Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges

Lead-cooled fast reactors (LFR), such as the ALFRED Demonstrator, are pivotal in advancing nuclear technology. This study presents a method for quantifying trace-level impurities generated through various nuclear reactions in lead coolant. It combines inductively coupled plasma mass spectrometry wit...

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Main Authors: Ivan Ana Maria, Abrudeanu Marioara, Tarantino Mariano, Gugiu Daniela, Diaconu Daniela, Mirita Diana
Format: Article
Language:English
Published: De Gruyter 2025-08-01
Series:Reviews in Analytical Chemistry
Subjects:
Online Access:https://doi.org/10.1515/revac-2025-0088
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author Ivan Ana Maria
Abrudeanu Marioara
Tarantino Mariano
Gugiu Daniela
Diaconu Daniela
Mirita Diana
author_facet Ivan Ana Maria
Abrudeanu Marioara
Tarantino Mariano
Gugiu Daniela
Diaconu Daniela
Mirita Diana
author_sort Ivan Ana Maria
collection DOAJ
description Lead-cooled fast reactors (LFR), such as the ALFRED Demonstrator, are pivotal in advancing nuclear technology. This study presents a method for quantifying trace-level impurities generated through various nuclear reactions in lead coolant. It combines inductively coupled plasma mass spectrometry with Sr-resin-based matrix separation to analyze trace impurities in lead matrices. The Sr-resin effectively removes lead, a highly interfering matrix, enhancing the precision and reliability of detecting trace elements. The study evaluates the effectiveness of lead matrix removal and assesses the method’s reliability for monitoring trace impurities in LFR systems. The results indicate the method’s suitability for tracking small changes in lead composition during the operation of lead-cooled facilities.
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institution Kabale University
issn 2191-0189
language English
publishDate 2025-08-01
publisher De Gruyter
record_format Article
series Reviews in Analytical Chemistry
spelling doaj-art-bacf5341c2874a19a1c064864bb744b32025-08-25T06:11:27ZengDe GruyterReviews in Analytical Chemistry2191-01892025-08-014411108843210.1515/revac-2025-0088Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challengesIvan Ana Maria0Abrudeanu Marioara1Tarantino Mariano2Gugiu Daniela3Diaconu Daniela4Mirita Diana5RATEN-ICN (Institute for Nuclear Research), Mioveni, RomaniaUPB – National University of Science and Technology POLITEHNICA Bucharest, Bucharest, RomaniaENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development), Bologna, ItalyRATEN-ICN (Institute for Nuclear Research), Mioveni, RomaniaRATEN-ICN (Institute for Nuclear Research), Mioveni, RomaniaRATEN-ICN (Institute for Nuclear Research), Mioveni, RomaniaLead-cooled fast reactors (LFR), such as the ALFRED Demonstrator, are pivotal in advancing nuclear technology. This study presents a method for quantifying trace-level impurities generated through various nuclear reactions in lead coolant. It combines inductively coupled plasma mass spectrometry with Sr-resin-based matrix separation to analyze trace impurities in lead matrices. The Sr-resin effectively removes lead, a highly interfering matrix, enhancing the precision and reliability of detecting trace elements. The study evaluates the effectiveness of lead matrix removal and assesses the method’s reliability for monitoring trace impurities in LFR systems. The results indicate the method’s suitability for tracking small changes in lead composition during the operation of lead-cooled facilities.https://doi.org/10.1515/revac-2025-0088alfredlfrtrace-level analysisactivation and fission productsicp-ms
spellingShingle Ivan Ana Maria
Abrudeanu Marioara
Tarantino Mariano
Gugiu Daniela
Diaconu Daniela
Mirita Diana
Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges
Reviews in Analytical Chemistry
alfred
lfr
trace-level analysis
activation and fission products
icp-ms
title Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges
title_full Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges
title_fullStr Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges
title_full_unstemmed Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges
title_short Trace-level impurity quantification in lead-cooled fast reactors using ICP-MS: Methodology and challenges
title_sort trace level impurity quantification in lead cooled fast reactors using icp ms methodology and challenges
topic alfred
lfr
trace-level analysis
activation and fission products
icp-ms
url https://doi.org/10.1515/revac-2025-0088
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AT tarantinomariano tracelevelimpurityquantificationinleadcooledfastreactorsusingicpmsmethodologyandchallenges
AT gugiudaniela tracelevelimpurityquantificationinleadcooledfastreactorsusingicpmsmethodologyandchallenges
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