Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films

Silver-copper-oxide thin films were formed by RF magnetron sputtering technique using Ag80Cu20 target at various oxygen partial pressures in the range 5 × 10−3–8 ×10−2 Pa and substrate temperatures in the range 303–523 K. The effect of oxygen partial pressure and substrate temperature on the struct...

Full description

Saved in:
Bibliographic Details
Main Authors: P. Narayana Reddy, A. Sreedhar, M. Hari Prasad Reddy, S. Uthanna, J. F. Pierson
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2011/986021
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832549880734679040
author P. Narayana Reddy
A. Sreedhar
M. Hari Prasad Reddy
S. Uthanna
J. F. Pierson
author_facet P. Narayana Reddy
A. Sreedhar
M. Hari Prasad Reddy
S. Uthanna
J. F. Pierson
author_sort P. Narayana Reddy
collection DOAJ
description Silver-copper-oxide thin films were formed by RF magnetron sputtering technique using Ag80Cu20 target at various oxygen partial pressures in the range 5 × 10−3–8 ×10−2 Pa and substrate temperatures in the range 303–523 K. The effect of oxygen partial pressure and substrate temperature on the structure and surface morphology and electrical and optical properties of the films were studied. The Ag-Cu-O films formed at room temperature (303 K) and at low oxygen partial pressure of 5 × 10−3 Pa were mixed phase of Ag2Cu2O3 and Ag, while those deposited at 2 × 10−2 Pa were composed of Ag2Cu2O4 and Ag2Cu2O3 phases. The crystallinity of the films formed at oxygen partial pressure of 2 × 10−2 Pa increased with the increase of substrate temperature from 303 to 423 K. Further increase of substrate temperature to 523 K, the films were decomposed in to Ag2O and Ag phases. The electrical resistivity of the films decreased from 0.8 Ωcm with the increase of substrate temperature from 303 to 473 K due to improvement in the crystallinity of the phase. The optical band gap of the Ag-Cu-O films increased from 1.47 to 1.83 eV with the increase of substrate temperature from 303 to 473 K.
format Article
id doaj-art-bac59d0377234dd6b2d5e46974eb3a63
institution Kabale University
issn 1687-9503
1687-9511
language English
publishDate 2011-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-bac59d0377234dd6b2d5e46974eb3a632025-02-03T06:08:23ZengWileyJournal of Nanotechnology1687-95031687-95112011-01-01201110.1155/2011/986021986021Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O FilmsP. Narayana Reddy0A. Sreedhar1M. Hari Prasad Reddy2S. Uthanna3J. F. Pierson4Department of Physics, Sri Venkateswara University, Tirupati 517 502, IndiaDepartment of Physics, Sri Venkateswara University, Tirupati 517 502, IndiaDepartment of Physics, Sri Venkateswara University, Tirupati 517 502, IndiaDepartment of Physics, Sri Venkateswara University, Tirupati 517 502, IndiaInstitut Jean Lamour (UMR CNRS 7198), Départment CP2S, Ecole des Mines, Nancy Universite, 54042 Nancy Cedex, FranceSilver-copper-oxide thin films were formed by RF magnetron sputtering technique using Ag80Cu20 target at various oxygen partial pressures in the range 5 × 10−3–8 ×10−2 Pa and substrate temperatures in the range 303–523 K. The effect of oxygen partial pressure and substrate temperature on the structure and surface morphology and electrical and optical properties of the films were studied. The Ag-Cu-O films formed at room temperature (303 K) and at low oxygen partial pressure of 5 × 10−3 Pa were mixed phase of Ag2Cu2O3 and Ag, while those deposited at 2 × 10−2 Pa were composed of Ag2Cu2O4 and Ag2Cu2O3 phases. The crystallinity of the films formed at oxygen partial pressure of 2 × 10−2 Pa increased with the increase of substrate temperature from 303 to 423 K. Further increase of substrate temperature to 523 K, the films were decomposed in to Ag2O and Ag phases. The electrical resistivity of the films decreased from 0.8 Ωcm with the increase of substrate temperature from 303 to 473 K due to improvement in the crystallinity of the phase. The optical band gap of the Ag-Cu-O films increased from 1.47 to 1.83 eV with the increase of substrate temperature from 303 to 473 K.http://dx.doi.org/10.1155/2011/986021
spellingShingle P. Narayana Reddy
A. Sreedhar
M. Hari Prasad Reddy
S. Uthanna
J. F. Pierson
Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films
Journal of Nanotechnology
title Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films
title_full Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films
title_fullStr Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films
title_full_unstemmed Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films
title_short Process-Parameter-Dependent Structural, Electrical, and Optical Properties of Reactive Magnetron Sputtered Ag-Cu-O Films
title_sort process parameter dependent structural electrical and optical properties of reactive magnetron sputtered ag cu o films
url http://dx.doi.org/10.1155/2011/986021
work_keys_str_mv AT pnarayanareddy processparameterdependentstructuralelectricalandopticalpropertiesofreactivemagnetronsputteredagcuofilms
AT asreedhar processparameterdependentstructuralelectricalandopticalpropertiesofreactivemagnetronsputteredagcuofilms
AT mhariprasadreddy processparameterdependentstructuralelectricalandopticalpropertiesofreactivemagnetronsputteredagcuofilms
AT suthanna processparameterdependentstructuralelectricalandopticalpropertiesofreactivemagnetronsputteredagcuofilms
AT jfpierson processparameterdependentstructuralelectricalandopticalpropertiesofreactivemagnetronsputteredagcuofilms