High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters

ABSTRACT In the process of water treatment from surface water sources, lime mud as waste is formed. This waste contains CaO, Ca(OH)2, and CaCO3. The article proposes a comprehensive method for processing lime mud into high‐strength anhydrite cement. The method involves the interaction of lime mud wi...

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Main Authors: Maksim Kamarou, Hongbin Tan, Dmitry Moskovskikh, Natallia Kulinich, Xiaoling Ma, Feihua Yang, Evgenii Beletskii, Elena Alekseeva, Sergey Yudin, Valentin Romanovski
Format: Article
Language:English
Published: Wiley 2025-01-01
Series:Engineering Reports
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Online Access:https://doi.org/10.1002/eng2.13054
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author Maksim Kamarou
Hongbin Tan
Dmitry Moskovskikh
Natallia Kulinich
Xiaoling Ma
Feihua Yang
Evgenii Beletskii
Elena Alekseeva
Sergey Yudin
Valentin Romanovski
author_facet Maksim Kamarou
Hongbin Tan
Dmitry Moskovskikh
Natallia Kulinich
Xiaoling Ma
Feihua Yang
Evgenii Beletskii
Elena Alekseeva
Sergey Yudin
Valentin Romanovski
author_sort Maksim Kamarou
collection DOAJ
description ABSTRACT In the process of water treatment from surface water sources, lime mud as waste is formed. This waste contains CaO, Ca(OH)2, and CaCO3. The article proposes a comprehensive method for processing lime mud into high‐strength anhydrite cement. The method involves the interaction of lime mud with waste sulfuric acid from the production of polymer fibers using a structure‐controlled method in the (CaO·Ca(OH)2·CaCO3)—H2SO4—H2O system at a temperature of 40°C. X‐ray diffraction analysis showed the presence of CaSO4 and CaSO4·0.62H2O phases with a purity of 99.8%. The structure‐controlled method makes it possible to control the formation and growth of calcium sulfate crystals of the required shape and size, due to which it is possible to obtain anhydrite cement with desired properties. Combined grinding of synthetic anhydrite with activator additives makes it possible to obtain anhydrite cement with a strength of up to 28.5 MPa.
format Article
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institution Kabale University
issn 2577-8196
language English
publishDate 2025-01-01
publisher Wiley
record_format Article
series Engineering Reports
spelling doaj-art-b9980a64cd4c4a30baaea9c676cf92972025-01-31T00:22:49ZengWileyEngineering Reports2577-81962025-01-0171n/an/a10.1002/eng2.13054High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological ParametersMaksim Kamarou0Hongbin Tan1Dmitry Moskovskikh2Natallia Kulinich3Xiaoling Ma4Feihua Yang5Evgenii Beletskii6Elena Alekseeva7Sergey Yudin8Valentin Romanovski9International Information and Analytical Center for Technology Transfer Belarusian State Technological University Minsk BelarusSchool of Materials and Chemistry Southwest University of Science and Technology Mianyang ChinaScience and Research Centre of Functional Nano‐Ceramics National University of Science and Technology “MISIS” Moscow RussiaInstitute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus Minsk BelarusSchool of Materials and Chemistry Southwest University of Science and Technology Mianyang ChinaState Key Laboratory of Solid Waste Resource Utilization and Energy Saving Building Materials Beijing ChinaInstitute of Chemistry Saint Petersburg State University St. Petersburg RussiaInstitute of Chemistry Saint Petersburg State University St. Petersburg RussiaResearch Laboratory of Scanning Probe Microscopy Moscow Polytechnic University Moscow RussiaDepartment of Materials Science and Engineering University of Virginia Charlottesville Virginia USAABSTRACT In the process of water treatment from surface water sources, lime mud as waste is formed. This waste contains CaO, Ca(OH)2, and CaCO3. The article proposes a comprehensive method for processing lime mud into high‐strength anhydrite cement. The method involves the interaction of lime mud with waste sulfuric acid from the production of polymer fibers using a structure‐controlled method in the (CaO·Ca(OH)2·CaCO3)—H2SO4—H2O system at a temperature of 40°C. X‐ray diffraction analysis showed the presence of CaSO4 and CaSO4·0.62H2O phases with a purity of 99.8%. The structure‐controlled method makes it possible to control the formation and growth of calcium sulfate crystals of the required shape and size, due to which it is possible to obtain anhydrite cement with desired properties. Combined grinding of synthetic anhydrite with activator additives makes it possible to obtain anhydrite cement with a strength of up to 28.5 MPa.https://doi.org/10.1002/eng2.13054anhydrite cementcrystalslime mudprocessing technologystructure‐guided methodsynthetic anhydrite
spellingShingle Maksim Kamarou
Hongbin Tan
Dmitry Moskovskikh
Natallia Kulinich
Xiaoling Ma
Feihua Yang
Evgenii Beletskii
Elena Alekseeva
Sergey Yudin
Valentin Romanovski
High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters
Engineering Reports
anhydrite cement
crystals
lime mud
processing technology
structure‐guided method
synthetic anhydrite
title High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters
title_full High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters
title_fullStr High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters
title_full_unstemmed High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters
title_short High Strength Anhydrite Cement Based on Lime Mud From Water Treatment Process: One Step Synthesis in Water Environment, Characterization and Technological Parameters
title_sort high strength anhydrite cement based on lime mud from water treatment process one step synthesis in water environment characterization and technological parameters
topic anhydrite cement
crystals
lime mud
processing technology
structure‐guided method
synthetic anhydrite
url https://doi.org/10.1002/eng2.13054
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