A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide
Carbazones are molecules containing important functional groups in designing anion chemosensors due to proton donor and acceptor sites in their structures. In this paper, we synthesize a novel colorimetric receptor with 1,3-dioxo-indene and thiosemicarbazone moieties by the reaction of ninhydrin and...
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| Format: | Article |
| Language: | English |
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Tokat Gaziosmanpasa University
2023-08-01
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| Series: | Journal of New Results in Science |
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| Online Access: | https://dergipark.org.tr/en/download/article-file/3309432 |
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| author | Fatma Aydın |
| author_facet | Fatma Aydın |
| author_sort | Fatma Aydın |
| collection | DOAJ |
| description | Carbazones are molecules containing important functional groups in designing anion chemosensors due to proton donor and acceptor sites in their structures. In this paper, we synthesize a novel colorimetric receptor with 1,3-dioxo-indene and thiosemicarbazone moieties by the reaction of ninhydrin and 4-phenyl-thiosemicarbazide in quantitative yield. We then identify its structure by means of FT-IR, $^{1}$H-NMR, $^{13}$C-NMR, and MS spectroscopic techniques. Moreover, we observe the reaction of the title compound with biologically important F$^¯$, OAc$^¯$, CN$^¯$, H2PO4$^¯$, and OH$^¯$ anions in the presence of other anions, such as Cl$^¯$, Br$^¯$, I$^¯$, SCN$^¯$, and OCl$^¯$ in dimethylsulfoxide solution through a color change from yellow to orange-red that can easily be distinguished even by the naked eye under ambient light. Finally, we evaluate the anion-sensing ability of the title compound via UV-vis spectroscopic studies. |
| format | Article |
| id | doaj-art-bb3eeac47fe3429aa090017fa4777a17 |
| institution | Kabale University |
| issn | 1304-7981 |
| language | English |
| publishDate | 2023-08-01 |
| publisher | Tokat Gaziosmanpasa University |
| record_format | Article |
| series | Journal of New Results in Science |
| spelling | doaj-art-bb3eeac47fe3429aa090017fa4777a172025-08-20T03:44:14ZengTokat Gaziosmanpasa UniversityJournal of New Results in Science1304-79812023-08-0112210811710.54187/jnrs.1338019142A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamideFatma Aydın0https://orcid.org/0000-0002-7219-6407Çanakkale Onsekiz Mart UniversityCarbazones are molecules containing important functional groups in designing anion chemosensors due to proton donor and acceptor sites in their structures. In this paper, we synthesize a novel colorimetric receptor with 1,3-dioxo-indene and thiosemicarbazone moieties by the reaction of ninhydrin and 4-phenyl-thiosemicarbazide in quantitative yield. We then identify its structure by means of FT-IR, $^{1}$H-NMR, $^{13}$C-NMR, and MS spectroscopic techniques. Moreover, we observe the reaction of the title compound with biologically important F$^¯$, OAc$^¯$, CN$^¯$, H2PO4$^¯$, and OH$^¯$ anions in the presence of other anions, such as Cl$^¯$, Br$^¯$, I$^¯$, SCN$^¯$, and OCl$^¯$ in dimethylsulfoxide solution through a color change from yellow to orange-red that can easily be distinguished even by the naked eye under ambient light. Finally, we evaluate the anion-sensing ability of the title compound via UV-vis spectroscopic studies.https://dergipark.org.tr/en/download/article-file/33094324-phenylsemithiocarbazideninhydrinanion receptoruv-vis titrationnaked eye |
| spellingShingle | Fatma Aydın A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide Journal of New Results in Science 4-phenylsemithiocarbazide ninhydrin anion receptor uv-vis titration naked eye |
| title | A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide |
| title_full | A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide |
| title_fullStr | A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide |
| title_full_unstemmed | A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide |
| title_short | A new colorimetric sensor based on semithiocarbazone for some anions: 2-(1,3-dioxo-1,3-dihydro-2H-inden-2-ylidene)-N-phenylhydrazine-1-carbothioamide |
| title_sort | new colorimetric sensor based on semithiocarbazone for some anions 2 1 3 dioxo 1 3 dihydro 2h inden 2 ylidene n phenylhydrazine 1 carbothioamide |
| topic | 4-phenylsemithiocarbazide ninhydrin anion receptor uv-vis titration naked eye |
| url | https://dergipark.org.tr/en/download/article-file/3309432 |
| work_keys_str_mv | AT fatmaaydın anewcolorimetricsensorbasedonsemithiocarbazoneforsomeanions213dioxo13dihydro2hinden2ylidenenphenylhydrazine1carbothioamide AT fatmaaydın newcolorimetricsensorbasedonsemithiocarbazoneforsomeanions213dioxo13dihydro2hinden2ylidenenphenylhydrazine1carbothioamide |