Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction

Objectives. The study aims to analyze the dichlorocarbenation of the isoamylene fraction, which is a mixture of 2-methyl-butene-1 and 2-methyl-butene-2, in order to obtain the corresponding alkyl-gem-dichlorocyclopropanes in quantitative yield, and also to determine their structure.Methods. In order...

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Main Authors: A. I. Musin, Yu. G. Borisova, G. Z. Raskil’dina, R. R. Daminev, R. U. Rabaev, S. S. Zlotskii
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2021-01-01
Series:Тонкие химические технологии
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Online Access:https://www.finechem-mirea.ru/jour/article/view/1662
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author A. I. Musin
Yu. G. Borisova
G. Z. Raskil’dina
R. R. Daminev
R. U. Rabaev
S. S. Zlotskii
author_facet A. I. Musin
Yu. G. Borisova
G. Z. Raskil’dina
R. R. Daminev
R. U. Rabaev
S. S. Zlotskii
author_sort A. I. Musin
collection DOAJ
description Objectives. The study aims to analyze the dichlorocarbenation of the isoamylene fraction, which is a mixture of 2-methyl-butene-1 and 2-methyl-butene-2, in order to obtain the corresponding alkyl-gem-dichlorocyclopropanes in quantitative yield, and also to determine their structure.Methods. In order to determine the qualitative and quantitative composition of the reaction masses, the following analysis methods were used: gas-liquid chromatography (using the Crystal 2000 hardware complex), mass spectrometry (using a Chromatec-Crystal 5000M device with NIST 2012 database), and nuclear magnetic resonance (NMR) spectroscopy (using a Bruker AM-500 device at operating frequencies of 500 and 125 MHz).Results. Alkyl-gem-dichlorocyclopropanes were synthesized from an isoamylene fraction in the presence of catamine AB as a catalyst. Alternatively, isomeric alkenyl-gem-dichlorocyclopropanes were obtained on the basis of isoprene, and by reduction, the corresponding alkyl-gemdichlorocyclopropanes were synthesized. The synthesized substances were analyzed by gasliquid chromatography, mass spectrometry, and NMR spectroscopy, as previously mentioned above.Conclusions. The results show that the dichlorocyclopropanation of the isoamylene fraction proceeds quantitatively with the formation of a mixture of 2-methyl-2-ethyl-1,1dichlorocyclopropane and 2,3,3-trimethyl-1,1-dichlorocyclopropane. Using isoprene, countersynthesis through successive dichlorocarbenation and hydrogenation was used to synthesize 2-methyl-2-ethyl-1,1-dichlorocyclopropane, one of the products of dichlorocarbenation of the isoamylene fraction.
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publishDate 2021-01-01
publisher MIREA - Russian Technological University
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spelling doaj-art-b85936bd1d594dbca40baaf6aa7cef032025-08-20T02:59:45ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752021-01-0115691510.32362/2410-6593-2020-15-6-9-151612Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fractionA. I. Musin0Yu. G. Borisova1G. Z. Raskil’dina2R. R. Daminev3R. U. Rabaev4S. S. Zlotskii5Ufa State Petroleum Technological University, Branch in SterlitamakUfa State Petroleum Technological University, Branch in SterlitamakUfa State Petroleum Technological UniversityUfa State Petroleum Technological University, Branch in SterlitamakUfa State Petroleum Technological UniversityUfa State Petroleum Technological UniversityObjectives. The study aims to analyze the dichlorocarbenation of the isoamylene fraction, which is a mixture of 2-methyl-butene-1 and 2-methyl-butene-2, in order to obtain the corresponding alkyl-gem-dichlorocyclopropanes in quantitative yield, and also to determine their structure.Methods. In order to determine the qualitative and quantitative composition of the reaction masses, the following analysis methods were used: gas-liquid chromatography (using the Crystal 2000 hardware complex), mass spectrometry (using a Chromatec-Crystal 5000M device with NIST 2012 database), and nuclear magnetic resonance (NMR) spectroscopy (using a Bruker AM-500 device at operating frequencies of 500 and 125 MHz).Results. Alkyl-gem-dichlorocyclopropanes were synthesized from an isoamylene fraction in the presence of catamine AB as a catalyst. Alternatively, isomeric alkenyl-gem-dichlorocyclopropanes were obtained on the basis of isoprene, and by reduction, the corresponding alkyl-gemdichlorocyclopropanes were synthesized. The synthesized substances were analyzed by gasliquid chromatography, mass spectrometry, and NMR spectroscopy, as previously mentioned above.Conclusions. The results show that the dichlorocyclopropanation of the isoamylene fraction proceeds quantitatively with the formation of a mixture of 2-methyl-2-ethyl-1,1dichlorocyclopropane and 2,3,3-trimethyl-1,1-dichlorocyclopropane. Using isoprene, countersynthesis through successive dichlorocarbenation and hydrogenation was used to synthesize 2-methyl-2-ethyl-1,1-dichlorocyclopropane, one of the products of dichlorocarbenation of the isoamylene fraction.https://www.finechem-mirea.ru/jour/article/view/1662alkenyl-gem-dichlorocyclopropaneisoamylene fractionhydrogenationpd/c
spellingShingle A. I. Musin
Yu. G. Borisova
G. Z. Raskil’dina
R. R. Daminev
R. U. Rabaev
S. S. Zlotskii
Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction
Тонкие химические технологии
alkenyl-gem-dichlorocyclopropane
isoamylene fraction
hydrogenation
pd/c
title Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction
title_full Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction
title_fullStr Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction
title_full_unstemmed Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction
title_short Synthesis of alkyl-<i>gem</i>-dichlorocyclopropanes based on isoamylene fraction
title_sort synthesis of alkyl i gem i dichlorocyclopropanes based on isoamylene fraction
topic alkenyl-gem-dichlorocyclopropane
isoamylene fraction
hydrogenation
pd/c
url https://www.finechem-mirea.ru/jour/article/view/1662
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AT rrdaminev synthesisofalkyligemidichlorocyclopropanesbasedonisoamylenefraction
AT rurabaev synthesisofalkyligemidichlorocyclopropanesbasedonisoamylenefraction
AT sszlotskii synthesisofalkyligemidichlorocyclopropanesbasedonisoamylenefraction