Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization

Organic synthesis of the monomer of poly(p-phenylenevinylene) was performed starting by the 2,5-dimethylphenol compound. An iodine atom was added to one end of the aromatic ring and then the iodine atom was substituted by a cyano group. Opposite to the cyano group was added a chain of six carbon ato...

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Main Authors: Álvaro Fontana, Fábio Santana dos Santos, Flávia Aparecida Fonseca, Adonilson Dos Reis Freitas, Andersson Barison, Jarem Raul Garcia
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2015/620938
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author Álvaro Fontana
Fábio Santana dos Santos
Flávia Aparecida Fonseca
Adonilson Dos Reis Freitas
Andersson Barison
Jarem Raul Garcia
author_facet Álvaro Fontana
Fábio Santana dos Santos
Flávia Aparecida Fonseca
Adonilson Dos Reis Freitas
Andersson Barison
Jarem Raul Garcia
author_sort Álvaro Fontana
collection DOAJ
description Organic synthesis of the monomer of poly(p-phenylenevinylene) was performed starting by the 2,5-dimethylphenol compound. An iodine atom was added to one end of the aromatic ring and then the iodine atom was substituted by a cyano group. Opposite to the cyano group was added a chain of six carbon atoms and the end of the carbon chain has an added bromine atom. The characterizations of the obtained compounds were made by FTIR, GC-MS, 1H, and 13C NMR and showed that almost all of the proposed monomers were obtained in their totality.
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spelling doaj-art-b8741b39a55644ae9e626e6a4db60dee2025-02-03T01:33:18ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/620938620938Synthesis and Characterization of PPV Monomer for Subsequent ElectropolymerizationÁlvaro Fontana0Fábio Santana dos Santos1Flávia Aparecida Fonseca2Adonilson Dos Reis Freitas3Andersson Barison4Jarem Raul Garcia5Department of Chemistry, State University of Ponta Grossa, Uvaranas, General Carlos Cavalcanti Avenue 4748, 84030-900 Ponta Grossa, PR, BrazilDepartment of Chemistry, State University of Ponta Grossa, Uvaranas, General Carlos Cavalcanti Avenue 4748, 84030-900 Ponta Grossa, PR, BrazilDepartment of Chemistry, Federal University of Parana, Polytechnic Center, Garden of the Americas, Coronel Francisco Heráclito dos Santos Street 100, P.O. Box 19032, 81531-980 Curitiba, PR, BrazilDepartment of Chemistry, State University of Ponta Grossa, Uvaranas, General Carlos Cavalcanti Avenue 4748, 84030-900 Ponta Grossa, PR, BrazilDepartment of Chemistry, Federal University of Parana, Polytechnic Center, Garden of the Americas, Coronel Francisco Heráclito dos Santos Street 100, P.O. Box 19032, 81531-980 Curitiba, PR, BrazilDepartment of Chemistry, State University of Ponta Grossa, Uvaranas, General Carlos Cavalcanti Avenue 4748, 84030-900 Ponta Grossa, PR, BrazilOrganic synthesis of the monomer of poly(p-phenylenevinylene) was performed starting by the 2,5-dimethylphenol compound. An iodine atom was added to one end of the aromatic ring and then the iodine atom was substituted by a cyano group. Opposite to the cyano group was added a chain of six carbon atoms and the end of the carbon chain has an added bromine atom. The characterizations of the obtained compounds were made by FTIR, GC-MS, 1H, and 13C NMR and showed that almost all of the proposed monomers were obtained in their totality.http://dx.doi.org/10.1155/2015/620938
spellingShingle Álvaro Fontana
Fábio Santana dos Santos
Flávia Aparecida Fonseca
Adonilson Dos Reis Freitas
Andersson Barison
Jarem Raul Garcia
Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
Journal of Chemistry
title Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
title_full Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
title_fullStr Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
title_full_unstemmed Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
title_short Synthesis and Characterization of PPV Monomer for Subsequent Electropolymerization
title_sort synthesis and characterization of ppv monomer for subsequent electropolymerization
url http://dx.doi.org/10.1155/2015/620938
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