Chemical Recycling of Expanded Polystyrene Waste: Synthesis of Novel Functional Polystyrene-Hydrazone Surface for Phenol Removal

Expanded polystyrene (EPS) waste was chemically recycled to a novel functional polystyrene-hydrazone (PSH) surface by acetylation of polystyrene (PS) and then condensation with phenyl hydrazine. The synthesized surface was characterized by the FT-IR and elemental analysis. Synthesized novel function...

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Bibliographic Details
Main Authors: Ali N. Siyal, Saima Q. Memon, Sajida Parveen, Asma Soomro, Mazhar I. Khaskheli, M. Y. Khuhawar
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/842435
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Summary:Expanded polystyrene (EPS) waste was chemically recycled to a novel functional polystyrene-hydrazone (PSH) surface by acetylation of polystyrene (PS) and then condensation with phenyl hydrazine. The synthesized surface was characterized by the FT-IR and elemental analysis. Synthesized novel functional PSH surface was successfully applied for the treatment of phenol-contaminated industrial wastewater by solid-phase extraction. Multivariant sorption optimization was achieved by factorial design approach. 99.93% of phenol was removed from aqueous solution. FT-IR study showed the involvement of nitrogen of hydrazone moiety of synthesized surface for the uptake of phenol through the hydrogen bonding.
ISSN:2090-9063
2090-9071