Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine
Cubic copper hexacyanoferrate (CuHCF) nanoparticles prepared via electrolytic deposition are presented with their morphology and crystalline structure characterized with SEM and XRD. The advantage of this methodology is that it allows the fabrication of uniform cubic nanoparticles with permeable str...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.4061/2011/395724 |
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| author | Xingxing Wang Yun Zhang Shan Jiang Xiaobo Ji Yong Liu Craig E. Banks |
| author_facet | Xingxing Wang Yun Zhang Shan Jiang Xiaobo Ji Yong Liu Craig E. Banks |
| author_sort | Xingxing Wang |
| collection | DOAJ |
| description | Cubic copper hexacyanoferrate (CuHCF) nanoparticles prepared via electrolytic deposition are presented with their morphology and crystalline structure characterized with SEM and XRD. The advantage of this methodology is that it allows the fabrication of uniform cubic nanoparticles with permeable structures onto the desired underlying electrode substrate. It was observed that the CuHCF film acts as a permeable membrane for cations such as K+, Na+, Li+, and NH4+ with a selection order of K+> Li+>NH4+> Na+. Furthermore, the analytical utility of these cubic-like CuHCF morphologies supported on a glassy carbon electrode was evaluated towards the electrochemical oxidation of hydrazine which was found to exhibit a linear response over the range 66 𝜇M to 17 mM with a detection limit corresponding to 16.5 𝜇M. |
| format | Article |
| id | doaj-art-b949320da9ef44e3bf240099de16561e |
| institution | OA Journals |
| issn | 2090-3537 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-b949320da9ef44e3bf240099de16561e2025-08-20T02:23:32ZengWileyInternational Journal of Electrochemistry2090-35372011-01-01201110.4061/2011/395724395724Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards HydrazineXingxing Wang0Yun Zhang1Shan Jiang2Xiaobo Ji3Yong Liu4Craig E. Banks5College of Material Science and Engineering, Sichuan University, Chengdu, Sichuan 610064, ChinaCollege of Material Science and Engineering, Sichuan University, Chengdu, Sichuan 610064, ChinaCollege of Material Science and Engineering, Sichuan University, Chengdu, Sichuan 610064, ChinaState Key laboratory of Powder Metallurgy Research Institute, Central South University, Changsha 410083, ChinaCollege of Material Science and Engineering, Sichuan University, Chengdu, Sichuan 610064, ChinaDivision of Chemistry and Environmental Science, School of Science and the Environment, Manchester Metropolitan University, Manchester M1 5GD, UKCubic copper hexacyanoferrate (CuHCF) nanoparticles prepared via electrolytic deposition are presented with their morphology and crystalline structure characterized with SEM and XRD. The advantage of this methodology is that it allows the fabrication of uniform cubic nanoparticles with permeable structures onto the desired underlying electrode substrate. It was observed that the CuHCF film acts as a permeable membrane for cations such as K+, Na+, Li+, and NH4+ with a selection order of K+> Li+>NH4+> Na+. Furthermore, the analytical utility of these cubic-like CuHCF morphologies supported on a glassy carbon electrode was evaluated towards the electrochemical oxidation of hydrazine which was found to exhibit a linear response over the range 66 𝜇M to 17 mM with a detection limit corresponding to 16.5 𝜇M.http://dx.doi.org/10.4061/2011/395724 |
| spellingShingle | Xingxing Wang Yun Zhang Shan Jiang Xiaobo Ji Yong Liu Craig E. Banks Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine International Journal of Electrochemistry |
| title | Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine |
| title_full | Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine |
| title_fullStr | Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine |
| title_full_unstemmed | Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine |
| title_short | Cubic Copper Hexacyanoferrates Nanoparticles: Facile Template-Free Deposition and Electrocatalytic Sensing Towards Hydrazine |
| title_sort | cubic copper hexacyanoferrates nanoparticles facile template free deposition and electrocatalytic sensing towards hydrazine |
| url | http://dx.doi.org/10.4061/2011/395724 |
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