Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust
The aromatic nitro compounds are reduced to their corresponding amines at room temperature in good yields by employing diammonium hydrogen phosphite as hydrogen donor and zinc as catalyst. The hydrogenation is fast and selective in the presence of the other sensitive functionalities such as halogens...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2008-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2008/374184 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832561313584250880 |
|---|---|
| author | K. Anil Kumar K. S. Shruthi Nagaraja Naik D. Channe Gowda |
| author_facet | K. Anil Kumar K. S. Shruthi Nagaraja Naik D. Channe Gowda |
| author_sort | K. Anil Kumar |
| collection | DOAJ |
| description | The aromatic nitro compounds are reduced to their corresponding amines at room temperature in good yields by employing diammonium hydrogen phosphite as hydrogen donor and zinc as catalyst. The hydrogenation is fast and selective in the presence of the other sensitive functionalities such as halogens, -OH, -NH2, -OCH3, -CN, -COCH3, -COOH, -COOR etc. It was observed that, this system is equally competitive with existing methods. |
| format | Article |
| id | doaj-art-ba850f444431402da1d226fb9d0798f5 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2008-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-ba850f444431402da1d226fb9d0798f52025-02-03T01:25:30ZengWileyE-Journal of Chemistry0973-49452090-98102008-01-015491491710.1155/2008/374184Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc DustK. Anil Kumar0K. S. Shruthi1Nagaraja Naik2D. Channe Gowda3Department of Studies in Chemistry, University of Mysore, Manasagangothri, Mysore-570006, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangothri, Mysore-570006, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangothri, Mysore-570006, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangothri, Mysore-570006, IndiaThe aromatic nitro compounds are reduced to their corresponding amines at room temperature in good yields by employing diammonium hydrogen phosphite as hydrogen donor and zinc as catalyst. The hydrogenation is fast and selective in the presence of the other sensitive functionalities such as halogens, -OH, -NH2, -OCH3, -CN, -COCH3, -COOH, -COOR etc. It was observed that, this system is equally competitive with existing methods.http://dx.doi.org/10.1155/2008/374184 |
| spellingShingle | K. Anil Kumar K. S. Shruthi Nagaraja Naik D. Channe Gowda Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust E-Journal of Chemistry |
| title | Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust |
| title_full | Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust |
| title_fullStr | Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust |
| title_full_unstemmed | Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust |
| title_short | Chemoselective Hydrogenation of Aromatic Nitro Compounds Using Diammonium Hydrogen Phosphite and Commercial Zinc Dust |
| title_sort | chemoselective hydrogenation of aromatic nitro compounds using diammonium hydrogen phosphite and commercial zinc dust |
| url | http://dx.doi.org/10.1155/2008/374184 |
| work_keys_str_mv | AT kanilkumar chemoselectivehydrogenationofaromaticnitrocompoundsusingdiammoniumhydrogenphosphiteandcommercialzincdust AT ksshruthi chemoselectivehydrogenationofaromaticnitrocompoundsusingdiammoniumhydrogenphosphiteandcommercialzincdust AT nagarajanaik chemoselectivehydrogenationofaromaticnitrocompoundsusingdiammoniumhydrogenphosphiteandcommercialzincdust AT dchannegowda chemoselectivehydrogenationofaromaticnitrocompoundsusingdiammoniumhydrogenphosphiteandcommercialzincdust |