Advancement of eco-friendly slag-based high-strength geopolymer concrete

This study investigates the production and testing of slag-based high-strength geopolymer concrete (HSGC) by incorporating various waste materials as partial substitutes for slag. The focus is on replacing slag with alternative materials such as fly ash (FA), metakaolin (MK), ceramic waste (CW), gla...

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Main Authors: Saeeb M. AL-Tam, Amr Riad, Nader Mohammed, Ali Al-Otaibi, Osama Youssf
Format: Article
Language:English
Published: Elsevier 2025-01-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424029491
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author Saeeb M. AL-Tam
Amr Riad
Nader Mohammed
Ali Al-Otaibi
Osama Youssf
author_facet Saeeb M. AL-Tam
Amr Riad
Nader Mohammed
Ali Al-Otaibi
Osama Youssf
author_sort Saeeb M. AL-Tam
collection DOAJ
description This study investigates the production and testing of slag-based high-strength geopolymer concrete (HSGC) by incorporating various waste materials as partial substitutes for slag. The focus is on replacing slag with alternative materials such as fly ash (FA), metakaolin (MK), ceramic waste (CW), glass waste (GW), rice husk ash (RHA), and charcoal ash (CA). These alternatives are not only cheaper but also have a lower environmental impact, offering additional benefits such as reduced CO2 emissions, representing a significant step towards sustainability. Key variables, such as geopolymer binder proportions (30% and 50%), curing methods (water + steam, heat, and water), and mixing procedures, were examined. Scanning electron microscope (SEM) and energy dispersive X-ray (EDX) spectroscopy analyses were performed on selected HSGC mixes. In addition, cost and energy efficiency analyses were performed on all HSGC blends. Among the mixes tested, CA30, FA30, and FA50 showed increases in both workability (by 30%, 46%, and 79%, respectively) and compressive strength (by 39%, 28%, and 15.4%, respectively) compared to the control mix. The steam + water curing method resulted in the highest compressive strength for all mixtures, except CA30, CA50, and the control mixtures. Furthermore, CA30 and FA30 blends achieved the lowest water permeability (1.9 cm and 1.5 cm, respectively) and sorptivity (3.1 mm and 3.8 mm, respectively), compared to the control mix. Shrinkage of CA50, CW30, and GW50 mixes decreased by an average of 57%, 53%, and 79%, respectively, at all ages. Microstructure analyses revealed a dense and homogeneous matrix for these mixtures, confirming their compressive strength results and identifying them as ideal mixtures. In addition, CA50, FA50, and CW30 mixtures demonstrated higher environmental efficiency, with lower carbon emissions, reduced energy consumption, and improved cost efficiency compared to the control mix. Their values were 139, 144, and 131 MPa/t-CO2/m³, 0.573, 0.575, and 0.586 t–CO2–e/m³, and 2.98, 2.99, and 3.07 GJ/m³, respectively, with cost efficiencies of 0.13, 0.159, and 0.103 MPa-$-m³.
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publishDate 2025-01-01
publisher Elsevier
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series Journal of Materials Research and Technology
spelling doaj-art-ba57237ef48e44a78e1ad0c37444a80c2025-01-19T06:25:37ZengElsevierJournal of Materials Research and Technology2238-78542025-01-013416361653Advancement of eco-friendly slag-based high-strength geopolymer concreteSaeeb M. AL-Tam0Amr Riad1Nader Mohammed2Ali Al-Otaibi3Osama Youssf4Structural Engineering Department, Faculty of Engineering, Al-Azhar University, Cairo, Egypt; Structural Engineering Department, Faculty of Engineering, Amran University, Amran, YemenStructural Engineering Department, Faculty of Engineering, Al-Azhar University, Cairo, EgyptStructural Engineering Department, Faculty of Engineering, Al-Azhar University, Cairo, EgyptCivil Engineering Department, College of Engineering, Shaqra University, Al-Dawadmi, Saudi ArabiaStructural Engineering Department, Faculty of Engineering, Mansoura University, Mansoura, Egypt; Corresponding author.This study investigates the production and testing of slag-based high-strength geopolymer concrete (HSGC) by incorporating various waste materials as partial substitutes for slag. The focus is on replacing slag with alternative materials such as fly ash (FA), metakaolin (MK), ceramic waste (CW), glass waste (GW), rice husk ash (RHA), and charcoal ash (CA). These alternatives are not only cheaper but also have a lower environmental impact, offering additional benefits such as reduced CO2 emissions, representing a significant step towards sustainability. Key variables, such as geopolymer binder proportions (30% and 50%), curing methods (water + steam, heat, and water), and mixing procedures, were examined. Scanning electron microscope (SEM) and energy dispersive X-ray (EDX) spectroscopy analyses were performed on selected HSGC mixes. In addition, cost and energy efficiency analyses were performed on all HSGC blends. Among the mixes tested, CA30, FA30, and FA50 showed increases in both workability (by 30%, 46%, and 79%, respectively) and compressive strength (by 39%, 28%, and 15.4%, respectively) compared to the control mix. The steam + water curing method resulted in the highest compressive strength for all mixtures, except CA30, CA50, and the control mixtures. Furthermore, CA30 and FA30 blends achieved the lowest water permeability (1.9 cm and 1.5 cm, respectively) and sorptivity (3.1 mm and 3.8 mm, respectively), compared to the control mix. Shrinkage of CA50, CW30, and GW50 mixes decreased by an average of 57%, 53%, and 79%, respectively, at all ages. Microstructure analyses revealed a dense and homogeneous matrix for these mixtures, confirming their compressive strength results and identifying them as ideal mixtures. In addition, CA50, FA50, and CW30 mixtures demonstrated higher environmental efficiency, with lower carbon emissions, reduced energy consumption, and improved cost efficiency compared to the control mix. Their values were 139, 144, and 131 MPa/t-CO2/m³, 0.573, 0.575, and 0.586 t–CO2–e/m³, and 2.98, 2.99, and 3.07 GJ/m³, respectively, with cost efficiencies of 0.13, 0.159, and 0.103 MPa-$-m³.http://www.sciencedirect.com/science/article/pii/S2238785424029491High-strength geopolymer concreteCharcoal ashCuring methodsMechanical propertiesMicrostructureEco-efficiency
spellingShingle Saeeb M. AL-Tam
Amr Riad
Nader Mohammed
Ali Al-Otaibi
Osama Youssf
Advancement of eco-friendly slag-based high-strength geopolymer concrete
Journal of Materials Research and Technology
High-strength geopolymer concrete
Charcoal ash
Curing methods
Mechanical properties
Microstructure
Eco-efficiency
title Advancement of eco-friendly slag-based high-strength geopolymer concrete
title_full Advancement of eco-friendly slag-based high-strength geopolymer concrete
title_fullStr Advancement of eco-friendly slag-based high-strength geopolymer concrete
title_full_unstemmed Advancement of eco-friendly slag-based high-strength geopolymer concrete
title_short Advancement of eco-friendly slag-based high-strength geopolymer concrete
title_sort advancement of eco friendly slag based high strength geopolymer concrete
topic High-strength geopolymer concrete
Charcoal ash
Curing methods
Mechanical properties
Microstructure
Eco-efficiency
url http://www.sciencedirect.com/science/article/pii/S2238785424029491
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