Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands
New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in compl...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Tikrit University
2021-07-01
|
| Series: | Tikrit Journal of Pure Science |
| Subjects: | |
| Online Access: | https://tjpsj.org/index.php/tjps/article/view/140 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850115141749702656 |
|---|---|
| author | Emad N. Al_Sabawi Ahmed S. Al-Janabi Hayfa Muhammed Jerjes |
| author_facet | Emad N. Al_Sabawi Ahmed S. Al-Janabi Hayfa Muhammed Jerjes |
| author_sort | Emad N. Al_Sabawi |
| collection | DOAJ |
| description |
New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in complex [Pd(Saly)2], through oxygen atom of hydroxylate group and nitrogen atom of oxime group. However, it was bonded as monodentate ligand in complexes [Pd(Saly)2(amine)] (2-4) via the oxygen atom of hydroxylate group. The amines were coordinated as bidentate chelate via N atom to give a square planner around the Palladium (II).
|
| format | Article |
| id | doaj-art-bb5f9daf30af4e258091621e392e45ab |
| institution | OA Journals |
| issn | 1813-1662 2415-1726 |
| language | English |
| publishDate | 2021-07-01 |
| publisher | Tikrit University |
| record_format | Article |
| series | Tikrit Journal of Pure Science |
| spelling | doaj-art-bb5f9daf30af4e258091621e392e45ab2025-08-20T02:36:39ZengTikrit UniversityTikrit Journal of Pure Science1813-16622415-17262021-07-0126310.25130/tjps.v26i3.140Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligandsEmad N. Al_SabawiAhmed S. Al-JanabiHayfa Muhammed Jerjes New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in complex [Pd(Saly)2], through oxygen atom of hydroxylate group and nitrogen atom of oxime group. However, it was bonded as monodentate ligand in complexes [Pd(Saly)2(amine)] (2-4) via the oxygen atom of hydroxylate group. The amines were coordinated as bidentate chelate via N atom to give a square planner around the Palladium (II). https://tjpsj.org/index.php/tjps/article/view/140SalicylaldoximePalladium oxime2,2'-bipyridyl1,10- phenanthroline |
| spellingShingle | Emad N. Al_Sabawi Ahmed S. Al-Janabi Hayfa Muhammed Jerjes Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands Tikrit Journal of Pure Science Salicylaldoxime Palladium oxime 2,2'-bipyridyl 1,10- phenanthroline |
| title | Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands |
| title_full | Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands |
| title_fullStr | Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands |
| title_full_unstemmed | Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands |
| title_short | Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands |
| title_sort | synthesis and spectroscopic study of pd ii salicylaldoxime complexes with amine ligands |
| topic | Salicylaldoxime Palladium oxime 2,2'-bipyridyl 1,10- phenanthroline |
| url | https://tjpsj.org/index.php/tjps/article/view/140 |
| work_keys_str_mv | AT emadnalsabawi synthesisandspectroscopicstudyofpdiisalicylaldoximecomplexeswithamineligands AT ahmedsaljanabi synthesisandspectroscopicstudyofpdiisalicylaldoximecomplexeswithamineligands AT hayfamuhammedjerjes synthesisandspectroscopicstudyofpdiisalicylaldoximecomplexeswithamineligands |