Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS

In order to develop sensors capable to detect harmful gases at the ambient temperature, the semiconductor heterostructure PbS/CdS has been synthesized. Formation of CdS nanorods was conducted in the presence of ethylenediamine. An ion-exchange method was used to deposit PbS nanoparticles over the Cd...

Full description

Saved in:
Bibliographic Details
Main Authors: S. L. Prokopenko, G. M. Gunja, S. M. Makhno, P. P. Gorbyk
Format: Article
Language:English
Published: Chuiko Institute of Surface Chemistry of NAS of Ukraine 2017-02-01
Series:Хімія, фізика та технологія поверхні
Subjects:
Online Access:https://cpts.com.ua/index.php/cpts/article/view/418
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849421611929698304
author S. L. Prokopenko
G. M. Gunja
S. M. Makhno
P. P. Gorbyk
author_facet S. L. Prokopenko
G. M. Gunja
S. M. Makhno
P. P. Gorbyk
author_sort S. L. Prokopenko
collection DOAJ
description In order to develop sensors capable to detect harmful gases at the ambient temperature, the semiconductor heterostructure PbS/CdS has been synthesized. Formation of CdS nanorods was conducted in the presence of ethylenediamine. An ion-exchange method was used to deposit PbS nanoparticles over the CdS nanorods to produce a large area of the surface heterojunction. Series of samples of with variation in the PbS amount on the CdS surface (from 2.5 to 20mol.%) was obtained. Surface morphology, optical properties and performance characteristics of the PbS/CdS heterostructure gas sensors were studied. The sample performance characteristics were measured by means of change in electric resistance of sensor due to reaction between the surface of material and NH3 in saturated vapours of ammonia. The gas sensor based on the PbS/CdS heterostructures have shorter response and recovery time compared to a sensor based on the CdS solely. It has been shown that with increase in amount of PbS on the CdS surface from 2.5 to 20mol.% the sensor response rate becomes 1.7 times greater.
format Article
id doaj-art-b922c24afbc046aea9c774d60be6bd3e
institution Kabale University
issn 2079-1704
2518-1238
language English
publishDate 2017-02-01
publisher Chuiko Institute of Surface Chemistry of NAS of Ukraine
record_format Article
series Хімія, фізика та технологія поверхні
spelling doaj-art-b922c24afbc046aea9c774d60be6bd3e2025-08-20T03:31:24ZengChuiko Institute of Surface Chemistry of NAS of UkraineХімія, фізика та технологія поверхні2079-17042518-12382017-02-018110.15407/hftp08.01.098Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdSS. L. Prokopenko0G. M. Gunja1S. M. Makhno2P. P. Gorbyk3Chuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineChuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineChuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineChuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineIn order to develop sensors capable to detect harmful gases at the ambient temperature, the semiconductor heterostructure PbS/CdS has been synthesized. Formation of CdS nanorods was conducted in the presence of ethylenediamine. An ion-exchange method was used to deposit PbS nanoparticles over the CdS nanorods to produce a large area of the surface heterojunction. Series of samples of with variation in the PbS amount on the CdS surface (from 2.5 to 20mol.%) was obtained. Surface morphology, optical properties and performance characteristics of the PbS/CdS heterostructure gas sensors were studied. The sample performance characteristics were measured by means of change in electric resistance of sensor due to reaction between the surface of material and NH3 in saturated vapours of ammonia. The gas sensor based on the PbS/CdS heterostructures have shorter response and recovery time compared to a sensor based on the CdS solely. It has been shown that with increase in amount of PbS on the CdS surface from 2.5 to 20mol.% the sensor response rate becomes 1.7 times greater.https://cpts.com.ua/index.php/cpts/article/view/418sensorPbS/CdS heterostructuresammoniananowires
spellingShingle S. L. Prokopenko
G. M. Gunja
S. M. Makhno
P. P. Gorbyk
Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS
Хімія, фізика та технологія поверхні
sensor
PbS/CdS heterostructures
ammonia
nanowires
title Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS
title_full Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS
title_fullStr Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS
title_full_unstemmed Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS
title_short Room-temperature NH<sub>3</sub> gas sensors based on heterostructures PbS/CdS
title_sort room temperature nh sub 3 sub gas sensors based on heterostructures pbs cds
topic sensor
PbS/CdS heterostructures
ammonia
nanowires
url https://cpts.com.ua/index.php/cpts/article/view/418
work_keys_str_mv AT slprokopenko roomtemperaturenhsub3subgassensorsbasedonheterostructurespbscds
AT gmgunja roomtemperaturenhsub3subgassensorsbasedonheterostructurespbscds
AT smmakhno roomtemperaturenhsub3subgassensorsbasedonheterostructurespbscds
AT ppgorbyk roomtemperaturenhsub3subgassensorsbasedonheterostructurespbscds