Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands
New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in compl...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Tikrit University
2021-07-01
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| Series: | Tikrit Journal of Pure Science |
| Subjects: | |
| Online Access: | https://tjpsj.org/index.php/tjps/article/view/140 |
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| Summary: | New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in complex [Pd(Saly)2], through oxygen atom of hydroxylate group and nitrogen atom of oxime group. However, it was bonded as monodentate ligand in complexes [Pd(Saly)2(amine)] (2-4) via the oxygen atom of hydroxylate group. The amines were coordinated as bidentate chelate via N atom to give a square planner around the Palladium (II).
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| ISSN: | 1813-1662 2415-1726 |