Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst
Abstract The synthesis of efficient organic compounds from simple substrates is both noticeable and important. However, it can be challenging to achieve this target using suitable strategies. To address this issue, pyrazinium chlorochromate (PCC) was used to modify carbonitride nanosheets (CNs) and...
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2024-10-01
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| Series: | Scientific Reports |
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| Online Access: | https://doi.org/10.1038/s41598-024-75036-6 |
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| author | Hasan Soltani Zeinab Tajik Zahra Nasri Peyman Hanifehnejad Elaheh Hamidi Zahra Aslbeigi Hossein Ghafuri |
| author_facet | Hasan Soltani Zeinab Tajik Zahra Nasri Peyman Hanifehnejad Elaheh Hamidi Zahra Aslbeigi Hossein Ghafuri |
| author_sort | Hasan Soltani |
| collection | DOAJ |
| description | Abstract The synthesis of efficient organic compounds from simple substrates is both noticeable and important. However, it can be challenging to achieve this target using suitable strategies. To address this issue, pyrazinium chlorochromate (PCC) was used to modify carbonitride nanosheets (CNs) and applied as a heterogeneous catalyst in the oxidation of benzyl alcohols. That can be regarded as innovation in ingenious synthesis of the PCC on the CNs. Then, it was identified by varied techniques such as EDS, FT-IR, XRD, STA and FE-SEM. This process resulted in in-situ synthesis of 1,4-dihydropyridine and 3,4-dihydropyrimidin-2-(1H) one derivatives with excellent yield. |
| format | Article |
| id | doaj-art-b94eb1fbb5244c7bb6be3dbbbb239740 |
| institution | OA Journals |
| issn | 2045-2322 |
| language | English |
| publishDate | 2024-10-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj-art-b94eb1fbb5244c7bb6be3dbbbb2397402025-08-20T02:32:50ZengNature PortfolioScientific Reports2045-23222024-10-0114111010.1038/s41598-024-75036-6Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalystHasan Soltani0Zeinab Tajik1Zahra Nasri2Peyman Hanifehnejad3Elaheh Hamidi4Zahra Aslbeigi5Hossein Ghafuri6Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyCatalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and TechnologyAbstract The synthesis of efficient organic compounds from simple substrates is both noticeable and important. However, it can be challenging to achieve this target using suitable strategies. To address this issue, pyrazinium chlorochromate (PCC) was used to modify carbonitride nanosheets (CNs) and applied as a heterogeneous catalyst in the oxidation of benzyl alcohols. That can be regarded as innovation in ingenious synthesis of the PCC on the CNs. Then, it was identified by varied techniques such as EDS, FT-IR, XRD, STA and FE-SEM. This process resulted in in-situ synthesis of 1,4-dihydropyridine and 3,4-dihydropyrimidin-2-(1H) one derivatives with excellent yield.https://doi.org/10.1038/s41598-024-75036-6Heterogeneous catalystCNs@PCC3,4-dihydropyrimidin-2-(1H)-one1,4-dihydropyridine |
| spellingShingle | Hasan Soltani Zeinab Tajik Zahra Nasri Peyman Hanifehnejad Elaheh Hamidi Zahra Aslbeigi Hossein Ghafuri Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst Scientific Reports Heterogeneous catalyst CNs@PCC 3,4-dihydropyrimidin-2-(1H)-one 1,4-dihydropyridine |
| title | Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst |
| title_full | Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst |
| title_fullStr | Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst |
| title_full_unstemmed | Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst |
| title_short | Efficient in-situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate-functionalized carbonitride as a novel catalyst |
| title_sort | efficient in situ synthesis of heterocyclic derivatives from benzyl alcohols using pyrazinium chlorochromate functionalized carbonitride as a novel catalyst |
| topic | Heterogeneous catalyst CNs@PCC 3,4-dihydropyrimidin-2-(1H)-one 1,4-dihydropyridine |
| url | https://doi.org/10.1038/s41598-024-75036-6 |
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