appazov Vladimir A. Burilov Svetlana E. Solovieva Igor S. Antipin |
| author_sort | Angelina A. Fedoseeva |
| collection | DOAJ |
| description | We report the first synthesis of zwitterionic thiacalixarenes featuring imidazolium and sulfonate groups on the upper rim and alkyl (butyl or octyl) fragments on the lower rim of the platform. Despite their amphiphilic structure, these macrocycles exhibit limited water solubility. However, dynamic light scattering detected the formation of associates for derivatives with octyl moieties at a concentration of 0.1 mM. To develop stable materials for aqueous environments and to investigate the functionality of zwitterionic sulfonate-imidazolium groups along with the thiacalixarene platform, mixed organo-organic systems based on polydiacetylene polymer were created. Characterization of the modified polydiacetylene systems through various analytical methods revealed a significant colorimetric response to lead ions in aqueous media, surpassing that of the unmodified polydiacetylene polymer. Additionally, the modified polymers demonstrated efficacy in purifying aqueous media from lead ions, as evidenced by anodic stripping voltammetry (ASV) and microwave plasma atomic emission spectroscopy (MP AES). |
| format | Article |
| id | doaj-art-bb765ff1e57f4ab489d792237d480c1e |
| institution | DOAJ |
| issn | 2504-5377 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Colloids and Interfaces |
| spelling | doaj-art-bb765ff1e57f4ab489d792237d480c1e2025-08-20T03:13:44ZengMDPI AGColloids and Interfaces2504-53772025-03-01922010.3390/colloids9020020Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion DetectionAngelina A. Fedoseeva0Indira Yespanova1Elza D. Sultanova2Bulat Kh. Gafiatullin3Regina R. Ibragimova4Klara Kh. Darmagambet5Marina A. Il’ina6Egor O. Chibirev7Vladimir G. Evtugyn8Nurbol O. Appazov9Vladimir A. Burilov10Svetlana E. Solovieva11Igor S. Antipin12A. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaInstitute of Engineering and Technology, Korkyt Ata Kyzylorda University, Ayteke bi Str. 29A, Kyzylorda 120014, KazakhstanA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaInstitute of Engineering and Technology, Korkyt Ata Kyzylorda University, Ayteke bi Str. 29A, Kyzylorda 120014, KazakhstanA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaInstitute of Engineering and Technology, Korkyt Ata Kyzylorda University, Ayteke bi Str. 29A, Kyzylorda 120014, KazakhstanA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaA.E. Arbuzov Institute of Organic & Physical Chemistry, 8 Arbuzov Str., Kazan 420088, RussiaA. M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Str. 18, Kazan 420018, RussiaWe report the first synthesis of zwitterionic thiacalixarenes featuring imidazolium and sulfonate groups on the upper rim and alkyl (butyl or octyl) fragments on the lower rim of the platform. Despite their amphiphilic structure, these macrocycles exhibit limited water solubility. However, dynamic light scattering detected the formation of associates for derivatives with octyl moieties at a concentration of 0.1 mM. To develop stable materials for aqueous environments and to investigate the functionality of zwitterionic sulfonate-imidazolium groups along with the thiacalixarene platform, mixed organo-organic systems based on polydiacetylene polymer were created. Characterization of the modified polydiacetylene systems through various analytical methods revealed a significant colorimetric response to lead ions in aqueous media, surpassing that of the unmodified polydiacetylene polymer. Additionally, the modified polymers demonstrated efficacy in purifying aqueous media from lead ions, as evidenced by anodic stripping voltammetry (ASV) and microwave plasma atomic emission spectroscopy (MP AES).https://www.mdpi.com/2504-5377/9/2/20polydiacetylene vesiclesthiacalixarenecolorimetric sensor |
| spellingShingle | Angelina A. Fedoseeva Indira Yespanova Elza D. Sultanova Bulat Kh. Gafiatullin Regina R. Ibragimova Klara Kh. Darmagambet Marina A. Il’ina Egor O. Chibirev Vladimir G. Evtugyn Nurbol O. Appazov Vladimir A. Burilov Svetlana E. Solovieva Igor S. Antipin Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection Colloids and Interfaces polydiacetylene vesicles thiacalixarene colorimetric sensor |
| title | Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection |
| title_full | Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection |
| title_fullStr | Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection |
| title_full_unstemmed | Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection |
| title_short | Sulfonate Thiacalixarene-Modified Polydiacetylene Vesicles as Colorimetric Sensors for Lead Ion Detection |
| title_sort | sulfonate thiacalixarene modified polydiacetylene vesicles as colorimetric sensors for lead ion detection |
| topic | polydiacetylene vesicles thiacalixarene colorimetric sensor |
| url | https://www.mdpi.com/2504-5377/9/2/20 |
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