Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities

Perilla leaves are a common traditional medicinal and edible crop, in order to further explore its medicinal value, after determining the optimal ultrasound-assisted extraction conditions a neutral polysaccharide was extracted. Its structure was analyzed, and sulfation modification was carried out....

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Main Authors: Jing Guan, Peng Guo, Meng Chen, Wenzhao Wang, Xinyu Chen, Qiuyun Li, Yiyang He, Jiayue Liang, Ningxin Yu, Pengna Gao, Yanli Wu
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Ultrasonics Sonochemistry
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Online Access:http://www.sciencedirect.com/science/article/pii/S1350417725000483
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author Jing Guan
Peng Guo
Meng Chen
Wenzhao Wang
Xinyu Chen
Qiuyun Li
Yiyang He
Jiayue Liang
Ningxin Yu
Pengna Gao
Yanli Wu
author_facet Jing Guan
Peng Guo
Meng Chen
Wenzhao Wang
Xinyu Chen
Qiuyun Li
Yiyang He
Jiayue Liang
Ningxin Yu
Pengna Gao
Yanli Wu
author_sort Jing Guan
collection DOAJ
description Perilla leaves are a common traditional medicinal and edible crop, in order to further explore its medicinal value, after determining the optimal ultrasound-assisted extraction conditions a neutral polysaccharide was extracted. Its structure was analyzed, and sulfation modification was carried out. After purification by different column chromatography, the optimal process for sulfation modification of PLP-2-1 was established, and sulfated modified PLP-2-1 (S-PLP-2-1) was successfully prepared. The potential structural framework and molecular weight of PLP-2-1 were determined by high performance liquid chromatography (HPLC), methylation analysis, and nuclear magnetic resonance (NMR) techniques, while sulfated modified S-PLP-2-1 maintained a high degree of structural similarity to PLP-2-1. Particle size analysis, Zeta potential measurement, infrared spectroscopy, and NMR analysis confirmed the presence of sulfate groups in S-PLP-2-1, while thermogravimetric and rheological analyses provided support for the development and utilization of these two polysaccharides. After determined the safe concentration range in vitro, the antioxidant and hypoglycemic activities of PLP-2-1 and S-PLP-2-1 were measured. Besides, the effects on the levels of total cholesterol (TC), triglyceride (TG), high-density lipoprotein cholesterol (HDL-C), and low-density lipoprotein cholesterol (LDL-C) in oleic acid (OA) induced high-fat HepG2 cells of both polysaccharides were determined. The results indicated that the various biological activities of S-PLP-2-1 were significantly enhanced after sulfation modification. Therefore, PLP-2-1 and S-PLP-2-1 have the potential to be developed as drugs for anti-glycolipid metabolism disorders.
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spelling doaj-art-bb6fcfa59d8849e7939d2c81ecce36de2025-08-20T02:18:46ZengElsevierUltrasonics Sonochemistry1350-41772025-06-0111710726910.1016/j.ultsonch.2025.107269Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activitiesJing Guan0Peng Guo1Meng Chen2Wenzhao Wang3Xinyu Chen4Qiuyun Li5Yiyang He6Jiayue Liang7Ningxin Yu8Pengna Gao9Yanli Wu10Department of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaDepartment of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaCorresponding author at: Department of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin 150081, PR China.; Department of Organic Chemistry, College of Pharmacy, Harbin Medical University, Harbin, Heilongjiang 150081, ChinaPerilla leaves are a common traditional medicinal and edible crop, in order to further explore its medicinal value, after determining the optimal ultrasound-assisted extraction conditions a neutral polysaccharide was extracted. Its structure was analyzed, and sulfation modification was carried out. After purification by different column chromatography, the optimal process for sulfation modification of PLP-2-1 was established, and sulfated modified PLP-2-1 (S-PLP-2-1) was successfully prepared. The potential structural framework and molecular weight of PLP-2-1 were determined by high performance liquid chromatography (HPLC), methylation analysis, and nuclear magnetic resonance (NMR) techniques, while sulfated modified S-PLP-2-1 maintained a high degree of structural similarity to PLP-2-1. Particle size analysis, Zeta potential measurement, infrared spectroscopy, and NMR analysis confirmed the presence of sulfate groups in S-PLP-2-1, while thermogravimetric and rheological analyses provided support for the development and utilization of these two polysaccharides. After determined the safe concentration range in vitro, the antioxidant and hypoglycemic activities of PLP-2-1 and S-PLP-2-1 were measured. Besides, the effects on the levels of total cholesterol (TC), triglyceride (TG), high-density lipoprotein cholesterol (HDL-C), and low-density lipoprotein cholesterol (LDL-C) in oleic acid (OA) induced high-fat HepG2 cells of both polysaccharides were determined. The results indicated that the various biological activities of S-PLP-2-1 were significantly enhanced after sulfation modification. Therefore, PLP-2-1 and S-PLP-2-1 have the potential to be developed as drugs for anti-glycolipid metabolism disorders.http://www.sciencedirect.com/science/article/pii/S1350417725000483Perilla leaves polysaccharidePurificationSulfation modificationHypoglycemic activityHypolipidemic activity
spellingShingle Jing Guan
Peng Guo
Meng Chen
Wenzhao Wang
Xinyu Chen
Qiuyun Li
Yiyang He
Jiayue Liang
Ningxin Yu
Pengna Gao
Yanli Wu
Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
Ultrasonics Sonochemistry
Perilla leaves polysaccharide
Purification
Sulfation modification
Hypoglycemic activity
Hypolipidemic activity
title Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
title_full Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
title_fullStr Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
title_full_unstemmed Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
title_short Ultrasound-assisted extraction, purification, sulfation of Perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
title_sort ultrasound assisted extraction purification sulfation of perilla leaves polysaccharide and hypoglycemic and hypolipidemic activities
topic Perilla leaves polysaccharide
Purification
Sulfation modification
Hypoglycemic activity
Hypolipidemic activity
url http://www.sciencedirect.com/science/article/pii/S1350417725000483
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